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ChemicalBook CAS DataBase List Methyl 2-furoate
611-13-2

Methyl 2-furoate synthesis

13synthesis methods
From 2-furoic acid in methanol solution in the presence of HCl as catalyst (oxidation or Carmizzaro reaction)
-

Yield:611-13-2 93%

Reaction Conditions:

with oxygen at 20; for 12 h;Irradiation;

Steps:

2.2.3. General procedure for the oxidative esterification of alcohols
General procedure: A 25 mL side-armed round bottomed flask equipped with a magneticstirring bar and a balloon filled with air was charged with alcohol(1 mmol), catalyst Pd(at)g-C3N4 (10 mg) and 5.0 mL of methanol. Thereaction mixture was exposed to visible light irradiation using 20-Wdomestic bulb. The progress of the reaction was monitored by TLC.After the completion of the reaction, Pd(at)g-C3N4 catalyst was separatedusing centrifuge. The product was extracted using ethyl acetate, driedover sodium sulfate, concentrated and characterized using NMR.

References:

Verma, Sanny;Nasir Baig;Nadagouda, Mallikarjuna N.;Varma, Rajender S. [Catalysis Today,2018,vol. 309,p. 248 - 252]

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