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Pirimiphos-methyl (ISO)

Pirimiphos-methyl  Struktur
29232-93-7
CAS-Nr.
29232-93-7
Bezeichnung:
Pirimiphos-methyl (ISO)
Englisch Name:
Pirimiphos-methyl
Synonyma:
Blex;Sybol;PP511;sybol2;Silosan;Sybol 2;aktelik;Actelic;oms1424;ACTELLIC
CBNumber:
CB7468690
Summenformel:
C11H20N3O3PS
Molgewicht:
305.33
MOL-Datei:
29232-93-7.mol

Pirimiphos-methyl (ISO) Eigenschaften

Schmelzpunkt:
15°C
Siedepunkt:
386.5±52.0 °C(Predicted)
Dichte
d30 1.157
Dampfdruck
1.5×10-2 Pa (30°C)
Brechungsindex
nD25 1.527
Flammpunkt:
-18 °C
storage temp. 
APPROX 4°C
L?slichkeit
Chloroform (Slightly), Ethyl Acetate (Slightly)
pka
3.71
Wasserl?slichkeit
9.9 mg l-1 (30 °C, pH 5.2)
Aggregatzustand
Liquid
Farbe
Light yellow to yellow
Merck 
13,7580
BRN 
755726
LogP
4.2 at 20℃
CAS Datenbank
29232-93-7(CAS DataBase Reference)
NIST chemische Informationen
Pirimiphos methyl(29232-93-7)
EPA chemische Informationen
Pirimiphos-methyl (29232-93-7)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xn,N,F
R-S?tze: 22-50/53-67-65-38-11
S-S?tze: 60-61-62
RIDADR  UN3082 9/PG 3
WGK Germany  3
RTECS-Nr. TF1410000
Giftige Stoffe Daten 29232-93-7(Hazardous Substances Data)
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitssch?dlich bei Verschlucken. Akute Toxizit?t oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
H370 Sch?digt die Organe. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 1 Achtung GHS hazard pictogramssrc="/GHS08.jpg" width="20" height="20" /> P260, P264, P270, P307+P311, P321,P405, P501
H372 Sch?digt bei Hautkontakt und Verschlucken die Organe bei l?ngerer oder wiederholter Exposition. Spezifische Zielorgan-Toxizit?t (wiederholte Exposition) Kategorie 1 Achtung GHS hazard pictogramssrc="/GHS08.jpg" width="20" height="20" /> P260, P264, P270, P314, P501
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS09.jpg" width="20" height="20" /> P273, P391, P501
Sicherheit
P260 Dampf/Aerosol/Nebel nicht einatmen.
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P270 Bei Gebrauch nicht essen, trinken oder rauchen.
P273 Freisetzung in die Umwelt vermeiden.
P301+P312 BEI VERSCHLUCKEN: Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.

Pirimiphos-methyl (ISO) Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R22:Gesundheitssch?dlich beim Verschlucken.
R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
R67:D?mpfe k?nnen Schl?frigkeit und Benommenheit verursachen.
R65:Gesundheitssch?dlich: kann beim Verschlucken Lungensch?den verursachen.
R38:Reizt die Haut.
R11:Leichtentzündlich.

S-S?tze Betriebsanweisung:

S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S62:Bei Verschlucken kein Erbrechen herbeiführen. Sofort ?rztlichen Rat einholen und Verpackung oder dieses Etikett vorzeigen.

Chemische Eigenschaften

Light yellow, straw colored, or amber oily liquid. Odorless when pure.

Verwenden

Pirimiphos-methyl is a phosphorothioate used as an insecticide. Pirimiphos-methyl is commonly used for mosquito control as well as control of greenhouse crop pests and stored-product insects.

Definition

ChEBI: An organic thiophosphate that is O,O-dimethyl O-pyrimidin-4-yl phosphorothioate substituted by a methyl group at position 6 and a diethylamino group at position 2.

Allgemeine Beschreibung

Yellow liquid. Corrosive to tin and mild steel. Used as an insecticide.

