Identification | More | [Name]
IRON (II) BROMIDE | [CAS]
7789-46-0 | [Synonyms]
FERROUS BROMIDE IRON BROMIDE IRON (II) BROMIDE FeBr2 Iron bromide (FeBr2) ironbromide(febr2) iron dibromide Ironbromideanhydrousorangepowder IRON(II) BROMIDE, ANHYDROUS, 99.999% ultradry,99.995%metalsbasis Iron(II)bromide,ultradry,99.995%(metalsbasis) Iron(II)bromide,ultradry,99,999%(metalbasis) Iron(II) bromide, anhydrous, 98+% iron(ii) bromide, anhydrous iron(ii) bromide, ultra dry Iron(II) bromide, anhydrous, 98% min | [EINECS(EC#)]
232-168-8 | [Molecular Formula]
Br2Fe | [MDL Number]
MFCD00016081 | [Molecular Weight]
215.65 | [MOL File]
7789-46-0.mol |
Chemical Properties | Back Directory | [Appearance]
Yellow to dark brown lumps | [Melting point ]
684 °C(lit.) | [Boiling point ]
934 °C(lit.) | [density ]
4.63 g/mL at 25 °C(lit.)
| [solubility ]
ethanol: very soluble(lit.) | [form ]
beads
| [color ]
Yellow | [Specific Gravity]
4.636 | [Water Solubility ]
Soluble in water, THF, methanol, ethanol. | [Sensitive ]
Hygroscopic | [Merck ]
14,4042 | [Stability:]
hygroscopic | [Uses]
Polymerization catalyst. | [CAS DataBase Reference]
7789-46-0(CAS DataBase Reference) | [EPA Substance Registry System]
Iron bromide (FeBr2) (7789-46-0) |
Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R20:Harmful by inhalation. R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [RIDADR ]
UN3260 | [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28275900 |
Hazard Information | Back Directory | [Chemical Properties]
In contrast to the chloride, iron(III) bromide is unstable
under these conditions. The hydrated bromide can be dehydrated in a stream of hydrogen
bromide at 400°C. Iron(II) bromide forms a layer lattice of the CdI2 type. It has a magnetic
moment,μeff= 5·71 B.M. at 295°K. It is deliquescent and very soluble in water; the pale
green hexahydrate crystallizes at room temperature, the tetrahydrate above 49°C and the
dihydrate above 83°C. A 9-hydrate forms below -29·3°C. The anhydrous salt is also
soluble in ether, ethanol and acetonitrile. | [Chemical Properties]
Yellow to dark brown lumps | [Preparation]
Iron(II) bromide can be prepared by the direct reaction of bromine or hydrogen
bromide with iron at red heat. | [General Description]
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