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Methyl-3-oxo-2-pentylcyclopentanacetat

Methyl dihydrojasmonate Struktur
24851-98-7
CAS-Nr.
24851-98-7
Bezeichnung:
Methyl-3-oxo-2-pentylcyclopentanacetat
Englisch Name:
Methyl dihydrojasmonate
Synonyma:
hedione;MDJ;HEDION;kharismal;Einecs 246-495-9;Methyl epi-dihydrojasmonate;DIHYDROJASMONIC ACID METHYL ESTER;Methyl-3-oxo-2-pentylcyclopentanacetat;methyl(2-pentyl-3-oxocyclopentyl)acetate;3-oxo-2-pentyl-cyclopentaneaceticacimethylester
CBNumber:
CB9377525
Summenformel:
C13H22O3
Molgewicht:
226.31
MOL-Datei:
24851-98-7.mol

Methyl-3-oxo-2-pentylcyclopentanacetat Eigenschaften

Siedepunkt:
110 °C/0.2 mmHg (lit.)
Dichte
0.998 g/mL at 25 °C (lit.)
Dampfdruck
0.21Pa at 25℃
FEMA 
3408 | METHYL DIHYDROJASMONATE
Brechungsindex
n20/D 1.459(lit.)
Flammpunkt:
>230 °F
storage temp. 
2-8°C
L?slichkeit
H2O: insoluble
Aggregatzustand
Oil
Farbe
Clear Colorless
Geruch (Odor)
at 100.00 %. floral oily jasmin green lactonic tropical natural
Geruchsart
floral
Wasserl?slichkeit
399.8mg/L(25 ºC)
Merck 
14,6052
JECFA Number
1898
InChIKey
KVWWIYGFBYDJQC-GHMZBOCLSA-N
LogP
2.93 at 22℃
CAS Datenbank
24851-98-7(CAS DataBase Reference)
NIST chemische Informationen
Cyclopentaneacetic acid, 3-oxo-2-pentyl-, methyl ester(24851-98-7)
EPA chemische Informationen
Methyl 3-oxo-2-pentyl-cyclopentaneacetate (24851-98-7)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
S-S?tze: 23-24/25
WGK Germany  2
RTECS-Nr. GY2453800
HS Code  29183000
Toxizit?t LD50 (g/kg): >5 orally in rats; >5 dermally in rabbits (Food Chem. Toxicol.)
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitssch?dlich bei Verschlucken. Akute Toxizit?t oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
Sicherheit
P261 Einatmen von Staub vermeiden.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

Methyl-3-oxo-2-pentylcyclopentanacetat Chemische Eigenschaften,Einsatz,Produktion Methoden

S-S?tze Betriebsanweisung:

S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
S24/25:Berührung mit den Augen und der Haut vermeiden.

Beschreibung

Methyl dihydrojasmonate has a powerful sweet-floral, jasminelike, somewhat fruity odor. This is the odoriferous component in jasmine oil (Jasminum gradiflorum L.). May be prepared by condensation of 2-pentyl-2-cyclopenten-l-one with ethyl malonate, followed by hydrolysis, decarboxylation, and methylation.

Chemische Eigenschaften

Methyl dihydrojasmonate has a powerful sweet-floral, jasmine-like, somewhat fruity odor. This compound is the odoriferous component of jasmine oil (Jasminum gradiflorum L.)

Occurrence

Reported found in jasmine oil (Jasminum gradiflorum L.) and black tea

Verwenden

Methyl (3-Oxo-2-pentylcyclopentyl)acetate is used in the preparation of hydrogels as delivery systems for the slow release of bioactive carbonyl derivatives.

synthetische

By condensation of 2-pentyl-2-cyclopenten-1-one with ethyl malonate, followed by hydrolysis, decarboxylation and methylation

Allgemeine Beschreibung

Methyl dihydrojasmonate is a fragrance ingredient mainly used in the perfumes, fragrance formulations, personal care and cosmetic products. It occurs naturally in pine honey and rhododendron honey.

Handelsname

Claigeon®, Cepionate®(Nippon Zeon),Hedione®,Hedione®HC (Firmenich), Kharismal® (IFF).

