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Vinylacetat

Vinyl acetate Struktur
108-05-4
CAS-Nr.
108-05-4
Bezeichnung:
Vinylacetat
Englisch Name:
Vinyl acetate
Synonyma:
VAM;VINYL ACETATE MONOMER;Ethenyl acetate;Ethenyl ethanoate;Vinylacetate 1;ethenylacetate;Vinyl Acetate(VAM);aceticacidethenylester;VyAc;Vinyle
CBNumber:
CB7852732
Summenformel:
C4H6O2
Molgewicht:
86.09
MOL-Datei:
108-05-4.mol

Vinylacetat Eigenschaften

Schmelzpunkt:
-93 °C (lit.)
Siedepunkt:
72-73 °C (lit.)
Dichte
0.934 g/mL at 25 °C (lit.)
Dampfdichte
3 (vs air)
Dampfdruck
88 mm Hg ( 20 °C)
Brechungsindex
n20/D 1.395(lit.)
Flammpunkt:
20 °F
storage temp. 
2-8°C
L?slichkeit
20g/l
Aggregatzustand
Liquid
Farbe
Clear colorless to almost colorless
PH
7 (20g/l, H2O, 20℃)
Explosionsgrenze
2.6-13.4%(V)
Wasserl?slichkeit
23 g/L (20 ºC)
Sensitive 
Light Sensitive
Merck 
14,9992
BRN 
1209327
Henry's Law Constant
4.81 (calculated, Howard, 1989)
Expositionsgrenzwerte
NIOSH REL: 15-min ceiling 4 ppm (15 mg/m3); ACGIH TLV: TWA 10 ppm, STEL 15 ppm (adopted).
Dielectric constant
4.5(23℃)
Stabilit?t:
Stable. Highly flammable. Incompatible with acids, bases, oxidizing agents, peroxides, chlorosulfonic acid, ethylene imine, hydrochloric acid, oleum, nitric acid, sulfuric acid, 2-aminoethanol, light. Susceptible to polymerization; commercial product may be stabilized by the addition of hydroquinone.
LogP
0.73 at 20℃
CAS Datenbank
108-05-4(CAS DataBase Reference)
IARC
2B (Vol. Sup 7, 63) 1995
NIST chemische Informationen
Acetic acid ethenyl ester(108-05-4)
EPA chemische Informationen
Vinyl acetate (108-05-4)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher F,T,Xn
R-S?tze: 11-39/23/24/25-23/24/25-36-20/21/22-40-37-20
S-S?tze: 16-23-29-33-45-36/37-7-9
RIDADR  UN 1301 3/PG 2
OEL Ceiling: 4 ppm (15 mg/m3) [15-minute]
WGK Germany  2
RTECS-Nr. AK0875000
Selbstentzündungstemperatur 801 °F
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29153200
HS Code  29333999
Giftige Stoffe Daten 108-05-4(Hazardous Substances Data)
Toxizit?t LD50 orally in rats: 2.92 g/kg (Smyth, Carpenter)
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H225 Flüssigkeit und Dampf leicht entzündbar. Entzündbare Flüssigkeiten Kategorie 2 Achtung GHS hazard pictogramssrc="/GHS02.jpg" width="20" height="20" /> P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H332 Gesundheitssch?dlich bei Einatmen. Akute Toxizit?t inhalativ Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P261, P271, P304+P340, P312
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
H351 Kann vermutlich Krebs verursachen. Karzinogenit?t Kategorie 2 Warnung P201, P202, P281, P308+P313, P405,P501
H412 Sch?dlich für Wasserorganismen, mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 3 P273, P501
Sicherheit
P202 Vor Gebrauch alle Sicherheitshinweise lesen und verstehen.
P210 Von Hitze, hei?en Oberfl?chen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.
P233 Beh?lter dicht verschlossen halten.
P273 Freisetzung in die Umwelt vermeiden.
P308+P313 BEI Exposition oder falls betroffen: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen.

Vinylacetat Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD

FARBLOSE, LEICHTBEWEGLICHE FLüSSIGKEIT MIT CHARAKTERISTISCHEM GERUCH.

PHYSIKALISCHE GEFAHREN

Die D?mpfe sind schwerer als Luft und k?nnen sich am Boden ausbreiten. Fernzündung m?glich.

CHEMISCHE GEFAHREN

Kann leicht polymerisieren beim Erw?rmen oder unter Einfluss von Licht oder Peroxiden. Feuer- und Explosionsgefahr. Reagiert sehr heftig mit starken Oxidationsmitteln.

