O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat
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- CAS-Nr.
- 57018-04-9
- Bezeichnung:
- O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat
- Englisch Name:
- Tolclofos-methyl
- Synonyma:
- S-3349;RIZOLEX;Basilex;Risolex;Risolex(TM);Tolcofos-methyl;olclofos-methyl;Methyl tolclofo;TOLCLOFOS-METHYL;Methyl tolclofos
- CBNumber:
- CB2451996
- Summenformel:
- C9H11Cl2O3PS
- Molgewicht:
- 301.13
- MOL-Datei:
- 57018-04-9.mol
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O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat Eigenschaften
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher |
Xi,N |
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R-S?tze: |
43-50/53 |
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S-S?tze: |
22-24/25-61-60-37-24 |
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RIDADR |
UN 3077 9 / PGIII |
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WGK Germany |
3 |
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RTECS-Nr. |
TF0460000 |
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HS Code |
29201900 |
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Giftige Stoffe Daten |
57018-04-9(Hazardous Substances Data) |
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Toxizit?t |
LD50 in male, female rats, male, female mice (mg/kg): ~5000, ~5000, 3500, 3600 orally; all >5000 dermally; ~5000, 4900, 1070, 1260 i.p.; all >5000 s.c. (Ohtsuki, Fujinami) |
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Bildanzeige (GHS) |
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Alarmwort |
Warnung |
Gefahrenhinweise |
Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
H317 |
Kann allergische Hautreaktionen verursachen. |
Sensibilisierung der Haut |
Kategorie 1A |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
P261, P272, P280, P302+P352,P333+P313, P321, P363, P501 |
H410 |
Sehr giftig für Wasserorganismen mit langfristiger Wirkung. |
Langfristig (chronisch) gew?ssergef?hrdend |
Kategorie 1 |
Warnung |
src="/GHS09.jpg" width="20" height="20" /> |
P273, P391, P501 |
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Sicherheit |
P261 |
Einatmen von Staub vermeiden. |
P272 |
Kontaminierte Arbeitskleidung nicht au?erhalb des Arbeitsplatzes tragen. |
P273 |
Freisetzung in die Umwelt vermeiden. |
P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
P302+P352 |
BEI BERüHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckm??ig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen. |
P333+P313 |
Bei Hautreizung oder -ausschlag: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen. |
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O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat Chemische Eigenschaften,Einsatz,Produktion Methoden
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Verwenden
Tolclofos-methyl is a non-systemic organophosphorus fungicide
with both protective and curative activities that control soil-borne diseases
caused by Rhizoctonia solani, Corticium rolfsii, Tphula incamata and Typhula
ishikariensis in/on potatoes, sugar beet, cotton and peanuts.
Definition
ChEBI: An organic thiophosphate that is 2,6-dichloro-4-methylphenol in which the hydrogen of the hydroxy group group has been replaced by a dimethoxyphosphorothioyl group. Tolclofos-methyl is a phospholipid biosynthesis inhibitor and fungicide that is used for co
trolling soil-borne diseases caused by Typhula incarnata, Corticium rolfsii, Typhula ishikariensis, and Rhizoctonia solani.
Stoffwechselwegen
Tolclofos-methyl underwent common degradation and metabolic pathways
in water, soil, plants and animals. These reactions are well
documented for most organophosphorus compounds and include oxidative
desulfuration, hydroxylation/oxidation of the 4-methyl group
to the alcohol and carboxylic acid, cleavage of the P-O-aryl linkage,
O-demethylation and conjugation. In addition to the above reactions,
photolytic isomerisation to the thionate (P=S) was also observed. A
schematic presentation of the primary metabolic pathways for tolclofosmethyl
is illustrated in Scheme 1.
O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 169)Lieferanten
57018-04-9(O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat)Verwandte Suche:
- 2,6-dichloro-4-methylphenyl o,o-dimethyl phosphorothioate
- Dimethyl O-(2,6-dichloro-4-methylphenyl) phosphorothioate
- S-3349
- RIZOLEX
- O-(2,6-DICHLORO-4-METHYLPHENYL) O,O-DIMETHYL PHOSPHOROTHIOATE
- TOLCLOFOS-METHYL
- Basilex
- Dichloro-4-methylphenyl-O,O-dimethyl phosphorothioate
- o-(2,6-Dichloro-4-methylphenyl) o,o-dimethyl thiophosphate
- o-(2,6-dichloro-p-tolyl)o,o-dimethylesterofphosphorothioicacid
- O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphate
- o,o-dimethylo-(2,6-dichloro-4-methylphenyl)phosphorothioate
- Phosphorothioic acid, O-(2,6-dichloro-4-methylphenyl) O,O-dimethyl ester
- Phosphorothioicacid,esters,O-(2,6-dichloro-4-methylphenyl)-O,O-dimethylester
- phosphorothioicacid,o-(2,6-dichloro-4-methylphenyl)o,o-dimethylester
- phosphorothioicacid,o-(2,6-dichloro-p-tolyl)o,o-dimethylester
- Risolex
- Tolcofos-methyl
- BENZTHIAZURON PESTANAL, 100 MG
- tolclofos-methyl (bsi,iso)
- TOLCHLOFOS-METHYL
- O,O-dimethyl-O-(2,6-dichloro-p-tolyl) phosphorothioate
- (2,6-Dichloro-4-methylphenoxy)-dimethoxy-sulfanylidenephosphorane
- Phosphorothioic acid O-(2,6-dichloro-4-methylphenyl) O,O-dimethyl
- Thiophosphoric acid O-(2,6-dichloro-4-methylphenyl)O,O-dimethyl ester
- Thiophosphoric acid O,O-dimethyl O-(2,6-dichloro-4-methylphenyl) ester
- Thiophosphoric acid=O-(2,6-dichloro-4-methylphenyl)=O,O-dimethyl ester
- O-2,6-DICHLORO-P-TOLYLO,O-DIMETHYLPHOSPHOROTHIOATE
- Tolclofos-methyl Standard
- Tolclofos-methyl Solution, 100ppm
- Tolclofos-Methyl 500mg [57018-04-9]
- Risolex(TM)
- Tolclofos-methyl Solution, 1000ppm
- Tolclofos-methyl@1000 μg/mL in Acetone
- Tolclofos-methyl @100 μg/mL in MeOH
- Tolchlophos-methyl
- Tolclofos-MethylStock,100mg/L,1ml
- olclofos-methyl
- TIANFU-CHEM - Tolclofos-methyl
- Methyl tolclofos
- Methyl tolclofo
- Tolclofos-methyl Solution in Methanol
- Tolclofos-methyl Solution in Hexane
- Tolclofos-methyl-d6 (O,O-dimethyl-d6) in methanol
- Tolclofos Methyl in Acetone
- Tolclofos Methyl in Methanol
- C17590000 Tolclofos-methyl
- L17590000CY Tolclofos-methyL10μg/mLin Cycloh
- Tolclofos-methyl 10.0 μg/ml Ethyl acetate
- Tolclofos-methyl 100 μg/ml Acetonitrile
- Tolclofos-methyl 100 μg/ml Toluene
- 57018-04-9
- C9H11Cl2O3PS
- FUNGICIDE