Identification | Back Directory | [Name]
TITANIUM(IV) BROMIDE | [CAS]
7789-68-6 | [Synonyms]
TiBr4 Titanium bromide Tetrabromotitanium Titanium(Ⅳ) Bromide TITANIUM(IV) BROMIDE TITANIUM TETRABROMIDE Tetrabromotitanium(IV) Titanium(IV) bromide,98% Titanium(IV) bromide 98% Titanium(IV) tetrabromide Titanium(IV)bromide,min.98% Titaniumbromide(TiBr4),(T-4)- Titanium(IV) bromide, min. 98% Titanium bromide (TiBr4), (T-4)- TITANIUM(IV) BROMIDE ON METALS BASIS TITANIUM TETRABROMIDE (99.% on metals basis) TITANIUM TETRABROMIDE (99.9% on Metals basis) TITANIUM(IV) BROMIDE, ANHYDROUS, POWDER, 99.99% | [EINECS(EC#)]
232-185-0 | [Molecular Formula]
Br4Ti | [MDL Number]
MFCD00011265 | [MOL File]
7789-68-6.mol | [Molecular Weight]
367.48 |
Chemical Properties | Back Directory | [Appearance]
Orange low melting lumps and powder | [Melting point ]
38-40 °C(lit.)
| [Boiling point ]
230 °C(lit.)
| [density ]
3.25 g/mL at 25 °C(lit.)
| [Fp ]
233°C | [solubility ]
reacts with H2O | [form ]
powder
| [color ]
Orange | [Specific Gravity]
2.6 | [Water Solubility ]
Soluble in absolute alcohol. Decomposes in waterSoluble in chlorocarbons, benzene and alcohol. | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [Sensitive ]
Moisture Sensitive | [Merck ]
14,9477 | [CAS DataBase Reference]
7789-68-6 |
Hazard Information | Back Directory | [Chemical Properties]
Orange low melting lumps and powder | [Uses]
Titanium(IV) bromide is used as a Lewis acid catalyst in organic synthesis. It reacts with tetrahydrofurnan and 2-methylpyridine and forms adducts such as TiBr4(THF)2 and TiBr4(2-MePy). It is also used for the formation of titanium silicide thin films on silicon substrates. | [Purification Methods]
Purify it by distillation. The distillate forms light orange hygroscopic crystals. Store it in the dark under N2 preferably in sealed brown glass ampules. [Olsen & Ryan J Am Chem Soc 54 2215 1932.] |
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Alfa Aesar
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Energy Chemical
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http://www.energy-chemical.com |
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