ARBEITSPLATZGRENZWERTE

TLV: 10 ppm (als TWA); 15 ppm (als STEL) Krebskategorie A3 (best?tigte krebserzeugende Wirkung beim Tier mit unbekannter Bedeutung für den Menschen); (ACGIH 2005).
MAK: Krebserzeugend Kategorie 3A; (DFG 2005).

AUFNAHMEWEGE

Aufnahme in den K?rper durch Inhalation und durch Verschlucken.

INHALATIONSGEFAHREN

Beim Verdampfen bei 20°C kann sehr schnell eine gesundheitssch?dliche Kontamination der Luft eintreten.

WIRKUNGEN BEI KURZZEITEXPOSITION

WIRKUNGEN BEI KURZZEITEXPOSITION:
Die Substanz reizt die Augen, die Haut und die Atemwege. M?glich sind Auswirkungen auf die Lunge mit nachfolgenden Gewebesch?den.

LECKAGE

Ausgelaufene Flüssigkeit in abdichtbaren Beh?ltern sammeln. Reste mit Sand oder inertem Absorptionsmittel aufnehmen und an einen sicheren Ort bringen. NICHT in die Kanalisation spülen. Pers?nliche Schutzausrüstung: Umgebungsluftunabh?ngiges Atemschutzger?t.

R-S?tze Betriebsanweisung:

R11:Leichtentzündlich.
R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.

S-S?tze Betriebsanweisung:

S16:Von Zündquellen fernhalten - Nicht rauchen.
S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
S29:Nicht in die Kanalisation gelangen lassen.
S33:Ma?nahmen gegen elektrostatische Aufladungen treffen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S7:Beh?lter dicht geschlossen halten.

Beschreibung

Vinyl acetate monomer (VAM) is a colourless liquid, immiscible or slightly soluble in water. VAM is a flammable liquid. VAM has a sweet, fruity smell (in small quantities), with sharp, irritating odour at higher levels. VAM is an essential chemical building block used in a wide variety of industrial and consumer products. VAM is a key ingredient in emulsion polymers, resins, and intermediates used in paints, adhesives, coatings, textiles, wire and cable polyethylene compounds, laminated safety glass, packaging, automotive plastic fuel tanks, and acrylic fibres. Vinyl acetate is used to produce polyvinyl acetate emulsions and resins. Very small residual levels of vinyl acetate have been found present in products manufactured using VAM, such as moulded plastic items, adhesives, paints, food packaging containers, and hairspray.

Chemische Eigenschaften

Vinyl acetate is a colorless, flammable liquid with a pungent odor. The odor threshold is 0.12 ppm 0.3 ppm (NY, NJ).it is the precursor to polyvinyl acetate, an important polymer in industry.

Physikalische Eigenschaften

Colorless, watery liquid with a pleasant, fruity odor. Experimentally determined detection and recognition odor threshold concentrations were 400 μg/m3 (120 ppbv) and 1.4 mg/m3 (400 ppbv), respectively (Hellman and Small, 1974).

Verwenden

Vinyl acetate is primarily used to produce polyvinyl acetate emulsions and polyvinyl alcohol. The principal use of these emulsions has been in adhesives, paints, textiles, and paper products.

synthetische

The major industrial route involves the reaction of ethylene and acetic acid with oxygen in the presence of a palladium catalyst.
Ethylene + acetic acid + 1/2 O2 → Vinyl acetate +H2O
But by products are also generated:
Ethylene + 3 O2 → 2CO2 + 2H2O
Vinyl acetate is also prepared by the gas-phase addition of acetic acid to acetylene.

Vorbereitung Methode

Vinyl acetate is an industrial chemical that is produced in large amounts in the United States. The worldwide production capacity of vinyl acetate monomer (VAM) was estimated at 6,154,000 tonnes/annum in 2007, with most capacity concentrated in the United States (1,585,000 all in Texas), China (1,261,000), Japan (725,000) and Taiwan (650,000) . The average list price for 2008 was $1600/tonne. Celanese is the largest producer (ca 25% of the worldwide capacity), while other significant producers include China Petrochemical Corporation (7 %), Chang Chun Group (6%) and LyondellBasell (5%).
It is a key ingredient in furniture-glue.

