| Identification | More | [Name]
Benzyltriphenylphosphonium chloride | [CAS]
1100-88-5 | [Synonyms]
AURORA KA-1173
BENZYLIDENE(TRIPHENYL)PHOSPHORANE
(phenylmethyl)triphenyl-phosphoniuchloride
(phenylmethyl)triphenylphosphoniumchloride
Benzyltriphenylchlorophosphine
benzyltriphenylphosphonidechloride
benzyltriphenyl-phosphoniuchloride
Phosphonium,triphenyl(phenylmethyl)-,chloride
triphenyl(phenylmethyl)-phosphoniuchloride
triphenyl(phenylmethyl)phosphoniumchloride
Triphenyl(phenylmethyl)-phosphoniumchloride
BPP
Benzyltriphenylphosphoniumchloride,99%
BTPPCl: Benzyltriphenylphosphonium Chloride
Benzyltriphenylphosphonium chloride
BENZYL TRIPHENYL PHOSPHONIUM CHLORIDE(BTTPC)
Phosphonium, benzyltriphenyl, chloride
Triphenylbenzylidenephosphorane
benzyltriphenilphosphonium chloride | [EINECS(EC#)]
214-154-3 | [Molecular Formula]
C25H22ClP | [MDL Number]
MFCD02177525 | [Molecular Weight]
388.87 | [MOL File]
1100-88-5.mol |
| Chemical Properties | Back Directory | [Appearance]
white powder | [Melting point ]
≥300 °C (lit.) | [density ]
1.18 g/cm3 (20℃) | [vapor pressure ]
0.1 hPa | [Fp ]
300°C | [storage temp. ]
Store at <= 20°C. | [form ]
Crystalline Powder | [color ]
White to almost white | [Stability:]
Stable. Incompatible with strong oxidizing agents. | [Water Solubility ]
SOLUBLE | [Sensitive ]
Hygroscopic | [BRN ]
3599868 | [InChIKey]
USFRYJRPHFMVBZ-UHFFFAOYSA-M | [LogP]
-0.7 at 20℃ | [CAS DataBase Reference]
1100-88-5(CAS DataBase Reference) | [Storage Precautions]
Light sensitive;Moisture sensitive | [EPA Substance Registry System]
1100-88-5(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T,Xi | [Risk Statements ]
R25:Toxic if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R24/25:Toxic in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 2811 6.1/PG 2
| [WGK Germany ]
3
| [RTECS ]
TA2416500
| [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
29310095 | [Toxicity]
LD50 orally in Rabbit: 43 mg/kg |
| Hazard Information | Back Directory | [Chemical Properties]
white powder | [Uses]
Benzyltriphenylphosphonium Chloride was used as a reagent in the organic synthesis of several compounds including that of stabilised phosphonium ylides containing saturated oxygen heterocycles. Also used in the synthesis of novel substituted cis-stilbene derivatives which display antimicrobial activity. | [Application]
Benzyltriphenylphosphonium chloride can be used as a reactant for the synthesis of:
Platinum chloro-tetrazole complexes via azidation.
Trans-stilbenes and cinnamates via Wittig olefination.
Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment.
Pentiptycenes for use as light-driven molecular brakes.
Archipelago structures for formation of petroleum asphaltenes.
It is also used as a crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites.
Crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites
Reactant for synthesis of:
Platinum chloro tetrazole complexes via azidation
Trans-stilbenes and cinnamates via Wittig olefination
Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment
Pentiptycenes for use as light-driven molecular brakes
Reactant for formation of archipelago structures for formation of petroleum asphaltenes | [Flammability and Explosibility]
Notclassified | [Purification Methods]
Wash it with Et2O and crystallise it from EtOH (six-sided plates). It is hygroscopic and forms crystals with one molecule of H2O. [Michaelis & Soden Justus Liebigs Ann Chem 229 320 1885, Kr.hnke Chem Ber 83 291 1950, Beilstein 16 IV 994.] |
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