Tricyclo[3.3.1.13,7]decan-1-ol
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- CAS-Nr.
- 768-95-6
- Bezeichnung:
- Tricyclo[3.3.1.13,7]decan-1-ol
- Englisch Name:
- 1-Adamantanol
- Synonyma:
- ADAMANTANOL;ADAMANTAN-1-OL;1-Adamantol;1-Admantanol;(3s,5s,7s)-adamantan-1-ol;1-AD-OH;1-HYDROXYADAMANTANE;1-ADA-OH;AKOS BC-0650;damantol-(1)
- CBNumber:
- CB2135047
- Summenformel:
- C10H16O
- Molgewicht:
- 152.23
- MOL-Datei:
- 768-95-6.mol
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Tricyclo[3.3.1.13,7]decan-1-ol Eigenschaften
- Schmelzpunkt:
- 247 °C (subl.) (lit.)
- Siedepunkt:
- 214.73°C (rough estimate)
- Dichte
- 0.8544 (rough estimate)
- Brechungsindex
- 1.4880 (estimate)
- Flammpunkt:
- 240°C
- storage temp.
- Sealed in dry,Room Temperature
- L?slichkeit
- Chloroform (Sparingly), Methanol (Slightly)
- pka
- 15.38±0.20(Predicted)
- Aggregatzustand
- Crystalline Powder or Needles
- Farbe
- White to off-white
- Wasserl?slichkeit
- Soluble in ethanol , methanol, and diethyl ether. Partly miscible in water.
- Sublimation
- 240 ºC
- BRN
- 1903952
- InChIKey
- VLLNJDMHDJRNFK-UHFFFAOYSA-N
- CAS Datenbank
- 768-95-6(CAS DataBase Reference)
- NIST chemische Informationen
- 1-Adamantanol(768-95-6)
Tricyclo[3.3.1.13,7]decan-1-ol Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Beschreibung
1-Adamantanol is a cyclic molecule with a hydroxyl group. It is produced by the oxidation of 2-methyl-2-adamantanol. 1-Adamantanol has been shown to be an effective substrate for bioremediation in wastewater treatment plants and can be used as a precursor to produce trifluoroacetic acid.
Chemische Eigenschaften
white to off-white crystalline powder or needles
Verwenden
1-Adamantanol was used in the preparation of 1,3-adamantanediol. It is used in the manufacture of synthetic adamantane derivatives and adapalene.
l?uterung methode
If 2-adamantanol is a suspected impurity, then dissolve the substance (10g) in acetone (100mL) and add Jones's reagent [CrO3 (10.3g) in H2O (30mL)], then conc H2SO4 (8.7mL) is added dropwise (turns green in colour) until excess reagent is present (slight red colour). Stir overnight, decant the acetone solution from the Cr salts and adamantan-2-one, dry (Na2SO4) and evaporate to dryness. The residue (ca 7g) is chromatographed through Al2O3 (250g) and washed with 50% *benzene/pet ether (b 40-60o), then 100% Et2O (to remove any adamantan-2-one present) and the 1-adamantanol is then eluted with 5% MeOH in Et2O. The eluate is evaporated, and the residue is recrystallised from pet ether (b 30-60o) at -70o, m 287.2-288.5o. It also crystallises from MeOH and can be sublimed in vacuo. It has characteristic IR, max 3640, 1114, 1086, 982 and 930cm-1. [Schleyer & Nicholas J Am Chem Soc 83 182 1961.] [Beilstein 6 IV 391.] Alternatively, if free from the 2-isomer, dissolve it in tetrahydrofuran, dilute with H2O to precipitate the alcohol. Collect, dry and sublime it in a vacuum at 130o. [Stetter et al. Chem Ber 92 1629 1959.]
Tricyclo[3.3.1.13,7]decan-1-ol Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Tricyclo[3.3.1.13,7]decan-1-ol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 513)Lieferanten
| Firmenname |
Telefon |
E-Mail |
Land |
Produktkatalog |
Edge Rate |
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Chengdu Yuanda Chemical Co., Ltd
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28-85356300 +8618980937689
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sales@ydachem.com |
CHINA |
94 |
58 |
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Nanjing Shunxiang Pharmaceutical Technology Co.,Ltd.
