| Identification | More | [Name]
STANNOUS CHLORIDE | [CAS]
7772-99-8 | [Synonyms]
STANNOUS CHLORIDE
STANNOUS CHLORIDE, ACID, STRONGER
STANNOUS CHLORIDE REAGENT I
STANNOUS CHLORIDE REAGENT II
TIN(+2)CHLORIDE
TIN CHLORIDE
TIN DICHLORIDE
TIN(II) CHLORIDE
Anhydrous stannous chloride
C.I. 77864
c.i.77864
chlorured’etain(ii)
ci77864
dichlorotin
Fascat 2004
NCI-C02722
nci-co2722
Single muriate of tin
SnCl2
stannouschloride(anhydrous) | [EINECS(EC#)]
231-868-0 | [Molecular Formula]
Cl2Sn | [MDL Number]
MFCD00011241 | [Molecular Weight]
189.62 | [MOL File]
7772-99-8.mol |
| Chemical Properties | Back Directory | [Appearance]
Stannous chloride is a white crystalline solid. | [Melting point ]
246 °C(lit.)
| [Boiling point ]
652 °C(lit.)
| [density ]
3.95
| [vapor pressure ]
0Pa at 20℃ | [Fp ]
652°C | [storage temp. ]
Store at RT. | [solubility ]
H2O: soluble
| [form ]
powder
| [color ]
White | [Specific Gravity]
3.95 | [PH]
2.0 (100g/l, H2O, 20℃) | [Stability:]
Stable, but moisture sensitive. Incompatible with strong bases, strong oxidizing agents, reactive metals, hydrogen peroxide, water. | [Water Solubility ]
Soluble in water, alkalies, alcohol, methyl ethyl ketone, methyl acetate and acetone. | [Sensitive ]
Air Sensitive & Hygroscopic | [Merck ]
14,8783 | [Exposure limits]
ACGIH: TWA 2 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3 | [InChIKey]
AXZWODMDQAVCJE-UHFFFAOYSA-L | [LogP]
-2.15 at 20℃ | [Uses]
Stannous Chloride is an antioxidant and preservative that exists as
white or colorless crystals, being very soluble in water. it reacts read-
ily with oxygen, preventing its combination with chemicals and
foods which would otherwise result in discoloration and undesirable
odors. it is used for color retention in asparagus at less than 20 ppm.
it is also used in carbonated drinks. | [CAS DataBase Reference]
7772-99-8(CAS DataBase Reference) | [EPA Substance Registry System]
Tin dichloride (7772-99-8) |
| Safety Data | Back Directory | [Hazard Codes ]
C,Xi | [Risk Statements ]
R22:Harmful if swallowed.
R34:Causes burns.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3260 8/PG 3
| [WGK Germany ]
1
| [RTECS ]
XP8700000
| [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
28273990 | [Safety Profile]
Poison by ingestion,
intraperitoneal, intravenous, and
subcutaneous routes. Experimental
reproductive effects. Human mutation data
reported. Potentially explosive reaction with
metal nitrates. Violent reactions with
hydrogen peroxide, ethylene oxide,
hydrazine hydrate, nitrates, K, Na. Ignition
on contact with bromine trifluoride. A
vigorous reaction with calcium acetylide is
initiated by flame. When heated to
decomposition it emits toxic fumes of Cl-.
See also TIN COMPOUNDS. | [Hazardous Substances Data]
7772-99-8(Hazardous Substances Data) | [Toxicity]
LD50 in mice, rats (mg/kg): 1710.0, 2000.0 orally; 271.0, 316.0 i.p.; 34.8, 43.0 i.v. (Singh, Junnarkar) |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Hydrochloric acid-->Chlorine-->Tin | [Preparation Products]
Rhodamine 6G-->2-CHLORO-5-FLUOROISONICOTINIC ACID-->4-Aminobenzotrifluoride-->4-(4-AMINOPHENYL)MORPHOLIN-3-ONE-->PYRIDAZINE-3,4-DIAMINE-->Dimidium bromide-->2-Aminoquinoline-->5-BROMO-2-BENZOXAZOLINONE 97-->2-Amino-4-bromophenol-->H-GLY-AMC HBR-->4-Aminobenzamidine dihydrochloride-->3-Amino-6-chloropyridine-2-carboxylic acid-->5-AMINO-2-CHLORO-NICOTINIC ACID-->2-[3-(2-FURYL)PHENYL]-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE-->3,6-DICHLORO-4-HYDROXYPYRIDINE-2-CARBOXYLIC ACID-->2,3-DIAMINO-6-CHLOROPYRIDINE-->3-AMINO-6-CHLORO-4-PICOLINE-->5-Amino-2,3-dichloropyridine-->7-Hydroxygranisetron-->Bathophenanthroline-->3-HYDRAZINOPYRIDINE Dihydrochloride-->Stannous octoate-->Stannous sulfate-->5-AMINO-4,6-DIHYDROXYPYRIMIDINE-->Oxibendazole-->5-AMINO-1-(4-CHLOROPHENYL)-1H-PYRAZOLE-4-CARBONITRILE-->Disodium stannous citrate-->5-ACETYLAMINO-2-CHLORO-4-PICOLINE |
| Hazard Information | Back Directory | [General Description]
Crystalline mass or flaky solid with a fatty appearance. Density 3.95 g/cm3. Melting point 247°C. Burns, but may be difficult to ignite. Toxic by ingestion. Irritates skin and eyes. Used in the manufacture of dyes, pharmaceuticals and as a tanning agent. | [Reactivity Profile]
