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Perhydro-1,4-diazepin

Homopiperazine Struktur
505-66-8
CAS-Nr.
505-66-8
Bezeichnung:
Perhydro-1,4-diazepin
Englisch Name:
Homopiperazine
Synonyma:
1,4-DIAZEPANE;HPRZ;Gao Paiqin;HOMOPIPERAZINE;hoMopiperazate;High-piperazine;Homo-Piperazines;AKOS BBS-00004278;1,4-Diazepane 97%;Homopiperazine>
CBNumber:
CB7138982
Summenformel:
C5H12N2
Molgewicht:
100.16
MOL-Datei:
505-66-8.mol

Perhydro-1,4-diazepin Eigenschaften

Schmelzpunkt:
38-40 °C (lit.)
Siedepunkt:
169 °C (lit.)
Dichte
0.95
Brechungsindex
1.4378 (estimate)
Flammpunkt:
148 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
L?slichkeit
Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Slightly)
pka
11.02±0.20(Predicted)
Aggregatzustand
Crystalline Mass
Farbe
White to light yellow
Wasserl?slichkeit
Soluble in water.
Sensitive 
Air Sensitive & Hygroscopic
BRN 
102711
CAS Datenbank
505-66-8(CAS DataBase Reference)
NIST chemische Informationen
Homopiperazine(505-66-8)
EPA chemische Informationen
1H-1,4-Diazepine, hexahydro- (505-66-8)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher C,Xi
R-S?tze: 21-34
S-S?tze: 26-36/37/39-45-27
RIDADR  UN 3259 8/PG 2
WGK Germany  1
RTECS-Nr. HM3850000
F  3-10-23
Hazard Note  Irritant/Corrosive
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29339900
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H311 Giftig bei Hautkontakt. Akute Toxizit?t dermal Kategorie 3 Achtung GHS hazard pictogramssrc="/GHS06.jpg" width="20" height="20" /> P280, P302+P352, P312, P322, P361,P363, P405, P501
H314 Verursacht schwere Ver?tzungen der Haut und schwere Augensch?den. ?tzwirkung auf die Haut Kategorie 1B Achtung GHS hazard pictogramssrc="/GHS05.jpg" width="20" height="20" /> P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Sicherheit
P260 Dampf/Aerosol/Nebel nicht einatmen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P303+P361+P353 BEI BERüHRUNG MIT DER HAUT (oder dem Haar): Alle kontaminierten Kleidungsstücke sofort ausziehen. Haut mit Wasser abwaschen oder duschen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

Perhydro-1,4-diazepin Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R21:Gesundheitssch?dlich bei Berührung mit der Haut.
R34:Verursacht Ver?tzungen.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S27:Beschmutzte, getr?nkte Kleidung sofort ausziehen.

Chemische Eigenschaften

white to light yellow crystalline mass

Verwenden

Homopiperazine is used to prepare 1,4-bis-(2-thiazolyl)-1,4-diazacycloheptane by reacting with 2-bromo-thiazole. It acts as an intermediate for repaglinide and fasudil hydrochloride. It is also used in the preparation of potent H3 receptor antagonists, which is used for the treatment of neurodegenerative conditions. Further, it is used in vesicant, cosmetic, emulsifier and energetic material. It acts as a corrosion inhibitor for iron. In pharmaceuticals, it is employed as antipyretic and reducing blood sugar, adiposity, calm, antipsychotic and anti-nervous.

structure and hydrogen bonding

The conformation of Homopiperazine is shown below, and the N–C–C–N torsion angle of 58.2(4)° confirms that the left-hand end of the molecule has an almost ideal chair-type conformation, which is only slightly distorted by the insertion of the extra atom at the right-hand end. The two nitrogen lone pairs are aligned in opposite directions, which facilitates the formation of a hydrogen-bonded network due to interaction with the NH of adjacent molecules.    Crystal data for C5H12N2, M = 100.16 g mol-1, colorless prism, crystal dimensions 0.10 × 0.10 × 0.10 mm3, tetragonal, space group I–42d (No. 122), a = b = 7.208(2), c = 23.094(7) Å, α = β = γ = 90.00°, V = 1199.9(6) Å3, Z = 8, Dcalc = 1.109 g cm-3, T = 93 K, R1 = 0.0637, Rw2 = 0.1633 for 536 reflections with I > 2σ(I), and 37 variables, Rint 0.0374, goodness of fit on F2 1.137. Data have been deposited at the Cambridge Crystallographic Data Centre as CCDC 2049324[1].

