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ChemicalBook--->CAS DataBase List--->15864-32-1

15864-32-1

15864-32-1 Structure

15864-32-1 Structure
IdentificationMore
[Name]

2-Amino-6-bromobenzothiazole
[CAS]

15864-32-1
[Synonyms]

2-AMINO-6-BROMO BENTHIAZOLE
2-AMINO-6-BROMOBENZOTHIAZOLE
6-BROMO-1,3-BENZOTHIAZOL-2-AMINE
6-BROMO-1,3-BENZOTHIAZOL-2-YLAMINE
6-BROMOBENZO[D]THIAZOL-2-AMINE
6-BROMO-BENZOTHIAZOL-2-YLAMINE
AKOS B000348
ART-CHEM-BB B000348
IFLAB-BB F1386-0398
6-bromo-2-benzothiazolamin
2-AMINO-6-BROMOBENZOTHAZOLE
6-Bromo-2-benzothiazolamine
6-Bromobenzothiazol-2-amine
[Molecular Formula]

C7H5BrN2S
[MDL Number]

MFCD00152229
[Molecular Weight]

229.1
[MOL File]

15864-32-1.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

213-217 °C (lit.)
[Boiling point ]

366.8±34.0 °C(Predicted)
[density ]

1.836±0.06 g/cm3(Predicted)
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[form ]

Powder
[pka]

3.30±0.10(Predicted)
[color ]

White
[CAS DataBase Reference]

15864-32-1(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Amino-6-bromobenzothiazole(15864-32-1)
[EPA Substance Registry System]

15864-32-1(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R36:Irritating to the eyes.
R43:May cause sensitization by skin contact.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

IRRITANT
[HS Code ]

29342000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Acetic acid-->Government regulation-->Sodium thiocyanate-->4-Bromoaniline-->2-Amino-7-bromobenzothiazole-->(3-Bromophenyl)thiourea
[Preparation Products]

6-BROMO-2-METHYL-1,3-BENZOTHIAZOLE-->6-BROMO-2-HYDRAZINO-1,3-BENZOTHIAZOLE-->6-Bromo-3-(prop-2-yn-1-yl)benzo[d]thiazol-2(3H)-imine-->6-bromo-N-cyclopropyl-1,3-benzothiazol-2-amine-->N-(6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzo[d]thiazol-2-yl)acetamide-->N-(6-BROMO-BENZOTHIAZOL-2-YL)-2-CHLORO-ACETAMIDE
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

2-Amino-6-bromobenzothiazole may be used in the synthesis of the following
  • 2-amino-6-arylbenzothiazole compounds:
  • 6-p-tolylbenzo[d]thiazole-2-amine
  • 6-(4chlorophenyl)benzo[d]thiazole-2-amine
  • 6-(4-methoxyphenyl)benzo[d]thiazole-2-amine
  • 6-(3,5-bis(triflouromethyl)phenyl)benzo[d]thiazole-2-amine
  • 6-phenylbenzo[d]thiazole-2-amine
It may be employed as a ligand (L) in the synthesis of organometallic derivatives of Rh(I) [Rh(CO)2(L)(Cl)].
[General Description]

Reaction of 4-bromoaniline with acetic acid and potassium thiocynate in solution of bromine in acetic acid yields 2-amino-6-bromobenzothiazole. 2-Amino-6-bromobenzothiazole can also be synthesized from 2-aminobenzothiazole via monobromination with silica-supported quinolinium tribromide.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Amino-6-bromobenzothiazole(15864-32-1)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

2-Amino-6-bromobenzothiazole, 98%(15864-32-1)
[Sigma Aldrich]

15864-32-1(sigmaaldrich)
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