Air & Water Reaktionen

Hydrolyzed by strong acid or base.

Reaktivit?t anzeigen

Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Landwirtschaftliche Anwendung

Insecticide, Acaricide: Pirimiphos-methyl is a post-harvest insecticide used to control a variety of insects in stored grain products and seed such as corn, rice, wheat and sorghum. It is also incorporated into cattle ear tags, and used for the fogging treatment of iris bulbs and pre-harvest clean up of fruits and vegetables.

Handelsname

ACTELLIC®; ACTELLIFOG®; BLEX®; ENT 27699Gc®; DOMINATOR® EAR TAG; DOUBLE BARREL® EAR TAG; PLANT PROTECTION PP511®; PP511®; SILOSAN®; SYBOL®; TOMAHAWK®[C]

Sicherheitsprofil

Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, POx, and SOx.

m?gliche Exposition

Pirimiphos-methyl is a post -harves organophosphate insecticide/acaricide used to control a variety of insects in stored grain products and seed such as corn, rice, wheat and sorghum. It is also incorporated into cattle ear tags, and used for the fogging treatment of iris bulbs and preharvest cleanup of fruits and vegetables.

Carcinogenicity

When rats were given diets with 0, 10, 50, or 300 ppm pirimiphos methyl (equivalent to 0, 0.4, 2.1, or 12.6 mg/kg/day) for 2 years, 4 of the 42 high-dose male rats had pancreatic islet cell adenomas and 1 had a carcinoma compared to none in control male rats . In a carcinogenicity study, mice were given diets with 0, 50, 200, or 400/300 ppm pirimiphos methyl (equivalent to 0, 8.3, 33, or 52 mg/kg/day (males); 0, 9.7, 39, or 61 mg/kg/day (females)) for 78 weeks . The initial 400 ppm dose resulted in excessive toxicity and moribundity and was reduced to 300 ppm after 8 days. There was no evidence of carcinogenicity. In another mouse carcinogenicity study, pirimiphos methyl was administered in the diet at levels of 0, 5, 250, or 500 ppm (equivalent to 0, 0.5, 25.9, or 45.0 mg/kg/ day (males) and 0, 0.6, 27.6, or 50.6 mg/kg/day (females), respectively) for 80 weeks. The test diet for the highest dose groups initially contained 300 ppm of the test compound (the duration of treatment was not specified). The dose was then increased weekly by 50 ppm to 500 ppm. No evidence of carcinogenicity was observed.

Stoffwechselwegen

The metabolism of pirimiphos-methyl is similar in soils, plants and animals and can be represented by initial hydrolysis to yield 2-diethylamino- 6-methyl-p yrimidin-4-0l which may be either conjugated or successively N-de-ethylated. In plants, pirimiphos-methyl itself is N-de-ethylated. It is probable that the oxon form of the compound is formed in many systems but it is more labile than the parent compound and is often not detected. 0-Dealkylation, as with most organophosphates, is most probably a major detoxification route in mammals but the evidence for it in the case of pirimiphos-methyl is poor.

Versand/Shipping

UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Inkompatibilit?ten

May react violently with antimony(V) pentafluoride. Incompatible with strong acids and alkalies, lead diacetate, magnesium, silver nitrate. In the presence of strong reducing agents such as hydrides, organophosphates form highly toxic and flammable phosphine gas. Contact with oxidizers can cause the release of toxic oxides of phosphorus.