Perhydro-1,4-diazepin Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Natriumhydrid Ammoniak, wssrige Lsung 1,2-Diaminoethan Oxamid (tert-Butyl)methylether N,N-Dimethylformamid Kaliumhydroxid Aceton Natriumsulfat Toluol Benzyltriethylammoniumbromid Phenol Kaliumcarbonat Nickel Natrium Natriumtetrahydroborat N,N-Diethylethanamin 2,3-DICHLORO-5,8-DIHYDROXY-1,4-NAPHTHOQUINONE Trichlormethan N,N'-Bis(ethylene)-p-Toluenesulfonamide Schwefligesure 1,3-Dibrompropan Tosylchlorid Malondialdehydbis(diethylacetal) Hydrogenbromid Tetrahydrofuran Diethylether Ethylacetat Hydrogenchlorid Natriumhydrogencarbonat Wasserstoff Dichlormethan 1,3-Diamino-propan Essigsure Methanol Phosphortribromid 1-Butanol Tetraoctylammoniumbromid Schwefelsure Ammoniak, wasserfrei

Downstream Produkte

1-BENZYL-1,4-DIAZEPANE 1-(4-FLUOROBENZYL)-1,4-DIAZEPANE N-ACETYLHOMOPIPERAZINE ethyl 1,4-diazepane-1-carboxylate 1-Formylhomopiperazine 1-(2-PHENYLETHYL)HOMOPIPERAZINE 1-Boc-hexahydro-1,4-diazepine Benzyl 1-homopiperazine carboxylate

Perhydro-1,4-diazepin Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 449)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hebei Mojin Biotechnology Co., Ltd 		+86 13288715578 +8613288715578
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Hebei Chuanghai Biotechnology Co,.LTD 		+86-13131129325
 sales1@chuanghaibio.com China 5889 58
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 deasea125996@gmail.com China 2472 58
Anhui Ruihan Technology Co., Ltd 		+8617756083858
 daisy@anhuiruihan.com China 973 58
Hebei Ganmiao New material Technology Co., LTD 		+86-17332992504 +86-17332992504
 sales8@hbganmiao.com China 300 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806
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Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512
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Hangzhou FandaChem Co.,Ltd. 		+8615858145714
 FandaChem@Gmail.com China 9087 55
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070
product@chemlin.com.cn CHINA 3009 60
career henan chemical co 		+86-0371-86658258 +8613203830695
 sales@coreychem.com China 29880 58

505-66-8(Perhydro-1,4-diazepin)Verwandte Suche:

  • 1H-1,4-Diazepine, hexahydro-
  • hexahydro-1h-4-diazepine
  • Trimethyleneethylenediamine
  • HEXAHYDRO-1,4-DIAZEPINE
  • HEXAHYDRO-1H-1,4-DIAZEPINE
  • HOMOPIPERAZINE
  • HPRZ
  • AKOS BBS-00004278
  • 2,3,4,5,6,7-HEXAHYDRO-1H-1,4-DIAZEPINE
  • 1,4-PERHYDRODIAZEPINE
  • Gao Paiqin
  • 1,4-DIAZACYCLOHEPTANE
  • PERHYDRO-1,4-DIAZEPINE
  • TIMTEC-BB SBB004367
  • HOJNEYSUCKLEEXTRACT
  • 1,4-Diazacycloheptane, 2,3,4,5,6,7-Hexahydro-1H-1,4-diazepine
  • 1,4-Diazacycloheptane~Hexahydro-1,4-diazepine
  • Homopiperazine,98%
  • [1H]-1,4-Azepine, hexahydro
  • Homopiperazine 97%
  • HOMOPIPERAZINE / 1,4-DIAZACYCLOHEPTANE
  • HEXAHYDRO-1H-4-DIAZEPINE/HOMOPIPERAZINE
  • 3,7-Diazacycloheptane
  • Homopiperazine ,99%
  • Homopiperazine,1,4-Diazacycloheptane, 2,3,4,5,6,7-Hexahydro-1H-1,4-diazepine
  • Homopiperazine 1g [505-66-8]
  • Homo-Piperazines
  • High-piperazine
  • HoMopiperazine, 98% 100GR
  • hoMopiperazate
  • 1,4-Diazepane 97%
  • 1,4-DIAZACYCLOHEPTANE 1,4-DIAZEPANE 1,4-PERHYDRODIAZEPINE 2,3,4,5,6,7-HEXAHYDRO-1H-1,4-DIAZEPINE AKOS BBS-00004278 HEXAHYDRO-1,4-DIAZEPINE HEXAHYDRO-1H-1,4-DIAZEPINE HOMOPIPERAZINE HPRZ PERHYDRO-1,4-DIAZEPINE TIMTEC-BB SBB004367
  • HoMopiperazine, extra pure
  • Homopiperazine, 99%, extra pure
  • Homopiperazine in stock Factory
  • Homopiperazine>
  • Homopiperazine ISO 9001：2015 REACH
  • 1,4-DIAZEPANE
  • 505-66-8
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