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ChemicalBook--->CAS DataBase List--->7789-68-6

7789-68-6

7789-68-6 Structure

7789-68-6 Structure
IdentificationBack Directory
[Name]

TITANIUM(IV) BROMIDE
[CAS]

7789-68-6
[Synonyms]

TiBr4
Titanium bromide
Tetrabromotitanium
Titanium(Ⅳ) Bromide
TITANIUM(IV) BROMIDE
TITANIUM TETRABROMIDE
Tetrabromotitanium(IV)
Titanium(IV) bromide,98%
Titanium(IV) bromide 98%
Titanium(IV) tetrabromide
Titanium(IV)bromide,min.98%
Titaniumbromide(TiBr4),(T-4)-
Titanium(IV) bromide, min. 98%
Titanium bromide (TiBr4), (T-4)-
TITANIUM(IV) BROMIDE ON METALS BASIS
TITANIUM TETRABROMIDE (99.% on metals basis)
TITANIUM TETRABROMIDE (99.9% on Metals basis)
TITANIUM(IV) BROMIDE, ANHYDROUS, POWDER, 99.99%
[EINECS(EC#)]

232-185-0
[Molecular Formula]

Br4Ti
[MDL Number]

MFCD00011265
[MOL File]

7789-68-6.mol
[Molecular Weight]

367.48
Chemical PropertiesBack Directory
[Appearance]

Orange low melting lumps and powder
[Melting point ]

38-40 °C(lit.)
[Boiling point ]

230 °C(lit.)
[density ]

3.25 g/mL at 25 °C(lit.)
[Fp ]

233°C
[solubility ]

reacts with H2O
[form ]

powder
[color ]

Orange
[Specific Gravity]

2.6
[Water Solubility ]

Soluble in absolute alcohol. Decomposes in waterSoluble in chlorocarbons, benzene and alcohol.
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[Sensitive ]

Moisture Sensitive
[Merck ]

14,9477
[CAS DataBase Reference]

7789-68-6
Hazard InformationBack Directory
[Chemical Properties]

Orange low melting lumps and powder
[Uses]

Titanium(IV) bromide is used as a Lewis acid catalyst in organic synthesis. It reacts with tetrahydrofurnan and 2-methylpyridine and forms adducts such as TiBr4(THF)2 and TiBr4(2-MePy). It is also used for the formation of titanium silicide thin films on silicon substrates.
[Purification Methods]

Purify it by distillation. The distillate forms light orange hygroscopic crystals. Store it in the dark under N2 preferably in sealed brown glass ampules. [Olsen & Ryan J Am Chem Soc 54 2215 1932.]
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

14-34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 3260 8/PG 2
[WGK Germany ]

3
[F ]

3-8-10-21
[TSCA ]

No
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

28275900
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