Waste disposal

Destruction by alkali hydrolysis or incineration. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Pirimiphos-methyl (ISO) Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Pirimiphos-methyl (ISO) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 190)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Qingdao Trust Agri Chemical Co.,Ltd
+8613573296305
aroma@qdtrustagri.com China 301 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-13131129325
sales1@chuanghaibio.com China 5889 58
Henan Bao Enluo International TradeCo.,LTD
+86-17331933971 +86-17331933971
deasea125996@gmail.com China 2472 58
career henan chemical co
+86-0371-86658258 +8613203830695
sales@coreychem.com China 29880 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28172 58
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22963 58
Shandong chuangyingchemical Co., Ltd.
18853181302
sale@chuangyingchem.com CHINA 5906 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873
sales@chemdad.com China 39894 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 49374 58
SIMAGCHEM CORP
+86-13806087780
sale@simagchem.com China 17365 58

29232-93-7(Pirimiphos-methyl (ISO))Verwandte Suche:


  • pyridiminephosphate
  • pyrimiphosmethyl
  • Pyrimiphos-methyl
  • Silosan
  • Sybol
  • Sybol 2
  • sybol2
  • Dimethyl O-(2-(diethylamino)-6-methyl-4-pyrimidinyl)phosphorothioate
  • Plant Protection
  • Pyrimidinol, 2-(diethylamino)-6-methyl-, O-ester with O,O-dimethyl phosphorothioate
  • PIRIMIPHOS-METHYL, 250MG, NEAT
  • PIRIMIPHOS-METHYL PESTANAL, 250 MG
  • ACTELLIC
  • ACTELLIC(R)
  • ACTELLIFOG
  • O-(2-Diethylamino-6-methyl-4-pyrimidinyl)-O,O-dimethyl phosphorothioate
  • Pyridimine phosphate
  • ent27699gc
  • ENT 27699Gc
  • Blex
  • aktellik
  • aktelik
  • Actelic
  • 2-diethylamino-6-methylpyrimidin-4-yldimethylphosphorothionate
  • 2-Diethylamino-6-methylpyrimidin-4-yl dimethyl phosphorothionate
  • O,O-dimethyl-O-(2-diethylamino-6-methyl-primidin-4-yl) phosphorothioate
  • Acellifog
  • pirimiphos-methyl (ISO) O-(2-diethylamino-6-methylpyrimidin-4-yl) O,O-dimethyl phosphorothioate
  • Pirimiphos-methyl Solution, 100ppm
  • PiriMifos Metil 90 %
  • Pirimiphos-methyl 250mg [29232-93-7]
  • Poromophos-methyl
  • Thiophosphoric acid=O,O-dimethyl=O-[2-(diethylamino)-6-methyl-4-pyrimidinyl] ester
  • Phosphorothioic acid O-[2-(diethylamino)-6-methylpyrimidin-4-yl] O,O-dimethyl
  • O-[2-(DIETHYLAMINO)-6-METHYL-4-PYRIMIDINYL],O-DIMETHYLPHOSPHOROTHIOATE
  • PiriMiphos-Methyl Standard
  • plantprotectionpp511
  • Plant Protection PP511
  • Pirimiphos Me
  • Pirimifosmethyl
  • phosphorothioicacid,o-(2-(diethylamino)-6-methyl-4-pyrimidinyl)o,o-dimethyl
  • Phosphorothioic acid, O-[2-(diethylamino)-6-methyl-4-pyrimidinyl] O,O-dimethyl ester
  • oms1424
  • OMS 1424
  • o-[2-(Diethylamino)-6-methyl-4-pyrimidinyl] o,o-dimethyl thiophosphate
  • o-(2-diethylamino-6-methylpyrimidin-4-yl)o,o-dimethylphosphorothioate
  • O-(2-Diethylamino-6-methylpyrimidin-4-yl) O,O-dimethyl phosphorothioate
  • Methylpyrimiphos
  • Methylpirimiphos
  • Fumite pirimiphos-methyl smoke
  • fosforanpirimidyny
  • O-2-DIETHYLAMINO-6-METHYLPYRIMIDINE-4-YL O,O-DIMETHYL PHOSPHOROTHIOATE
  • PIRIMPHOS-METHYL ESTER
  • PIRIMIPHOS-METHYL
  • PP511
  • O,O-DIMETHYL-O-[2-(DIETHYLAMINO)-6-METHYL-4-PYRIMIDINYL]PHOSPHOROTHIOATE
  • pirimiphos-methyl (bsi,iso,ansi,ban,esa)
  • pirimiphos-methyl solution
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