Identification | More | [Name]
Ferric ammonium oxalate trihydrate | [CAS]
13268-42-3 | [Synonyms]
AMMONIUM IRON(III) OXALATE TRIHYDRATE, PURE, 98 Iron ammonium oxalate AMMONIUM IRON(III) OXALATE-3-HYDRATEPURE AMMONIUM IRON(III) OXALATE TRIHYDRATE, 99.99% Ammonium iron(III) oxalate trihydrate, 99.5% AMMONIUM IRON(III) OXALATE 3 H2O Ethanedioic acid, ammonium iron(3+) salt (3:3:1), trihydrate FERRICAMMONIUMOXALATE,GRANULAR Ammonium iron(III) oxalate trihydrate Ferric ammonium oxalate trihydrate Ammonium ferric oxalate, Iron ammonium oxalate AMMONIUM IRON(III) OXALATE TRIHYDRATE, 98%, PURE Ammonium iron(III) oxalate trihydrate, pure | [EINECS(EC#)]
220-952-2 | [Molecular Formula]
C4H10FeNO11 | [MDL Number]
MFCD00150137 | [Molecular Weight]
303.97 | [MOL File]
13268-42-3.mol |
Chemical Properties | Back Directory | [Appearance]
Ferric ammonium oxalate is a green crystalline, solid with a granular or salt-like appearance. Color
depends on level of iron present | [Melting point ]
161°C (rough estimate) | [density ]
1,78 g/cm3 | [solubility ]
very soluble in H2O; insoluble in ethanol | [form ]
Crystalline Powder | [color ]
Green | [Stability:]
May decompose upon exposure to light. Incompatible with strong acids, strong oxidizing agents. Hygroscopic. | [Water Solubility ]
Very soluble in water. Insoluble in alcohol | [Sensitive ]
Light Sensitive & Hygroscopic | [Merck ]
14,517 | [Exposure limits]
ACGIH: TWA 1 mg/m3 NIOSH: TWA 1 mg/m3 | [CAS DataBase Reference]
13268-42-3(CAS DataBase Reference) | [EPA Substance Registry System]
13268-42-3(EPA Substance) |
Safety Data | Back Directory | [Hazard Codes ]
C,Xn | [Risk Statements ]
R21/22:Harmful in contact with skin and if swallowed . R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S27:Take off immediately all contaminated clothing . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S25:Avoid contact with eyes . S24/25:Avoid contact with skin and eyes . | [RIDADR ]
3288 | [WGK Germany ]
1 | [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29171100 |
Hazard Information | Back Directory | [Potential Exposure]
Ferric ammonium oxalate is used in
photography and making blueprints | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce
vomiting. Do not make an unconscious person vomit. The
symptoms of metal fume fever may be delayed for
412 hours following exposure: it may last less than
36 hours. | [Shipping]
UN3288 Toxic solids, inorganic, n.o.s., Hazard
Class: 6.1; Labels: 6.1-Poisonous materials, Technical
Name Required | [Incompatibilities]
Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides. Strong oxidizers may cause
release of toxic phosphorus oxides. Organophosphates, in the
presence of strong reducing agents such as hydrides, may
form highly toxic and flammable phosphine gas. Keep away
from alkaline materials. | [Chemical Properties]
Ferric ammonium oxalate is a green crystalline, solid with a granular or salt-like appearance. Color
depends on level of iron present | [Chemical Properties]
yellow-green crystals | [Uses]
Ammonium iron(III) oxalate trihydrate is used in the preparation of Langmuir-Blodgett magnetic thin films. It is also involved in the production of blueprint paper. | [General Description]
Ammonium ferric oxalate trihydrate decomposes completely at 275°C giving Fe2O3 and has been investigated by thermogravimetry and differential thermal analysis. | [Purification Methods]
Crystallise it from hot water (0.5mL/g). [Beilstein 3 III 1103.] |
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