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Analytical Chemistry

Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Structure Chemical Name CAS MF
17ALPHA(H)-22,29,30-TRISNORHOPANE 17ALPHA(H)-22,29,30-TRISNORHOPANE 53584-59-1 C27H46
NITRATE IONOPHORE - COCKTAIL A NITRATE IONOPHORE - COCKTAIL A
Tube-type  sprayer Tube-type sprayer
Carbon  dioxide  in  nitrogen Carbon dioxide in nitrogen
Aluminum  multi-plate  racks Aluminum multi-plate racks
Ethanol  absolute,  (isotope  ratio) Ethanol absolute, (isotope ratio) C2H6O
EPA  8270  Organophosphorus  Pesticide  Mix  1 EPA 8270 Organophosphorus Pesticide Mix 1
Cellulose  fibres  on  TLC-plates Cellulose fibres on TLC-plates
Thallium  205Tl  (certified  for  isotope  abundance  ratio) Thallium 205Tl (certified for isotope abundance ratio)
EPA  505/525  Update  Pesticides  Mix  B EPA 505/525 Update Pesticides Mix B
EPA  610  Polynuclear  Aromatic  Hydrocarbons  Mixture EPA 610 Polynuclear Aromatic Hydrocarbons Mixture
Ionic  strength  adjustor  solution  for  sodium  electrode  (21%  NH4Cl,  14%  NH4OH) Ionic strength adjustor solution for sodium electrode (21% NH4Cl, 14% NH4OH)
EPA  Chlorinated  Hydrocarbon  Mix EPA Chlorinated Hydrocarbon Mix
LC  column  replacement  bed  supports LC column replacement bed supports
Glucose  (isotope  ratio) Glucose (isotope ratio)
Cuvette  mixer Cuvette mixer
3,6,3-Nonylphenol-13C6,  363-NP-13C6,  4-(1-Ethyl-1,4-dimethylpentyl)phenol-13C6  (ring-13C6) 3,6,3-Nonylphenol-13C6, 363-NP-13C6, 4-(1-Ethyl-1,4-dimethylpentyl)phenol-13C6 (ring-13C6) 1173020-38-6 C15H24O
Snap-in  micro-cavity  cell  holder Snap-in micro-cavity cell holder
EPA  8270  Chloronated  Hydrocarbons  Mix EPA 8270 Chloronated Hydrocarbons Mix
2-[(2,6-Diethylphenyl)(butoxymethyl)amino]-2-oxo-ethanesulfonic  acid  sodium  salt 2-[(2,6-Diethylphenyl)(butoxymethyl)amino]-2-oxo-ethanesulfonic acid sodium salt 1173022-75-7 C17H26NNaO5S
Potassium  chloride  fertilizer  (elemental  composition) Potassium chloride fertilizer (elemental composition)
4-(1,1,3,3-Tetramethylbutyl)phenol-13C6,  4-tert-OP-13C6 4-(1,1,3,3-Tetramethylbutyl)phenol-13C6, 4-tert-OP-13C6 1173020-24-0 C14H22O
BRAND  UV  cuvettes BRAND UV cuvettes
Moroccan  phosphate  rock  (trace  elements) Moroccan phosphate rock (trace elements)
Polychlorodibenzo-p-dioxins  (PCDDs)  and  polychlorodibenzofurans  (PCDFs)  solution Polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) solution
Magnesium  ionophore  IV  -  membrane  A Magnesium ionophore IV - membrane A
Rubidium-87Rb  solution Rubidium-87Rb solution Rb
