Gases under pressure: Compressed gas

Flammable gases, Category 1A, Flammable gas

Carcinogenicity, Category 1B

H225 Highly Flammable liquid and vapour

H280 Contains gas under pressure; may explode if heated

H302 Harmful if swallowed

H319 Causes serious eye irritation

H335 May cause respiratory irritation

H350 May cause cancer

P201 Obtain special instructions before use.

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P370+P378 In case of fire: Use … for extinction.

P403+P235 Store in a well-ventilated place. Keep cool.

P410+P403 Protect from sunlight. Store in a well-ventilated place.

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P203 Obtain, read and follow all safety instructions before use.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

P381 In case of leakage, eliminate all ignition sources.

P318 IF exposed or concerned, get medical advice.

P410+P403 Protect from sunlight. Store in a well-ventilated place.

P403 Store in a well-ventilated place.

P405 Store locked up.

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

no data available

Fresh air, rest. Refer for medical attention.

ON FROSTBITE: rinse with plenty of water, do NOT remove clothes.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Give one or two glasses of water to drink. Refer for medical attention .

Excerpt from ERG Guide 116P [Gases - Flammable (Unstable)]: Vapors may cause dizziness or asphyxiation without warning. Some may be toxic if inhaled at high concentrations. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases. (ERG, 2016)

Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary . Monitor for shock and treat if necessary . Anticipate seizures and treat if necessary . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal . Cover skin burns with dry sterile dressings after decontamination . Bromine, methyl bromide, and related compounds

To fight fire, use /carbon dioxide/, dry chemical, or water spray.

Excerpt from ERG Guide 116P [Gases - Flammable (Unstable)]: EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Silane (UN2203) will ignite spontaneously in air. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Vapors from liquefied gas are initially heavier than air and spread along ground. Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket. (ERG, 2016)

Use water spray, foam, carbon dioxide. In case of fire: keep cylinder cool by spraying with water.

Evacuate danger area! Personal protection: chemical protection suit including self-contained breathing apparatus. Ventilation. Remove all ignition sources. NEVER direct water jet on liquid. Remove fumes with fine water spray. Do NOT wash away into sewer.

Evacuate danger area! Personal protection: chemical protection suit including self-contained breathing apparatus. Ventilation. Remove all ignition sources.

PRECAUTIONS FOR "CARCINOGENS": A high-efficiency particulate arrestor (HEPA) or charcoal filters can be used to minimize amt of carcinogen in exhausted air ventilated safety cabinets, lab hoods, glove boxes or animal rooms ... Filter housing that is designed so that used filters can be transferred into plastic bag without contaminating maintenance staff is avail commercially. Filters should be placed in plastic bags immediately after removal ... The plastic bag should be sealed immediately ... The sealed bag should be labelled properly ... Waste liquids ... should be placed or collected in proper containers for disposal. The lid should be secured & the bottles properly labelled. Once filled, bottles should be placed in plastic bag, so that outer surface ... is not contaminated ... The plastic bag should also be sealed & labelled. ... Broken glassware ... should be decontaminated by solvent extraction, by chemical destruction, or in specially designed incinerators. Chemical Carcinogens

NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Fireproof. Cool. Keep in a well-ventilated room. Separated from oxidants. Store only if stabilized.Keep container in a well-ventilated place.

TLV: 0.5 ppm as TWA; A2 (suspected human carcinogen).EU-OEL: 4.4 mg/m3, 1 ppm as TWA

no data available

Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

Wear safety goggles or eye protection in combination with breathing protection.

Cold-insulating gloves. Protective clothing.

Use ventilation, local exhaust or breathing protection.

no data available

NIOSH considers vinyl bromide to be a potential occupational carcinogen.

Reacts violently with oxidants. Decomposes on burning. This produces toxic gases. The substance polymerizes under the influence of heat and light.

no data available

A VERY DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME.The vapour is heavier than air.VINYL BROMIDE is a light sensitive, peroxidizable monomer may initiate exothermic polymerization of the bulk material [Handling Chemicals Safely 1980.. p. 958]. It will react violently with oxidants.

no data available

Reacts violently with oxidants .

When strongly heated, they emit highly toxic fumes of /hydrogen bromide/.

no data available

no data available

no data available

no data available

Evaluation: No epidemiological data relevant to the carcinogenicity of vinyl bromide were available. There is sufficient evidence in experimental animals for the carcinogenicity of vinyl bromide. Overall evaluation: Vinyl bromide is probably carcinogenic to humans (Group 2A). In making the overall evaluation, the Working Group took into consideration that all available studies showed a consistently parallel response between vinyl bromide and vinyl chloride. In addition, both vinyl chloride and vinyl bromide are activated via P450 dependent pathway to their corresponding epoxides. For both vinyl chloride and vinyl bromide, the covalent binding of these compounds to DNA forms the respective etheno adducts. The weight of positive evidence for both compounds was also noted among the studies for genotoxicity, although the number and variety of tests for vinyl bromide were fewer.

No information is available on the reproductive or developmental effects of vinyl bromide in animals or humans.

Rapid evaporation of the liquid may cause frostbite. The substance is irritating to the eyes. The substance may cause effects on the central nervous system.

This substance is probably carcinogenic to humans.

A harmful concentration of this gas in the air will be reached very quickly on loss of containment.

no data available

An estimated BCF of 3 was calculated for vinyl bromide(SRC), using a log Kow of 1.57(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

The Koc of vinyl bromide is estimated as 170(SRC), using a log Kow of 1.57(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that vinyl bromide is expected to have moderate mobility in soil(SRC).

no data available

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

ADR/RID: UN1085 (For reference only, please check.)

IMDG: UN1085 (For reference only, please check.)

IATA: UN1085 (For reference only, please check.)

ADR/RID: VINYL BROMIDE, STABILIZED (For reference only, please check.)

IMDG: VINYL BROMIDE, STABILIZED (For reference only, please check.)

IATA: VINYL BROMIDE, STABILIZED (For reference only, please check.)

ADR/RID: 2.1 (For reference only, please check.)

IMDG: 2.1 (For reference only, please check.)

IATA: 2.1 (For reference only, please check.)

ADR/RID: (For reference only, please check.)

IMDG: (For reference only, please check.)

IATA: (For reference only, please check.)

ADR/RID: No

IMDG: No

IATA: No

no data available

no data available

An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.