Reaktionen

Vinyl acetate undergoes many of the reactions anticipated for an alkene and an ester. Bromine adds to give the dibromide. Hydrogen halides add to give 1-haloethyl acetates, which cannot be generated by other methods because of the non - availability of the corresponding halo-alcohols. Acetic acid adds in the presence of palladium catalysts to give ethylidene diacetate, CH3CH(OAc)2. It undergoes transesterification with a variety of carboxylic acids.The alkene also undergoes Diels - Alder and 2 + 2 cycloadditions.

Allgemeine Beschreibung

Vinyl acetate appears as a clear colorless liquid. Flash point 18 °F. Density 7.8 lb / gal. Slightly soluble in water. Vapors are heavier than air. Vapors irritate the eyes and respiratory system. May polymerize if heated or contaminated. If polymerization occurs inside a container, the container may violently rupture. Used to make adhesives, paints, and plastics.

Air & Water Reaktionen

Highly flammable. Slightly soluble in water.

Reaktivit?t anzeigen

Vinyl acetate may undergo spontaneous exothermic polymerization on exposure to light. Reacts with air or water to produces peroxides that initiate explosively violent polymerization. Reacts with hydrogen peroxide to form explosive peracetic acid. Reacts with oxygen to form explosive peroxides. Forms explosive Vinyl acetate ozonide on contact with ozone. Undergoes violent or explosive reactions with 2-aminoethanol, chlorosulfonic acid, ethylenediamine, mineral acids (hydrochloric acid, hydrofluoric acid, nitric acid, sulfuric acid, oleum), and peroxides [Lewis, 3rd ed., 1993, p. 1311]. Polymerization initiated by dibenzoyl peroxide in ethyl acetate accelerated out of control, ignited and exploded [Vervalin, 1973, p. 81]. Polymerization in toluene solution has caused several large industrial explosions [MCA Case History No. 2087].

Health Hazard

Vinyl acetate has been related to reproductive abnormalities. It is a skin and upper respiratory tract irritantand a central nervous system depressant. Exposure caused gradual deterioration of heart muscles.

Brandgefahr

When heated to decomposition, Vinyl acetate burns and emits acrid fumes. Highly dangerous when exposed to heat, flames or oxidizers; explosion hazard with strong acids and strong oxidizers. Incompatible with alumina, oxidizing materials, 2-aminoethanol, chlorosulfonic acid; ethyleneimine; 36% hydrochloric acid; 48.7% hydrofluoric acid; 70% nitric acid; oleum; 96% sulfuric acid; ethylene diamine; peroxides and silica gel. Avoid light or any polymerizing initiator. Hazardous polymerization can be initiated by organic and inorganic peroxides; azo compounds; redox systems (including organometallic components); light; and high energy radiation.

Sicherheitsprofil

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Moderately toxic by ingestion, inhalation, and intraperitoneal routes. A skin and eye irritant. Experimental reproductive effects. Human mutation data reported. Highly dangerous fire hazard when exposed to heat, flame, or oxidzers. A storage hazard, it may undergo spontaneous exothermic polymerization. Reaction with air or water to form peroxides that catalyze an exothermic polymerization reaction has caused several large industrial explosions. Reaction with hydrogen peroxide forms the explosive peracetic acid. Reacts with oxygen above 50℃ to form an unstable explosive peroxide. Reacts with ozone to form the explosive vinyl acetate ozonide. Solution polymerization of the acetate dmolved in toluene has resulted in large industrial explosions. Polymerization reaction with dibenzoyl peroxide + ethyl acetate may release ignitable and explosive vapors. The vapor may react vigorously with desiccants (e.g., sihca gel or alumina). Incompatible (explosive) with 2-amino ethanol, chlorosulfonic acid, ethylenediamine, ethyleneimine, HCl, HF, HNO3, oleum, peroxides, H2SO4. See also ESTERS.

m?gliche Exposition

Vinyl acetate is used primarily in polymerization processes to produce polyvinyl acetate; polyvinyl alcohol, and vinyl acetate copolymer. The polymers, usually made as emulsions, suspensions, solutions, or resins, are used to prepare adhesives, paints, paper coatings, and textile finishes. Low molecular weight vinyl acetate is used as a chewing gum base.

Carcinogenicity

There is inadequate evidence in humans for the carcinogenicity of vinyl acetate. There is limited evidence in experimental animals for the carcinogenicity of vinyl acetate. Therefore, IARC has classified vinyl acetate as possibly carcinogenic to humans (Group 2B). This conclusion was based on the following evidence: vinyl acetate is rapidly transformed into acetaldehyde in human blood and animal tissues, there is sufficient evidence in experimental animals for the carcinogenicity of acetaldehyde, both vinyl acetate and acetaldehyde induce nasal cancer in rats after administration by inhalation, and vinyl acetate and acetaldehyde are genotoxic in human cells in vitro and in animals in vivo .