Human  serum  (17β-estradiol,  low  level) Human serum (17β-estradiol, low level)
Chlorinated  Pesticides  Mix Chlorinated Pesticides Mix
Electrode  connecting  wire Electrode connecting wire
GVO  Standard  ERM-BF423,  Maize  MIR604 GVO Standard ERM-BF423, Maize MIR604
EPA  CLP  SOW  OLM04  Volatiles  Mix EPA CLP SOW OLM04 Volatiles Mix
MISA  Group  19  Base-Neutral  Extractables  Mix  B MISA Group 19 Base-Neutral Extractables Mix B
EPA  Phase  V  Volatile  Organic  Compounds  Mix  9 EPA Phase V Volatile Organic Compounds Mix 9
Ionic  strength  adjustor  buffer  solution  for  fluoride  electrode  (1.4%  HOAc,  8.2%  NaOAc,  5.8%  NaCl,  trace  CDTA) Ionic strength adjustor buffer solution for fluoride electrode (1.4% HOAc, 8.2% NaOAc, 5.8% NaCl, trace CDTA)
Natural  milk  powder  (PCBs  ) Natural milk powder (PCBs )
3,3μ,4,4μ,5-PentaBDE,  3,3μ,4,4μ,5-Pentabromodiphenyl  ether  solution,  PBDE  126 3,3μ,4,4μ,5-PentaBDE, 3,3μ,4,4μ,5-Pentabromodiphenyl ether solution, PBDE 126 366791-32-4 C12H5Br5O
Pesticide  Mix  B-2 Pesticide Mix B-2
CEN  PCB  Congener  Mix-1 CEN PCB Congener Mix-1
Qwik  Cell  body Qwik Cell body
LALLS  viscosity  validation  set  polystyrene  Mp  9μ000-800μ000  in  TCB  certified  according  to  DIN LALLS viscosity validation set polystyrene Mp 9μ000-800μ000 in TCB certified according to DIN
N,Nμ-(4-Methyl-1,3-phenylene)bis{4-(2-pyridinyl)-1-piperazinecarboxamide}  (derivative  of  2,4-TDIP) N,Nμ-(4-Methyl-1,3-phenylene)bis{4-(2-pyridinyl)-1-piperazinecarboxamide} (derivative of 2,4-TDIP)
EPA  TO-1  Toxic  Organic  Mix  1B EPA TO-1 Toxic Organic Mix 1B
Arsenic  test  paper Arsenic test paper
Superphosphate  (various  parameters) Superphosphate (various parameters)
Fame  22:4n-6 Fame 22:4n-6 C23H38O2
EPA  8270  Add-On  Mix EPA 8270 Add-On Mix
Nucleosides  Test  Mix Nucleosides Test Mix
Nimonic  75  for  ambient  temperature  tensile  properties Nimonic 75 for ambient temperature tensile properties
Polished  IR  crystal  window Polished IR crystal window
Preval  spray  unit Preval spray unit
Sodium  hydroxide  on  carrier Sodium hydroxide on carrier HNaO
Econo-Cards Econo-Cards
Bovine  urine  (diethylstilboestrol  blank) Bovine urine (diethylstilboestrol blank)
PESTICIDE SURROGATE SPIKE MIX PESTICIDE SURROGATE SPIKE MIX
HYDRANAL-COULOMAT OIL HYDRANAL-COULOMAT OIL
NICKEL TEST STICKS QUANTOFIX NICKEL TEST STICKS QUANTOFIX
HYDRANAL-MOISTURE TESTKIT HYDRANAL-MOISTURE TESTKIT
AQUANAL-PROFESSIONAL AMMONIA NO. 1 AQUANAL-PROFESSIONAL AMMONIA NO. 1
AQUANAL-PROFESSIONAL DPD NO.3 AQUANAL-PROFESSIONAL DPD NO.3
AQUANAL-PROFESSIONAL COPPER NO.2 AQUANAL-PROFESSIONAL COPPER NO.2