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+86-86-02586819868 +8613913839793
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sales@jinchemical.com |
China |
23 |
58 |
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Huzhou Chenxi Environmental Protection Technology Co. , Ltd.
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+8616762203950
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1034385273@qq.com |
China |
55 |
58 |
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Hebei Mojin Biotechnology Co., Ltd
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+86 13288715578 +8613288715578
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sales@hbmojin.com |
China |
12835 |
58 |
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Hebei Yanxi Chemical Co., Ltd.
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+8617531190177
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peter@yan-xi.com |
China |
5857 |
58 |
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Hebei Chuanghai Biotechnology Co,.LTD
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+86-13131129325
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sales1@chuanghaibio.com |
China |
5889 |
58 |
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Hebei Weibang Biotechnology Co., Ltd
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+8617732866630
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bess@weibangbio.com |
China |
18151 |
58 |
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Shaanxi Haibo Biotechnology Co., Ltd
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+undefined18602966907
|
qinhe02@xaltbio.com |
China |
997 |
58 |
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hebei hongtan Biotechnology Co., Ltd
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+86-86-1913198-3935 +8617331935328
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sales03@chemcn.cn |
China |
970 |
58 |
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Capot Chemical Co.,Ltd.
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+86-（0）57185586718 +86-13336195806
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sales@capot.com |
China |
29791 |
60 |
768-95-6(Tricyclo[3.3.1.13,7]decan-1-ol)Verwandte Suche:
- TRICYCLO[3.3.1.1(3,7)]DECAN-1-OL
- TRICYCLO[3.3.1.1]DECAN-1-OL
- 1-HYDROXYDIAMANTANE
- 1-ADA-OH
- 1-ADAMANTANOL
- 1-Adamatanol
- -Adamantyl alcohol
- damantol-(1)
- tricyclo(3.3.1.1(sup3,7))decan-1-ol
- ADAMANTANOL, 1-
- AKOS BC-0650
- 1-Adamantonal
- 1-Adamantanol,98%
- LABOTEST-BB LT00436924
- ADAMANTANOL, 1-(SG)
- (1-Adamantyl) alcohol
- Adamantan-3-ol
- Hydroxyadamantane
- 1-Adamantanol,99%
- Tricyclo[3,3,1,1]3,7 decanol-1
- adamantan-1-ol(SALTDATA: FREE)
- 1-AdaMantanol, 99% 5GR
- 1-ADAMANTANOL FOR SYNTHESIS 10 G
- Adapalene IMpurity H
- Adamantan-1-ol, Tricyclo[3.3.1.1~3,7~]decan-1-ol
- 1-Adamantanol Vetec(TM) reagent grade, 98%
- Tricyclo(3.3.1.1(sup 3,7))decan-1-ol (9CI)
- 1-AdaMantanol ReagentPlus(R), 99%
- 1 - adaMantane alcohol
- 1-Adamanthanol/Adamantan-1-ol
- 1-Adamantano
- 1 Adamentanol (768-95-6)
- 1-Adamantanol >
- 1-HYDROXYADAMANTANE
- 1-AD-OH
- 1-Adamantol
- ADAMANTANOL
- ADAMANTAN-1-OL
- 1-Admantanol
- (3s,5s,7s)-adamantan-1-ol
- 1-Adamantanol (6CI, 7CI, 8CI)
- 1-HYDROXY ADAMANTANE (1-adamantanol)
- HYDROXY ADAMANTANE (1-ADAMANTANOL)
- 768-95-6
- C9 to C30
- Alcohols
- Building Blocks
- Oxygen Compounds
- Organic Building Blocks
- Adamantanes
- Alcohols
- Building Blocks
- C9 to C10
- Chemical Synthesis
- Organic Building Blocks
- Oxygen Compounds
- FINE Chemical & INTERMEDIATES
- Adamantane derivatives
