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4-Nitrobenzoylchlorid

4-Nitrobenzoyl chloride Struktur
122-04-3
CAS-Nr.
122-04-3
Bezeichnung:
4-Nitrobenzoylchlorid
Englisch Name:
4-Nitrobenzoyl chloride
Synonyma:
P-NITROBENZOYL CHLORIDE;PNBC;4-Nitrobenzoyl;SKL748;4-Nitrobenzoyl chlor;p-Nitrobenzoyl chlori;LABOTEST-BB LT00077260;4-nitro-benzoylchlorid;p-nitro-benzoylchlorid;NITROBENZOYL-4 CHLORIDE
CBNumber:
CB2182076
Summenformel:
C7H4ClNO3
Molgewicht:
185.56
MOL-Datei:
122-04-3.mol

4-Nitrobenzoylchlorid Eigenschaften

Schmelzpunkt:
71-74 °C (lit.)
Siedepunkt:
202-205 °C/105 mmHg (lit.)
Dichte
1.53
Brechungsindex
1.5890 (estimate)
Flammpunkt:
102 °C
storage temp. 
Store below +30°C.
L?slichkeit
Soluble in terahydrofuran, dichloromethane, chloroform and pyridine.
Aggregatzustand
Flakes or Crystals
Farbe
Yellow
Geruch (Odor)
pungent odor
Wasserl?slichkeit
Decomposes
Sensitive 
Moisture Sensitive
Merck 
14,6589
BRN 
473192
Stabilit?t:
Stable, but moisture sensitive. Combustible. Incompatible with water, alcohols, strong oxidizing agents, strong bases.
InChIKey
SKDHHIUENRGTHK-UHFFFAOYSA-N
CAS Datenbank
122-04-3(CAS DataBase Reference)
NIST chemische Informationen
4-Nitrobenzoic acid chloride(122-04-3)
EPA chemische Informationen
p-Nitrobenzoyl chloride (122-04-3)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher C
R-S?tze: 34
S-S?tze: 26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  2
RTECS-Nr. DM6651000
F  9-19-21
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29163900
Toxizit?t LD50 orally in Rabbit: 5600 mg/kg
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H314 Verursacht schwere Ver?tzungen der Haut und schwere Augensch?den. ?tzwirkung auf die Haut Kategorie 1B Achtung GHS hazard pictogramssrc="/GHS05.jpg" width="20" height="20" /> P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Sicherheit
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.
P310 Sofort GIFTINFORMATIONSZENTRUM/Arzt/ anrufen.

4-Nitrobenzoylchlorid Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R34:Verursacht Ver?tzungen.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).

Chemische Eigenschaften

yellow needles or powder

Verwenden

4-Nitrobenzoyl Chloride is used inorganic syntheses such as Michael additions. Also used in the synthesis of polysubstituted furanonaphthoquinoines.

Allgemeine Beschreibung

Yellow needles or powder with a pungent odor.

Air & Water Reaktionen

Unstable in moist surroundings and should be kept in a tightly-closed container. React with water or steam .

Reaktivit?t anzeigen

4-Nitrobenzoyl chloride is incompatible with bases (including amines), with strong oxidizing agents, and with alcohols. May react with reducing agents. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Brandgefahr

Flash point data are not available for 4-Nitrobenzoyl chloride, but 4-Nitrobenzoyl chloride is combustible.

Sicherheitsprofil

Moderately toxic by ingestion. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx and Cl-. See also NITRO COhlPOUNDS OF AROMATIC HYDROCARBONS and CHLORIDES.

l?uterung methode

Crystallise the acid chloride from dry pet ether (b 60-80o), *C6H6 or CCl4. Distil it under vacuum. Irritant. [Adama & Jenkins Org Synth Coll Vol I 394 1941, Beilstein 9 III 1709, 9 IV 1191.]