STANNOUS CHLORIDE is a powerful reducing agent. Can react violently with oxidizing agents. Undergoes flaming reaction with bromine trifluoride [Mellor 2 Supp. 1:164 1956]. Catalyzes the exothermic rearrangement and polymerization of ethylene oxide [J. Soc. Chem. Ind. 68:179 1949]. Mixtures with calcium carbide can be ignited with a match, and the reaction proceeds with incandescence [Mellor 7:430 1946-47]. Reacts with hydrazine hydrate to give stannous dihydrazine chloride which decomposes explosively when heated [Mellor 7:430 1946-47]. Undergoes a strongly exothermic reaction with aqueous solutions of hydrogen peroxide having concentration exceeding 3%) [Chem. & Ind., 1949, 657]. | [Air & Water Reactions]
Water soluble. | [Health Hazard]
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. | [Potential Exposure]
Stannous chloride is used as a dye, pigment, and printing ink; in making chemicals; chemical preservatives; food additives; polymers, textiles, glass, silvering mirrors. | [Fire Hazard]
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. | [First aid]
Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy. | [Shipping]
UN3260 Corrosive solid, acidic, inorganic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. | [Incompatibilities]
A strong reducing agent. Reacts violently with oxidants. Reacts violently with bromine trifluoride; potassium, hydrazine hydrate, sodium, sodium peroxide; ethylene oxide; and nitrates. Keep away from moisture, sources of oxygen, and combustible materials. | [Chemical Properties]
Also known as tin chloride, tin crystals, tin dichloride and tin salts, SnCl2 is white crystals, soluble in water, alcohol, and alkalies, oxidized in air to the oxychloride, that melt at 247°C. Used as a chemical intermediate, reducing agent, and ink-stain remover, and for silvering mirrors.
| [Chemical Properties]
Stannous chloride is a white crystalline solid. | [Definition]
ChEBI: An inorganic chloride that has formula Cl2Sn. | [Hazard]
Irritant to skin, use in foods restricted to
0.0015%, as tin. | [Purification Methods]
Analytical reagent grade stannous chloride dihydrate is dehydrated by adding it slowly to vigorously stirred, redistilled acetic anhydride (120g salt per 100g of anhydride) in a fume cupboard. After ca an hour, the anhydrous SnCl2 is filtered on to a sintered-glass or Büchner funnel, washed free from acetic acid with dry Et2O (2 x 30mL), and dried under vacuum. It is stored in a sealed container. [Stephen J Chem Soc 2786 1930, Williams Org Synth Coll Vol III 627 1955.] |
| Questions and Answers (Q&A) | Back Directory | [Physical properties]
White orthogonal crystal; density 3.90 g/cm3; melts at 247°C; vaporizes at 623°C; vapor pressure 1 torr at 316°C, 5 torr at 366°C and 20 torr at 420°C; soluble in water, ethanol, acetone and ether; insoluble in xylene and mineral spirits.
TIN(II) CHLORIDE 937The dihydrate, SnCl2•2H2O, is a white monoclinic crystalline substance; density 2.71 g/cm3; absorbs oxygen from air forming an oxychloride; melts at 37°C on rapid heating; decomposes on strong heating; very soluble in water; forms an insoluble basic salt with excess water; very soluble in hydrochloric acid; soluble in caustic soda solution, ethanol and ethyl acetate.
| [Uses]
Tin (II) chloride is a strong reducing agent and is used in many industrial processes, such as manufacturing dyes, phosphors, and polymers. The compound is a major ingredient in acid tin plating baths. Other uses are a mordant in dyeing; an additive to lubricating oil to prevent sludging; a stablizier for perfume in soaps; in removing ink stains; a sensitizing agent for glass, paper, and plastics; and a soldering flux. Tin(II) chloride is used for preparing a number of tin(II) salts. It is a catalyst in many organic reactions. It is a common laboratory reagent.
| [Preparation]
Tin(II) chloride is prepared by dissolving tin in hydrochloric acid followed by evaporation of the solution and crystallization.
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