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ChemicalBook CAS DataBase List Sodium 3-methyl-2-oxobutanoate
3715-29-5

Sodium 3-methyl-2-oxobutanoate synthesis

3synthesis methods
-

Yield:3715-29-5 92.85%

Reaction Conditions:

with sodium ethanolate in butan-1-ol at 40; under 600.06 Torr; for 2 h;Solvent;Temperature;Pressure;

Steps:

4.2; 5.2 (2) Preparation of α-ketovaline salt

Add 27.9g of sodium ethoxide (0.410mol) and 9.60g of isopropylidene hydantoin (0.0686mol) to 50mL of butanol; the temperature is raised to 40°C under slight negative pressure (pressure is -0.08MPa), and the reaction time is 2 hours; another container holds water for collecting the ammonia gas produced to prepare ammonia water; after the reaction is completed, the temperature is lowered, and the temperature of the reaction solution is controlled to be 10 ° C, incubated for 2 hours, filtered, and dried to obtain 8.79 g of sodium ketovaline. . The yield is 92.85%, and the purity is more than 99.91%.

References:

CN113735775,2021,A Location in patent:Paragraph 0038; 0041

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