4-Nitrobenzoylchlorid Upstream-Materialien And Downstream Produkte

Upstream-Materialien

4-Nitrobenzoes?ure Phosphorylchlorid Thionyldichlorid

Downstream Produkte

(6R-trans)-7-Amino-3-[[(5-methyl-1,3,4-thiadiazol-2-yl)thio]methyl]-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-en-2-carbonsure N-4-Aminobenzoyl-L-glutaminsure N-(4-Nitrobenzoyl)-L-glutaminsurehemihydrat 4-Benzoyl Acetanilide Butethamine 4'-Nitroacetophenon 1,3-Dichloro-4-fluorobenzene N-(2-(2-DIETHYLAMINO)ETHYL)-4-NITROBENZAMIDE Procainamidhydrochlorid Fipronil 5,5'-(3-Carboxy-4-oxocyclohexa-2,5-dienylidenmethylen)disalicylsure 4-FLUORO-4'-NITROBENZOPHENONE 1,4-Dinitronaphthalene p-Aminobenzamid Otiloniumbromid 4,4'-Diaminobenzanilid Propan-1,3-diylbis(4-aminobenzoat) 4-Azidobenzoesure CI 36900 Trinatrium-[7-[[4-[[4-[[4-[[2,4-dihydroxy-5-[(2-hydroxy-5-sulfophenyl)azo]phenyl]azo]benzoyl]amino]-o-tolyl]azo]-o-tolyl]azo]naphthalin-1,3-disulfonato(5-)]cuprat(3-)

122-04-3(4-Nitrobenzoylchlorid)Verwandte Suche:

  • 4-NITROBENZOYL CHLORIDE
  • 4-NITROBENZOIC ACID CHLORIDE
  • LABOTEST-BB LT00077260
  • NITROBENZOYL-4 CHLORIDE
  • 4-nitro-benzoylchlorid
  • Benzoyl chloride, 4-nitro-
  • Benzoyl chloride, p-nitro-
  • Benzoylchloride,4-nitro-
  • Nitrobenzoyl chloride, 4-
  • p-Nitrobenzoic acid chloride
  • p-nitrobenzoicacidchloride
  • p-nitro-benzoylchlorid
  • 4-Nitrobenzoic acid chloran hydride
  • 4-Nitrobenzenecarbonyl chloride
  • 4-Nitrobenzoyl chloride,98%
  • 4-Nitrobenzoyl chlor
  • 4-(Chlorocarbonyl)nitrobenzene
  • 4-Nitrobenzoyl chloride, 98% 100GR
  • 4-Nitrobenzoyl chloride, 98% 5GR
  • 4-NITROBENZOYL CHLORIDE FOR SYNTHESIS
  • p-Nitrobenzoyl chlori
  • 4-(Chlorocarbonyl)nitrobenzene, 4-(Chloroformyl)nitrobenzene
  • The nitrobenzene forMyl chloride
  • p-Nitro Benzoyl Chloride 4-Nitro Benzoyl Chloride
  • paraNitro Benzoyl Chloride
  • 4-NitrobenzoylChloride99%
  • 4-NitrobenzoylChloride>
  • SKL748
  • TIANFUCHEM--122-04-3--4-Nitrobenzoyl chloride factory price
  • 4-Nitrobenzoyl Chloride (PNBC) pure, 98%
  • P-NITROBENZOYL CHLORIDE
  • PNBC
  • 4-Nitrobenzoyl
  • 122-04-3
  • 112-04-3
  • O2NC6H4COCl
  • NO2C6H4COCl
  • Acid Halides
  • UV-VIS
  • Organic Building Blocks
  • Carbonyl Compounds
  • Building Blocks
  • ACID CHLORIDE
  • Amino Group Labeling Reagents for HPLC
  • Exciton Chirality CD Method (for Hydroxyl Groups)
  • UV Detection (HPLC Labeling Reagents)
  • HPLC Labeling Reagents
  • Enantiomer Excess & Absolute Conefiguration Determination
  • Hydroxyl Group Labeling Reagents for HPLC
  • Absolute Conefiguration Determination (Exciton Chirality CD Method)
  • Acid Halides
  • Carbonyl Compounds
  • Organic Building Blocks
  • Derivatization Reagents
  • Derivatization Reagents HPLC
  • UV-VIS
  • Absolute Configuration Determination (Exciton Chirality CD Method)
  • Amino Group Labeling Reagents for HPLC
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