| Identification | More | [Name]
CIS-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE; >98% | [CAS]
85-43-8 | [Synonyms]
1,2,3,6-Tetrahydrophthalic acid anhydride
1,2,3,6-tetrahydrophthalicacidanhydride
1,2,3,6-tetrahydro-phthalicanhydrid
1,2,3,6-tetrahydrophthalicanhydride[qr]
1,3-Isobenzofurandione, 3a,4,7,7a-tetrahydro-, cis-
1,3-isobenzofurandione,3a,4,7,7a-tetrahydro-[qr]
3a,4,7,7a-tetrahydro-1,3-benzofurandione
3a,4,7,7a-tetrahydro-3-isobenzofurandione
3-Isobenzofurandione,3a,4,7,7a-tetrahydro-1
4-Cyclohexene-1,2-dicarboxylic acid anhydride
4-Cyclohexene-1,2-dicarboxylic anhydride, cis-
4-cyclohexene-1,2-dicarboxylicacidanhydride
4-cyclohexene-1,2-dicarboxylicanhydride[qr]
Anhydrid kyseliny tetrahydroftalove
anhydridetetrahydrophtalique
anhydridkyselinytetrahydroftalove
anhydridkyselinytetrahydroftalove[czech][qr]
Butadiene-maleic anhydride adduct
butadiene-maleicanhydrideadduct
Cyclohex-4-en-1,2-dicarbonsaeureanhydrid | [EINECS(EC#)]
201-605-4 | [Molecular Formula]
C8H8O3 | [MDL Number]
MFCD00005916 | [Molecular Weight]
152.147 | [MOL File]
85-43-8.mol |
| Chemical Properties | Back Directory | [Melting point ]
101-102°C | [Boiling point ]
195°C 5mm | [density ]
1,375 g/cm3 | [vapor pressure ]
0.021Pa at 20℃ | [refractive index ]
1.4810 (estimate) | [Fp ]
157°C | [storage temp. ]
Store below +30°C. | [solubility ]
soluble in DCM, Ethyl Acetate, Toluene | [form ]
Solid | [pka]
3.84[at 20 ℃] | [color ]
Off-White to Light Tan | [Water Solubility ]
29.4g/L at 20℃ | [LogP]
1.29 at 40℃ | [Uses]
Chemical intermediate for light-colored alkyds,
polyesters, plasticizers, and adhesives; intermediate
for pesticides; hardener for resins. | [CAS DataBase Reference]
85-43-8(CAS DataBase Reference) | [EPA Substance Registry System]
Tetrahydrophthalic anhydride (85-43-8) |
| Safety Data | Back Directory | [Risk Statements ]
R41:Risk of serious damage to eyes.
R42/43:May cause sensitization by inhalation and skin contact .
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
2698 | [HazardClass ]
8 | [PackingGroup ]
III | [Safety Profile]
Moderately toxic by intraperitoneal route. Mildly toxic by ingestion. A corrosive irritant to skin, eyes, and mucous membranes. Combustible when exposed to heat or flame. Will react with water or steam to produce heat; can react with oxidizing materials. To fight fre, use water, foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ANHYDRIDES. | [Hazardous Substances Data]
85-43-8(Hazardous Substances Data) |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
1,3-Butadiene-->Maleic anhydride-->cyclohex-4-ene-1,2-dicarboxylic acid-->3-SULFOLENE-->1,2-BUTADIENE | [Preparation Products]
Tetramethrin-->N-Hydroxymethyl-3,4,5,6-tetrahydrophthalimide-->Captan-->3,4,5,6-Tetrahydrophthalic anhydride-->Hexahydrophthalic anhydride-->CIS-4-CYCLOHEXENE-1,2-DICARBOXYLIC ACID-->Tetrahydrophthalimide-->diethyl cyclohex-4-ene-1,2-dicarboxylate-->dimethyl cyclohex-3-ene-1,6-dicarboxylate |
| Hazard Information | Back Directory | [General Description]
Clear colorless to light yellow slight viscous liquid. Highly toxic and a strong irritant to skin, eyes and mucous membranes. Corrosive to skin and metal. Used in making polyester, alkyd resins, and plasticizers. | [Reactivity Profile]
MEMTETRAHYDROPHTHALIC ANHYDRIDE(85-43-8) is combustible. Reacts with oxidizers. Reacts exothermically with water. These reactions are usually slow, but can become violent when local heating accelerates their rate. Acids accelerate the reaction with water. Incompatible with acids, strong oxidizing agents, alcohols, amines, and bases. | [Air & Water Reactions]
Reacts exothermically with water to form memtetrahydrophthalic acid. | [Hazard]
Strong irritant to eyes and skin. | [Health Hazard]
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. | [Fire Hazard]
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. | [Chemical Properties]
white flaky solid | [Definition]
ChEBI: 1,2,3,6-tetrahydrophthalic anhydride is a cyclic dicarboxylic anhydride that is 1,3,3a,4,7,7a-hexahydro-2-benzofuran carrying oxo groups at positions 1 and 3. It is a cyclic dicarboxylic anhydride and a tetrahydrofurandione. | [Flammability and Explosibility]
Nonflammable |
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