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Analytical Chemistry

Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Structure Chemical Name CAS MF
HEPTACHLOR HEPTACHLOR 76-44-8 C10H5Cl7
Novaluron Novaluron 116714-46-6 C17H9ClF8N2O4
Chlortalidone Chlortalidone 77-36-1 C14H11ClN2O4S
(1S)-(+)-3-Carene (1S)-(+)-3-Carene 498-15-7 C10H16
N-NITROSOMORPHOLINE N-NITROSOMORPHOLINE 59-89-2 C4H8N2O2
GLOBULINS, CAT GAMMA GLOBULINS, CAT GAMMA 9007-83-4
N-(2-Ethylhexyl)-5-norbornene-2,3-dicarboximide N-(2-Ethylhexyl)-5-norbornene-2,3-dicarboximide 113-48-4 C17H25NO2
10E,12Z-octadecadienoic acid 10E,12Z-octadecadienoic acid 2420-56-6 C18H32O2
(1R,2R,5R)-(+)-2-Hydroxy-3-pinanone (1R,2R,5R)-(+)-2-Hydroxy-3-pinanone 24047-72-1 C10H16O2
GLIOTOXIN GLIOTOXIN 67-99-2 C13H14N2O4S2
N-CAPROIC ACID SODIUM SALT N-CAPROIC ACID SODIUM SALT 10051-44-2 C6H11NaO2
2,3,4-TRICHLOROPHENOL 2,3,4-TRICHLOROPHENOL 15950-66-0 C6H3Cl3O
PARAOXON PARAOXON 311-45-5 C10H14NO6P
DISPERSE ORANGE 3 DISPERSE ORANGE 3 730-40-5 C12H10N4O2
TERPIN MONOHYDRATE TERPIN MONOHYDRATE 2451-01-6 C10H22O3
Pamabrom Pamabrom 606-04-2 C11H18BrN5O3
Safflower oil Safflower oil 8001-23-8 NULL
2-(1-NAPHTHYL)-5-PHENYLOXAZOLE 2-(1-NAPHTHYL)-5-PHENYLOXAZOLE 846-63-9 C19H13NO
7-Amino-3-(1,2,3-triazol-4-ylthio)methyl cephalosporanic acid 7-Amino-3-(1,2,3-triazol-4-ylthio)methyl cephalosporanic acid 37539-03-0 C10H11N5O3S2
METHYL RICINOLEATE METHYL RICINOLEATE 141-24-2 C19H36O3
FENCHOL FENCHOL 1632-73-1 C10H18O
DEOXYNIVALENOL DEOXYNIVALENOL 51481-10-8 C15H20O6
Nitrosobenzene Nitrosobenzene 586-96-9 C6H5NO
3-CARBAMYL-1-METHYLPYRIDINIUM CHLORIDE 3-CARBAMYL-1-METHYLPYRIDINIUM CHLORIDE 1005-24-9 C7H9ClN2O
Clopamide Clopamide 636-54-4 C14H20ClN3O3S
Clobetasone butyrate Clobetasone butyrate 25122-57-0 C26H32ClFO5
2-[4-Aminosulfonyl-phenyl]-ethyl-5-methylpyrazinecarboxamide 2-[4-Aminosulfonyl-phenyl]-ethyl-5-methylpyrazinecarboxamide 33288-71-0 C14H16N4O3S
ELAIDIC ACID METHYL ESTER ELAIDIC ACID METHYL ESTER 1937-62-8 C19H36O2
N-(4-AMINOBUTYL)-2-NAPHTHALENESULFONAMIDE HYDROCHLORIDE N-(4-AMINOBUTYL)-2-NAPHTHALENESULFONAMIDE HYDROCHLORIDE 89108-46-3 C14H19ClN2O2S
INDENO(1,2,3-C,D)PYRENE INDENO(1,2,3-C,D)PYRENE 193-39-5 C22H12
PONCEAU 3R PONCEAU 3R 3564-09-8 C19H19N2NaO7S2
8-METHYLNONANOIC ACID 8-METHYLNONANOIC ACID 5963-14-4 C10H20O2
CARAZOLOL HCL CARAZOLOL HCL 57775-29-8 C18H22N2O2
Somatotropin Somatotropin 12629-01-5 C990H1529N263O299S7
Prednisolone succinate Prednisolone succinate 2920-86-7 C25H32O8
FMOC-HYDRAZIDE HCL FMOC-HYDRAZIDE HCL 35661-51-9 C15H14N2O2
Trinexapac-ethyl Trinexapac-ethyl 95266-40-3 C13H16O5
Etifenin Etifenin 63245-28-3 C16H22N2O5
MECOPROP MECOPROP 7085-19-0 C10H11ClO3
3-Pyridyl dimethylcarbamate 3-Pyridyl dimethylcarbamate 51581-32-9 C8H10N2O2
