| Identification | More | [Name]
Dichloromethylphenylsilane | [CAS]
149-74-6 | [Synonyms]
DICHLOROMETHYLPHENYLSILANE
METHYLPHENYLDICHLOROSILANE
METHYLPHENYLSILICON DICHLORIDE
PHENYLDICHLOROMETHYLSILANE
PHENYLMETHYLDICHLOROSILANE
CM8930
Dichlor-fenyl-methylsilane
dichloromethylphenyl-silan
Methylphenyldichlorosilane(Dichloromethylphenylsilane)
Methylphenyldichlorosilane,min.97%
Silane, dichloromethylphenyl-
dow corning product z-1221
Methyl(phenyl)dichlorosilane (as hydrochloridy)
Dow Corning(R) product Z-1221, Methyl-phenyl-dichlorosilane
Methylphenyldichlorosilane, min. 97%
Dichloro(phenyl)(methyl)silane
Methyldichlorophenylsilane | [EINECS(EC#)]
205-746-2 | [Molecular Formula]
C7H8Cl2Si | [MDL Number]
MFCD00000490 | [Molecular Weight]
191.13 | [MOL File]
149-74-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Dichloromethylphenylsilane is a flammable,
colorless liquid. | [Melting point ]
-53°C | [Boiling point ]
205 °C(lit.) | [density ]
1.176 g/mL at 25 °C(lit.)
| [vapor pressure ]
0.004-32Pa at 25℃ | [refractive index ]
n20/D 1.519(lit.)
| [Fp ]
181 °F
| [storage temp. ]
Store below +30°C. | [form ]
liquid | [color ]
colorless | [Specific Gravity]
1.187 | [explosive limit]
0.2-8.6%(V) | [Water Solubility ]
reacts | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [Sensitive ]
Moisture Sensitive | [BRN ]
970975 | [InChIKey]
GNEPOXWQWFSSOU-UHFFFAOYSA-N | [LogP]
0.8 at 20℃ | [Uses]
Manufacture of silicones. | [CAS DataBase Reference]
149-74-6(CAS DataBase Reference) | [NIST Chemistry Reference]
Silane, dichloromethylphenyl-(149-74-6) | [EPA Substance Registry System]
Dichloromethylphenylsilane (149-74-6) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R14:Reacts violently with water.
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2437 8/PG 2
| [WGK Germany ]
1
| [RTECS ]
VV3530000
| [F ]
10-21 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29310095 | [Safety Profile]
Poison by inhalation,
subcutaneous, and intraperitoneal routes.
Corrosive to eyes, skin, and mucous
membranes. Flammable liquid. When heated
to decomposition it emits toxic fumes of
Cl-. See also CHLOROSILANES. | [Hazardous Substances Data]
149-74-6(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
A colorless liquid. Insoluble in water and denser than water. Flash point between 70-140°F. Corrosive to skin and eyes and may be toxic by inhalation and skin absorption. Used to make other chemicals. | [Reactivity Profile]
Chlorosilanes, such as METHYLPHENYLDICHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases. | [Hazard]
Flammable, moderate fire risk, reactsstrongly with oxidizing materials. Irritant. | [Health Hazard]
The chemical is toxic and is an irritant. Contact may cause burns to the skin and eyes. | [Potential Exposure]
Used in the manufacture of silicones;
and as a chemical intermediate for silicone fluids, resins,
and elastomers | [Fire Hazard]
When heated to decomposition, METHYLPHENYLDICHLOROSILANE emits toxic fumes of chlorine-containing compounds. Flammable/combustible material; may be ignited by heat, sparks, or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Fire may produce irritating or poisonous gases. Reacts strongly with oxidizing materials. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR
if heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get
medical attention. If victim is conscious, administer water
or milk. Do not induce vomiting. | [Shipping]
UN2437 Methylphenyldichlorosilane, Hazard
class: 8; Labels: 8-Corrosive material | [Incompatibilities]
Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases,
strong acids, oxoacids, and epoxides. Chlorosilanes react
vigorously with bases and both organic and inorganic acids
generating toxic and/or flammable gases. Chlorosilanes
react with water, moist air, or steam to produce heat and
toxic, corrosive fumes of hydrogen chloride. They may also
produce flammable gaseous hydrogen. Contact with ammonia may form a self-igniting material. Attacks some metals
in the presence of moisture | [Description]
Dichloromethylphenyl-silane is a flammable,colorless liquid. Molecular weight=191.14; Boilingpoint=205℃; Freezing/Melting point: 2 52.7℃; Flashpoint=82℃. Hazard Identification (based on NFPA-704 MRating System): Health 3, Flammability 3, Reactivity 2 .Reacts with water. | [Chemical Properties]
CLEAR COLOURLESS LIQUID | [Chemical Properties]
Dichloromethylphenylsilane is a flammable,
colorless liquid. | [Flammability and Explosibility]
Notclassified | [storage]
Color Code—White: Corrosive or Contact Hazard;Store separately in a corrosion-resistant location. Prior toworking with methylphenyldichlorosilane you should betrained on its proper handling and storage. Store in tightlyclosed containers in a cool, well-ventilated area away frommoisture, oxidizers, and ammonia. Where possible, automatically pump liquid from drums or other storage containers to process containers. | [Purification Methods]
Methylphenyl dichlorosilane (dichloro methyl phenylsilane) [149-74-6] M 191.1, b 114 -115o/50mm, 202-205o/atm, d 4 1.17. Purify it by fractionation using an efficient column. It hydrolyses ca ten times more slowly than methyltrichlorosilane and ca sixty times more slowly than phenyltrichlorosilane. [Shaffer & Flanigen J Phys Chem 61 1591 1957, Beilstein 16 III 1211, 16 IV 1517.] |
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