Methyl-3-oxo-2-pentylcyclopentanacetat Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Methyl-3-oxo-2-pentylcyclopentanacetat Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 420)Lieferanten
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24851-98-7(Methyl-3-oxo-2-pentylcyclopentanacetat)Verwandte Suche:


  • (2-Pentyl-3-oxocyclopentyl)acetic acid methyl ester
  • 2-Amyl-3-oxo-1-cyclopentaneacetic acid methyl ester
  • Dihydrojasmonic acid methyl
  • methyl3-oxo-2-pentylcyclopentaneacetate
  • 2-AMYLCYCLOPENTAN-1-ONE-3-ACETIC ACID METHYL ESTER
  • METHYL-(2-PENTYL-3-OXOCYCLOPENTAN-1-YL) ACETATE
  • METHYL 3-OXO-2-PENTYL-1-CYCLOPENTANEACETATE
  • METHYL (3-OXO-2-PENTYLCYCLOPENTYL)ACETATE
  • METHYL DIHYDROJASMONATE
  • METHYLDIHYDRO JASMONATE (CIS)
  • FEMA 3408
  • Methyl epi-dihydrojysmonate
  • 3-(METHYLTHIO)-1-PROPANOL 98+%
  • 3-Oxo-2-pentylcyclopentaneaceticacidmethylester
  • Claigeon(R),Cepionate(R)orSuperCepionate(R)
  • Methyldihydrojasonate
  • hedione(r) (firmenich)
  • MDJ SUPER
  • CAIGEON 98%
  • CAIGEON A.K.A. CYCLOPENTANEACETIC ACID, 3-OXO-2-
  • CEPIONATE 95%
  • Cyclopentaneaceticacid,3-oxo-2-pentyl-,methylester
  • CEPIONATE A.K.A. METHYL EPI-DIHYDROJASMONATE
  • (3-Oxo-2-pentyl-cyclopentyl)-acetic acid methyl ester
  • Methyl Dihydrojasmonate (cis- and trans- mixture)
  • METHYL DIHYDROJASMONATE HC
  • Fema no. 3408
  • (±)-9,10-DIHYDROJASMONIC ACID METHYL ESTER (MeDJA)
  • Methyl DihydrojasMonate 
  • Methyl dihydrojasMonate(MDJ)
  • 2-Amylcyclopentan-1-one-3-acetic Acid Methyl Ester Dihydrojasmonic Acid Methyl Ester Methyl 3-Oxo-2-pentyl-1-cyclopentaneacetate
  • Methyl dihydrojasMonate (cis-and trans-Mixture)
  • Methyl dihydrojasmonate, mixture of cis and trans
  • Methyl dihydrojasmonate Methyl (3-oxo-2-pentylcyclopentyl)acetate
  • Methyl dihydrojasmonate(EDC)
  • Nano Liposomal sodium tetrahydrojasmonate
  • methyl dihydrojasmonate/Hedione
  • Methyl Dihydrojasmonate (cis- and trans- mixture)>
  • Methyl dihydrojasmonate(EDC),≥98%
  • Methyl dihydrojasmonate USP/EP/BP
  • Hedione (methyl dihydrojasmonate, mdj)
  • C13H22O3 Methyl dihydrojasmonate 24851-98-7
  • HEDION
  • hedione
  • kharismal
  • MDJ
  • 3-oxo-2-pentyl-cyclopentaneaceticacimethylester
  • Methyl epi-dihydrojasmonate
  • DIHYDROJASMONIC ACID METHYL ESTER
  • Methyl-3-oxo-2-pentylcyclopentanacetat
  • Einecs 246-495-9
  • methyl(2-pentyl-3-oxocyclopentyl)acetate
  • Polymaleic acid 26099-09-2
  • Methyl dihydrojasmonate (mixture of isomers)
  • Methyldihydrojasmonate(mixtureofcis-andtrans-isomers
  • High Cis Hedione
  • Methyl dihydrojasmonate in isooctane
  • Methyl dihydrojasmonate, mixture of cis and
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