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ChemicalBook--->CAS DataBase List--->15529-49-4

15529-49-4

15529-49-4 Structure

15529-49-4 Structure
IdentificationMore
[Name]

Tris(triphenylphosphine)ruthenium(II) chloride
[CAS]

15529-49-4
[Synonyms]

DICHLOROTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENATE (II)
DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
DICHLOROTRIS(TRIPHENYLPHOSPHINO)RUTHENIUM (II)
RUTHENIUM DICHLOROTRIS(TRIPHENYLPHOSPHINE)
RUTHENIUM(II)-TRIS(TRIPHENYLPHOSPHINE) DICHLORIDE
TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(2) DICHLORIDE
TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CHLORIDE
TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) DICHLORIDE
dichlorotris(triphenylphosphine)ruthenium
Dichlorotris(triphenylphosphine)ruthenium(II),99%
dichlorotris(triphenylphosphine)ruthenium(ii), premion
DICHLOROTRIS(TRIPHENYLPHOSPHINO)RUTHENIUM(II) (10% RU)
TRIS(TRIPHENYLPHOSPHINE) RUTHENIUM II
Dichlorotris(triphenylphosphine)ruthenium(II), Premion(R), 99.95% (metals basis), Ru 10.2% min
Dichlorotris(triphenylphosphine)ruthenium(II) Dissociates in solution
Dichlorotris(triphenylphosphine)ruthenium(II), Premion, 99.95% (metals basis), Ru 10.2% min
Ruthenium chloride triphenyl phosphine
Dichlorotris(triphenylphosphine)ruthenium(II), Ruthenium(II)-tris(triphenylphosphine) dichloride
[EINECS(EC#)]

239-569-7
[Molecular Formula]

C54H45Cl2P3Ru
[MDL Number]

MFCD00013077
[Molecular Weight]

958.83
[MOL File]

15529-49-4.mol
Chemical PropertiesBack Directory
[Appearance]

black crystals
[Melting point ]

159 °C
[storage temp. ]

Refrigerator
[solubility ]

Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene
[form ]

Solution
[color ]

Clear
[Water Solubility ]

insoluble
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[Sensitive ]

Air & Moisture Sensitive
[BRN ]

4935939
[InChI]

InChI=1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
[InChIKey]

QUVLSIIMVTXAPD-UHFFFAOYSA-M
[SMILES]

P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Ru](Cl)Cl
[CAS DataBase Reference]

15529-49-4(CAS DataBase Reference)
[Storage Precautions]

Air sensitive;Store under inert gas;Moisture sensitive
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R20/21:Harmful by inhalation and in contact with skin .
[Safety Statements ]

S36/37:Wear suitable protective clothing and gloves .
S22:Do not breathe dust .
[RIDADR ]

2811
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

28439000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Tetrahydrofuran-->Dichloromethane-->Isopropyl alcohol-->Hydrazinium hydroxide solution-->Triphenylphosphine-->Lithium-->Ruthenium(III) chloride hydrate
Hazard InformationBack Directory
[Chemical Properties]

black crystals
[Uses]

Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System
[Uses]

suzuki reaction
Spectrum DetailBack Directory
[Spectrum Detail]

Tris(triphenylphosphine)ruthenium(II) chloride(15529-49-4)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Tris(triphenylphosphine)ruthenium(II) chloride, 98%(15529-49-4)
[Alfa Aesar]

Dichlorotris(triphenylphosphine)ruthenium(II), Premion, 99.95% (metals basis), Ru 10.2% min(15529-49-4)
[Sigma Aldrich]

15529-49-4(sigmaaldrich)
[TCI AMERICA]

Tris(triphenylphosphine)ruthenium(II) Dichloride,>90.0%(T)(15529-49-4)
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