Identification | More | [Name]
2-Amino-6-bromobenzothiazole | [CAS]
15864-32-1 | [Synonyms]
2-AMINO-6-BROMO BENTHIAZOLE 2-AMINO-6-BROMOBENZOTHIAZOLE 6-BROMO-1,3-BENZOTHIAZOL-2-AMINE 6-BROMO-1,3-BENZOTHIAZOL-2-YLAMINE 6-BROMOBENZO[D]THIAZOL-2-AMINE 6-BROMO-BENZOTHIAZOL-2-YLAMINE AKOS B000348 ART-CHEM-BB B000348 IFLAB-BB F1386-0398 6-bromo-2-benzothiazolamin 2-AMINO-6-BROMOBENZOTHAZOLE 6-Bromo-2-benzothiazolamine 6-Bromobenzothiazol-2-amine | [Molecular Formula]
C7H5BrN2S | [MDL Number]
MFCD00152229 | [Molecular Weight]
229.1 | [MOL File]
15864-32-1.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R22:Harmful if swallowed. R36:Irritating to the eyes. R43:May cause sensitization by skin contact. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37:Wear suitable protective clothing and gloves . | [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
IRRITANT | [HS Code ]
29342000 |
Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
2-Amino-6-bromobenzothiazole may be used in the synthesis of the following
- 2-amino-6-arylbenzothiazole compounds:
- 6-p-tolylbenzo[d]thiazole-2-amine
- 6-(4chlorophenyl)benzo[d]thiazole-2-amine
- 6-(4-methoxyphenyl)benzo[d]thiazole-2-amine
- 6-(3,5-bis(triflouromethyl)phenyl)benzo[d]thiazole-2-amine
- 6-phenylbenzo[d]thiazole-2-amine
It may be employed as a ligand (L) in the synthesis of organometallic derivatives of Rh(I) [Rh(CO)2(L)(Cl)]. | [General Description]
Reaction of 4-bromoaniline with acetic acid and potassium thiocynate in solution of bromine in acetic acid yields 2-amino-6-bromobenzothiazole. 2-Amino-6-bromobenzothiazole can also be synthesized from 2-aminobenzothiazole via monobromination with silica-supported quinolinium tribromide. |
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