2-Methylfuran synthesis
- Product Name:2-Methylfuran
- CAS Number:534-22-5
- Molecular formula:C5H6O
- Molecular Weight:82.1
98-00-0
481 suppliers
$23.00/50g
534-22-5
305 suppliers
$10.00/5mL
Yield:534-22-5 90%
Reaction Conditions:
with formic acid;sulfuric acid;Pd/C in tetrahydrofuran;
Steps:
6
This example demonstrates that a catalytic amount of a strong acid is necessary for hydrogenolysis of formate esters generated from furfuryl alcohol and benyl alcohol. Neither alcohol underwent hydrogenolysis in the presence of formic acid and Pd/C in THF. However, addition of catalytic amounts of sulfuric acid (0.065 equivalents/ROH) to such solutions resulted in clean conversions to 2-methylfuran and toluene.
References:
US2011/263880,2011,A1 Location in patent:Page/Page column 12
98-01-1
496 suppliers
$22.00/25g
96-47-9
451 suppliers
$15.00/25mL
534-22-5
305 suppliers
$10.00/5mL
620-02-0
495 suppliers
$14.14/5gm:
534-22-5
305 suppliers
$10.00/5mL
98-01-1
496 suppliers
$22.00/25g
534-22-5
305 suppliers
$10.00/5mL