AQUANAL-PROFESSIONAL GLYCINE AQUANAL-PROFESSIONAL GLYCINE
AQUANAL-PROFESSIONAL VARIO H SULFATE AQUANAL-PROFESSIONAL VARIO H SULFATE
SUGAR ALCOHOL KIT SUGAR ALCOHOL KIT
VOLATILE ORGANIC CONTAMINANTS - MIX 2 VOLATILE ORGANIC CONTAMINANTS - MIX 2
FATTY ACID METHYL ESTERS FATTY ACID METHYL ESTERS
LITHIUM ATOMIC ABSORPTION STANDARD SOLUTION 1,000 ΜG/ML LI IN 1 WT. % HCL (EXACT LI CONCENTRATION ON LABEL) LITHIUM ATOMIC ABSORPTION STANDARD SOLUTION 1,000 ΜG/ML LI IN 1 WT. % HCL (EXACT LI CONCENTRATION ON LABEL) Li
MOLYBDENUM ICP/DCP STANDARD SOLUTION MOLYBDENUM ICP/DCP STANDARD SOLUTION Mo
PRESSLOK DEMOUNTABLE CELL HOLDER PRESSLOK DEMOUNTABLE CELL HOLDER
CLEAN SANDY SOIL CLEAN SANDY SOIL
GLYPHOSATE-3-13C GLYPHOSATE-3-13C 287399-30-8 C3H8NO5P
HEATING OIL TEST MARKER 2 HEATING OIL TEST MARKER 2
SODIUM IONOPHORE I - COCKTAIL A SODIUM IONOPHORE I - COCKTAIL A
LAURIC ACID-1,2,3,4-13C4 LAURIC ACID-1,2,3,4-13C4 287111-14-2 C12H24O2
TUERK SOLUTION TUERK SOLUTION
TRACERS IN ANHYDROUS BUTTER FAT TRACERS IN ANHYDROUS BUTTER FAT
5-pentadecylresorcinol 5-pentadecylresorcinol 3158-56-3 C21H36O2
4-(1-ethyl-1-methylhexyl)phenol 4-(1-ethyl-1-methylhexyl)phenol 52427-13-1 C15H24O
5(E),9(Z),12(Z)-Octadecatrienoicacid(Columbinic)MethylEster 5(E),9(Z),12(Z)-Octadecatrienoicacid(Columbinic)MethylEster
MethylDocosatrienoate(13c,16c,19c) MethylDocosatrienoate(13c,16c,19c)
Fresh  water  (nitrate,  high  level) Fresh water (nitrate, high level)
Ground  water  (Br,  high  level) Ground water (Br, high level)
Buffer  solution  pH  13.0  (20.C) Buffer solution pH 13.0 (20.C)
EPA  506  Phthalate  Esters  Mix  1 EPA 506 Phthalate Esters Mix 1
Genomic  DNA  of  Campylobacter  jejuni  (NCTC  11351) Genomic DNA of Campylobacter jejuni (NCTC 11351)
Gas  oil  (0.091%  S) Gas oil (0.091% S)
Magnesium,  24Mg  (certified  for  isotope  abundance  ratio) Magnesium, 24Mg (certified for isotope abundance ratio)
Fumonisin  B1-13C34  solution Fumonisin B1-13C34 solution 1217458-62-2 13C34H59NO15
Oxygen  in  nitrogen Oxygen in nitrogen
CARB  Method  1004  DNPH  Mix  2 CARB Method 1004 DNPH Mix 2
Acid  Herbicide  Mix Acid Herbicide Mix
Econo-Press  only Econo-Press only
Reversed  Phase  Test  Mix  2 Reversed Phase Test Mix 2
Fumonisin  Mixture Fumonisin Mixture
TLC-PET-foils  Polyamide  6 TLC-PET-foils Polyamide 6
EPA  TCLP  Pesticides  Mix EPA TCLP Pesticides Mix
Redox  standard Redox standard
Naphthenes  Mix Naphthenes Mix
Bacterial  Acid  Methyl  Ester  (BAME)  Mix Bacterial Acid Methyl Ester (BAME) Mix
Acidity  Test  Mix Acidity Test Mix
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