| Identification | More | [Name]
Chlorotriphenyltin | [CAS]
639-58-7 | [Synonyms]
CHLOROTRIPHENYLSTANNANE
CHLOROTRIPHENYLTIN
FENTIN CHLORIDE
FENTIN-CHLORIDE STANDARD
TRIPHENYLCHLOROTIN
TRIPHENYL-D15-TIN CHLORIDE
TRIPHENYLTIN CHLORIDE
TRIPHENYLTIN CHLORIDE-D15
TRIPHENYLTIN(IV) CHLORIDE
TRIPHENYLTIN(IV) CHLORIDE-D15
ai3-25207
Aquatin
Aquatin 20 ec
aquatin20ec
Brestanol
caswellno896d
chlorotriphenyl-stannan
epapesticidechemicalcode496500
GC 8993
gc8993 | [EINECS(EC#)]
211-358-4 | [Molecular Formula]
C18H15ClSn | [MDL Number]
MFCD01861652 | [Molecular Weight]
385.47 | [MOL File]
639-58-7.mol |
| Chemical Properties | Back Directory | [Appearance]
White to off-white crystalline powder | [Melting point ]
108 °C (dec.)(lit.)
| [Boiling point ]
240 °C13.5 mm Hg(lit.)
| [density ]
1.49 g/cm3 (20℃) | [vapor pressure ]
<0.02 hPa (20 °C) | [Fp ]
70°C | [storage temp. ]
APPROX 4°C
| [solubility ]
0.04g/l | [form ]
Powder | [color ]
white | [Water Solubility ]
insoluble | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [Sensitive ]
Moisture Sensitive | [BRN ]
524762 | [Exposure limits]
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 | [CAS DataBase Reference]
639-58-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Chlorotriphenyl tin(639-58-7) | [EPA Substance Registry System]
639-58-7(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T,N,C | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN 3146 6.1/PG 3
| [WGK Germany ]
3
| [RTECS ]
WH6860000
| [Autoignition Temperature]
>250 °C | [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29310095 | [Safety Profile]
Poison by ingestion,
intraperitoneal, and intravenous routes.
Experimental reproductive effects. Mutation
data reported. An insect chemosterilant. See
also TIN COMPOUNDS. When heated to
decomposition it emits toxic fumes of Cl-. | [Hazardous Substances Data]
639-58-7(Hazardous Substances Data) | [Toxicity]
LD50 orally in Rabbit: 135 mg/kg |
| Hazard Information | Back Directory | [General Description]
White crystalline solid. Used as a rodent repellent, molluscicide, fungicide and insecticide. | [Reactivity Profile]
TRIPHENYLTIN CHLORIDE(639-58-7) is in the family of tin compounds widely used as stabilizers for plastics, additives to paint(as antifouling agents). Some have catalytic properties. Examples include butyl tin, dibutyl tin oxide. Their main hazard is associated with their high toxicity, in skin adsorption or inhalation. | [Air & Water Reactions]
Hydrolyzes to hydroxide in water. | [Health Hazard]
Toxic and irritating to the skin. Dermal exposure may lead to severe skin burns as well as renal failure and possible death. (Non-Specific--Tin Compounds, Organic) Target organs affected are central nervous system, eyes, liver, urinary tract, skin and the blood. | [Fire Hazard]
When heated to decomposition, TRIPHENYLTIN CHLORIDE emits toxic fumes of chlorides. Hydrolyzes to hydroxide in water. Stable when stored in dark with dry air. | [Uses]
Chlorotriphenylstannane is used in the synthesis of nanoparticles which bear triamide ligands. | [Definition]
ChEBI: An organotin compound that is triphenylstannane in which the hydrogen attached to tin is replaced by a chloro group. A fungicide used to control blights on potatoes, leaf spot diseases on sugar beet and anthracnose on beans. | [Purification Methods]
Purify it by distillation, followed by recrystallisation from MeOH by adding pet ether (b 30-60o), m 105-106o [Kozeschow et al. Chem Ber 67 1348 1934], or by crystallisation from Et2O, or 5 parts of EtOH and a small volume of pet ether. [Krause Chem Ber 51 914 1918.] It sublimes in a vacuum. [Beilstein 16 H 914, 16 I 540, 16 II 625, 16 III 1240, 16 IV 1606.] HIGHLY TOXIC. |
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