| Identification | More | [Name]
(Carbomethoxymethyl)triphenylphosphonium bromide | [CAS]
1779-58-4 | [Synonyms]
CARBOMETHOXYMETHYL TRIPHENYLPHOSPHONIUM BROMIDE
(METHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
(2-methoxy-2-oxoethyl)triphenylphosphonium bromide
carbmethoxy Methyl Triphenyl Phosphonium Bromide
Carbomethoxymethyl triphenylphosphonium bromide, 98+%
methyl (triphenylphosphonio)acetate bromide
(METHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE, 98+%
CMMTPPB
PHOSPHONIUM,(2-METHOXY-2-OXOETHYL)TRIPHENYL-,BROMIDE
(2-Oxo-2-methoxyethyl)triphenylphosphonium·bromide
Triphenyl(2-oxo-2-methoxyethyl)phosphonium·bromide
Triphenyl(methoxycarbonylmethyl)phosphonium·bromide | [EINECS(EC#)]
217-222-0 | [Molecular Formula]
C21H20BrO2P | [MDL Number]
MFCD00011801 | [Molecular Weight]
415.26 | [MOL File]
1779-58-4.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [F ]
9 | [HS Code ]
29319019 |
| Hazard Information | Back Directory | [Chemical Properties]
white powder | [Uses]
(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts. | [Purification Methods]
Wash it with pet ether (b 40-50o), recrystallise it from CHCl3/Et2O and dry it at high vacuum at 65o. [Isler et al. Helv Chim Acta 40 1242 1957, Wittig & Haag Chem Ber 88 1654, 1664 1955, Beilstein 16 IV 981.] |
|
|