| Identification | More | [Name]
1,3,5-Triglycidyl isocyanurate | [CAS]
2451-62-9 | [Synonyms]
1,3,5-TRIGLYCIDYL ISOCYANURATE
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1h,3h,5h)-trione
AKOS BBS-00004710
araldite pt-810
ISOCYANURIC ACID TRIGLYCIDYL ESTER
ISOCYANURIC ACID TRIS(2,3-EPOXYPROPYL) ESTER
Teroxirone
TGIC
TRIGLYCIDYL ISOCYANURATE
TRIS(2,3-EPOXYPROPYL) ISOCYANURATE
XB 2615
1,3,5-Triazine-2,4,6(1H,3H,5H)-trione,1,3,5-tris(oxiranylmethyl)-
1,3,5-triglycidylisocyanuricacid
1,3,5-triglycidyl-s-triazinetrione
1,3,5-truglycidyl-s-triazinetrione
3,5-Triazine-2,4,6(1H,3H,5H)-trione,1,3,5-tris(oxiranylmethyl)-1
5-triazine-2,4,6(1h,3h,5h)-trione,1,3,5-tris(oxiranemethyl)-3
5-triazine-2,4,6(1h,3h,5h)-trione,1,3,5-tris(oxiranylmethyl)-3
6(1h,3h,5h)-trione,1,3,5-tris(2,3-epoxypropyl)-s-triazine-4
6(1h,3h,5h)-trione,tris(2,3-epoxypropyl)-s-triazine-4 | [EINECS(EC#)]
219-514-3 | [Molecular Formula]
C12H15N3O6 | [MDL Number]
MFCD00080670 | [Molecular Weight]
297.26 | [MOL File]
2451-62-9.mol |
| Chemical Properties | Back Directory | [Melting point ]
95-98°C | [Boiling point ]
438.78°C (rough estimate) | [density ]
1,42 g/cm3 | [vapor pressure ]
0.007Pa at 20℃ | [refractive index ]
1.5290 (estimate) | [storage temp. ]
Store at 4°C | [solubility ]
DMSO: 50 mg/mL (168.20 mM) | [form ]
powder to crystal | [pka]
-2.44±0.20(Predicted) | [color ]
White to Almost white | [Water Solubility ]
<0.1 g/100 mL at 20 ºC | [Usage]
TGIC is widely used as a cross-linking agent or curing agent in powder coating industry, It is used also in the printed circuit board industry, electrical insulation and as a stabilizer in plastic industry.
Typical applications of polyester TGIC powder coatings are where sharp edges and corners exist such as on automotive wheels, air conditioners, lawn furniture, and air conditioner cabinets.
| [Detection Methods]
GC,NMR | [Contact allergens]
Triglycidyl isocyanurate is a triazine epoxy compound
used as a resin hardener in polyester powder paints, in
the plastics industry, resin molding systems, inks, and
adhesives. Occupational contact dermatitis can occur in people producing this chemical, in those producing
the powder coat paint, and in sprayers. Respiratory
symptoms have been observed. | [LogP]
-0.8 at 20℃ | [CAS DataBase Reference]
2451-62-9(CAS DataBase Reference) | [Storage Precautions]
Light sensitive;Moisture sensitive;Heat sensitive | [EPA Substance Registry System]
2451-62-9(EPA Substance) |
| Hazard Information | Back Directory | [Chemical Properties]
White powder or chunks | [Uses]
1,3,5-triglycidyl isocyanurate be used for curing agent of polyester and acrylic resin carboxyl-containing powder coating, manufacturing an electrical insulating laminates, adhesives, plastics stabilizers. | [Uses]
TGIC is widely used as a cross-linking agent or curing agent in powder coating industry, It is used also in the printed circuit board industry, electrical insulation and as a stabilizer in plastic industry.
Typical applications of polyester TGIC powder coatings are where sharp edges and corners exist such as on automotive wheels, air conditioners, lawn furniture, and air conditioner cabinets.
| [General Description]
White crystalline solid. | [Reactivity Profile]
Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts. | [Air & Water Reactions]
Insoluble in water. | [Fire Hazard]
Flash point data for this chemical are not available; however, TRIS(2,3-EPOXYPROPYL)ISOCYANURATE is probably combustible. | [Description]
Occupational contact dermatitis can occur
in people producing this chemical, in those producing
the powder coat paint and in sprayers. | [Flammability and Explosibility]
Nonflammable |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R23/25:Toxic by inhalation and if swallowed .
R41:Risk of serious damage to eyes.
R43:May cause sensitization by skin contact.
R48/22:Harmful: danger of serious damage to health by prolonged exposure if swallowed .
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 2811 6.1/PG 3
| [WGK Germany ]
3
| [RTECS ]
XZ1994900
| [HazardClass ]
6.1(b) | [PackingGroup ]
III | [HS Code ]
29299090 | [Hazardous Substances Data]
2451-62-9(Hazardous Substances Data) | [Toxicity]
LD50 oral in rat: 188mg/kg |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Ethanol-->Sodium hydroxide-->Epichlorohydrin-->Cyanuric acid-->Tris(3-chloro-2-hydroxypropyl)isocyanurate-->1,3,5-Tri-2-propenyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione-->1,3-bis(oxiranylmethyl)-5-(2-propenyl)-1,3,5-Triazine-2,4,6(1H,3H,5H)-trione |
| Questions And Answer | Back Directory | [Industrial Application]
1,3,5-triglycidyl isocyanurate (TGIC) is a white powder or granular solid and is normally sold under the trade name ARALDITE PT810R or TEPIC G R. As a tri-functional epoxy monomer, TGIC is used in large scale as curing agent for powder coatings or for cross-linking elastomers. Rosin acids of natural origin may also be cured with TGIC for versatile applications. TGIC has also been used for pharmaceutical purposes, in membranes, for curing intelligent gels or liquid crystal elastomers. Especially, this curing agent has been widely used in dry powder coating for over 40 years. | [Health Toxicity]
It has been known that TGIC is toxic by inhalation and if swallowed. It is a severe eye irritant, and a mild skin and nasal irritant, although it has the potential to cause skin sensitisation in people which can lead to severe skin rashes. Exposure to TGIC in powder paints may cause not only contact dermatitis, but also occupational asthma. Kidney damage has also been observed in rats repeatedly exposed to TGIC by oral dosing, and damage to the developing sperm cells has been observed in mice repeatedly exposed to TGIC orally and by inhalation. There is an evidence that exposure of males to TGIC produces genetic changes in the sperm which may lead to heritable effects in the offspring. There is cause for concern that these effects could occur in humans, so that TGIC has been classified in the EU as a Category 2 mutagen. Exposures to TGIC during manufacturing procedures have been identified as hazardous to workers. |
|
|