Versand/Shipping

UN1301 Vinyl acetate, stabilized, Hazard Class: 3; Labels: 3-Flammable liquid.

l?uterung methode

Inhibitors such as hydroquinone and other impurities are removed by drying with CaCl2 and fractionally distilling under nitrogen, then refluxing briefly with a small amount of benzoyl peroxide and redistilling it under nitrogen. Store it in the dark at 0o. Add inhibitor (~0.004%) for storage. [Beilstein 2 IV 176.]

Inkompatibilit?ten

Vinyl acetate may undergo spontaneous exothermic polymerization on exposure to light. Vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, strong light and UV. The vapor may react vigorously with silica gel or aluminum, acids, bases, silica gel; alumina, oxidizers, azo compounds. Ozone readily polymerizes in elevated temperatures, under the influence of light, or peroxides. Usually contains a stabilizer to prevent polymerization.

Waste disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Vinylacetat Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Vinylacetat Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 601)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Shaanxi Didu New Materials Co. Ltd
+86-89586680 +86-13289823923
1026@dideu.com China 8670 58
Shandong Yanshuo Chemical Co., Ltd.
+86-18678179670 +86-18615116763
sales@yanshuochem.com China 101 58
PT CHEM GROUP LIMITED
+86-85511178; +86-85511178;
peter68@ptchemgroup.com China 35425 58
Shandong Dexiang International Trade Co., Ltd
+86-15662691337 +86-15662695772
539942812@qq.com China 998 58
Hebei Weibang Biotechnology Co., Ltd
+8615531157085
abby@weibangbio.com China 8810 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578
sales@hbmojin.com China 12835 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-13131129325
sales1@chuanghaibio.com China 5889 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21634 55
Hangzhou FandaChem Co.,Ltd.
+8615858145714
FandaChem@Gmail.com China 9087 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +8618949832763
info@tnjchem.com China 2986 55

108-05-4(Vinylacetat)Verwandte Suche:


  • Vinylacetaat
  • Vinylacetat
  • vinylacetateh.q.
  • vinylacetatehq
  • vinylacetatemonomer15
  • Vinylaceticester
  • vinylamonomer
  • Vinyle
  • Vinyle(acetate de)
  • vinyle(acetatede)
  • Vinyl acetate, 99%, stab. with hydroquinone
  • (2-Pyridyl)methanamine
  • 2-Pyridinylmethylamine
  • a-(Aminomethyl)pyridine
  • Vinyl acetate, 99+%, stabilized
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  • Vinyl acetate 10g [108-05-4]
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  • VINYL ACETATE (STABILISED) FOR SYNTHESIS
  • Vinyl acetate, stabilized, 99+% 1LT
  • Vinyl acetate, stabilized, 99+% 25ML
  • Vinyl Acetate (Stabilized with 8-12 ppM Hydroquinone)
  • Vinyl acetate contains 3-20 ppM hydroquinone as inhibitor, >=99%
  • Vinyl acetate, Standard for GC, >=99.5% (GC)
  • Vinyl acetate, stabilized with 8 to 12ppm hydroquinone
  • acetoxyethene
  • CH3CO2CH=CH2
  • Ethanoic acid, ethenyl ester
  • ethanoicacid,ethenylester
  • Everflex 81L
  • Octan winylu
  • octanwinylu
  • octanwinylu(polish)
  • Plyamul 40305-00
  • Unocal 76 Res 6206
  • Unocal 76 Res S-55
  • Vinile
  • Vinile(acetato di)
  • vinile(acetatodi)
  • Vinnapas A 50
  • Vinyl A monomer
  • Vinyl acetate h.q.
  • Vinyl ester of acetic acid
  • Vinyl ethanoate
  • vinyle(acetatede)(french)
  • Vinylester kyseliny octove
  • vinylesterkyselinyoctove
  • vinylethanoate
  • VyAc
  • Zeset T
  • zesett
  • VINYL ACETATE
  • ACETIC ACID VINYL ESTER
  • ACETIC ACID VINYL ESTER MONOMER
  • VINYL ACETATE BETWEEN %6 TO %10 FOR PLASTIC
  • VINYL ACETATE 1000MG, NEAT
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