Identification | More | [Name]
1,3-Bis(bromomethyl)benzene | [CAS]
626-15-3 | [Synonyms]
1,3-BIS(BROMOMETHYL)BENZENE 1,3-DI(BROMOMETHYL)BENZENE A,A'-DIBROMO-M-XYLENE ALPHA,ALPHA'-DIBROMO-M-XYLENE M-XYLIDENE DIBROMIDE M-XYLYLENE BROMIDE M-XYLYLENE DIBROMIDE 1,3-bis(bromomethyl)-benzen a,a'-m-Xylene dibromide alpha,alpha'-Dibromo-meta-xylene benzene,1,3-bis(bromomethyl)- m-(Bromomethyl)benzyl bromide m-alpha,alpha'-Dibromoxylene m-Bis(bromomethyl)benzene m-Xylene, a,a'-dibromo- m-Xylene, alpha,alpha'-dibromo- α,α’-dibromo-m-xylene m-Xylene dibromide Xylenedibromide,97% M-XYLYENE DIBROMIDE | [EINECS(EC#)]
210-931-6 | [Molecular Formula]
C8H8Br2 | [MDL Number]
MFCD00000178 | [Molecular Weight]
263.96 | [MOL File]
626-15-3.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . R43:May cause sensitization by skin contact. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37:Wear suitable protective clothing and gloves . | [RIDADR ]
UN 3448 6.1/PG 2
| [WGK Germany ]
3
| [F ]
8-19-21 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29036990 |
Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
1,3-Bis(bromomethyl)benzene has been used in preparation of four novel dinuclear half-titanocenes with meta - and ortho xylene bridges as new metallocenes 1 . It was used in the synthesis of dissymmetrical bis -macrocyclic salt 2 .
| [Uses]
It is used in preparation of four novel dinuclear half-titanocenes with?meta- and?orthoxylene bridges as new metallocenes. It was used in the synthesis of dissymmetrical bis-macro cyclic salt. | [General Description]
α,α′-Dibromo-m-xylene can cross-link and cyclize peptides containing two cysteine residues. | [Purification Methods]
Crystallise it from acetone or *benzene, and fractionally distil it under vacuum. [Wenner Org Chem 17 527 1952, Beilstein 5 H 374, 5 I 184, 5 II 294, 5 III 839, 5 IV 946.] |
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