N-(2,2,2-TRICHLOROETHOXYCARBONYLOXY)SUCCINIMIDE N-(2,2,2-TRICHLOROETHOXYCARBONYLOXY)SUCCINIMIDE 66065-85-8 C7H6Cl3NO5
ETIZOLAM ETIZOLAM 40054-69-1 C17H15ClN4S
4-Nitro-7-(1-piperazinyl)-2,1,3-benzoxadiazole 4-Nitro-7-(1-piperazinyl)-2,1,3-benzoxadiazole 139332-66-4 C10H11N5O3
5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE 5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE 25440-14-6 C44H10F20N4
Propisochlor Propisochlor 86763-47-5 C15H22ClNO2
CORTICOSTERONE 21-ACETATE CORTICOSTERONE 21-ACETATE 1173-26-8 C23H32O5
(R)-(-)-1-Cyclohexylethylamine (R)-(-)-1-Cyclohexylethylamine 5913-13-3 C8H17N
METHYL MELISSATE METHYL MELISSATE 629-83-4 C31H62O2
4-TRIFLUOROACETYL-3-METHYL-1-PHENYL-5-PYRAZOLONE 4-TRIFLUOROACETYL-3-METHYL-1-PHENYL-5-PYRAZOLONE 1691-93-6 C12H9F3N2O2
trans-caffeic acid trans-caffeic acid 501-16-6 C9H8O4
DICYCLOMINE HYDROCHLORIDE DICYCLOMINE HYDROCHLORIDE 67-92-5 C19H36ClNO2
2,9-DIMETHYL-1,10-PHENANTHROLINE HEMIHYDRATE 2,9-DIMETHYL-1,10-PHENANTHROLINE HEMIHYDRATE 34302-69-7 C14H14N2O
(R)-(+)-1-PHENYL-1-PROPANOL (R)-(+)-1-PHENYL-1-PROPANOL 1565-74-8 C9H12O
7-(2-HYDROXYETHYL)THEOPHYLLINE 7-(2-HYDROXYETHYL)THEOPHYLLINE 519-37-9 C9H12N4O3
PHTHALIC ACID MONOBENZYL ESTER PHTHALIC ACID MONOBENZYL ESTER 2528-16-7 C15H12O4
Cetyltrimethylammonium hydrogensulfate Cetyltrimethylammonium hydrogensulfate 68214-07-3 C19H43NO4S
KANAMYCIN ACID SULFATE KANAMYCIN ACID SULFATE 64013-70-3 C18H40N4O19S2
4,4'-Dihydroxytetraphenylmethane 4,4'-Dihydroxytetraphenylmethane 1844-01-5 C25H20O2
ETRIDIAZOLE ETRIDIAZOLE 2593-15-9 C5H5Cl3N2OS
GRAM'S IODINE GRAM'S IODINE 12298-68-9 I3K
O-(4-NITROBENZYL)-N,N'-DIISOPROPYLISOUREA O-(4-NITROBENZYL)-N,N'-DIISOPROPYLISOUREA 2978-11-2 C14H21N3O3
CARFENTRAZONE-ETHYL CARFENTRAZONE-ETHYL 128639-02-1 C15H14Cl2F3N3O3
ISOBUTYRALDEHYDE 2,4-DINITROPHENYLHYDRAZONE ISOBUTYRALDEHYDE 2,4-DINITROPHENYLHYDRAZONE 2057-82-1 C10H12N4O4
CIS-CHLORDANE CIS-CHLORDANE 5103-71-9 C10H6Cl8
AZINPHOS-METHYL AZINPHOS-METHYL 86-50-0 C10H12N3O3PS2
Formoterol fumarate dihydrate Formoterol fumarate dihydrate 183814-30-4 C23H28N2O8
7H-DIBENZO[C,G]CARBAZOLE 7H-DIBENZO[C,G]CARBAZOLE 194-59-2 C20H13N
DINOTERB DINOTERB 1420-07-1 C10H12N2O5
AFLATOXIN B2 AFLATOXIN B2 7220-81-7 C17H14O6
2-Methyl-4-nitroimidazole 2-Methyl-4-nitroimidazole 696-23-1 C4H5N3O2
Fluphenazine decanoate Fluphenazine decanoate 5002-47-1 C32H44F3N3O2S
1-Isobutyl-4-piperidone 1-Isobutyl-4-piperidone 72544-16-2 C9H17NO
6-HYDROXYCHLORZOXAZONE 6-HYDROXYCHLORZOXAZONE 1750-45-4 C7H4ClNO3
Oxethazaine Oxethazaine 126-27-2 C28H41N3O3
TEOC-ONP TEOC-ONP 80149-80-0 C12H17NO5Si
TRANS-NONACHLOR TRANS-NONACHLOR 39765-80-5 C10H5Cl9
(2-METHOXYETHOXYMETHYL)TRIETHYLAMMONIUM CHLORIDE (2-METHOXYETHOXYMETHYL)TRIETHYLAMMONIUM CHLORIDE 60043-43-8 C10H24ClNO2
1-(2-THIAZOLYLAZO)-2-NAPHTHOL 1-(2-THIAZOLYLAZO)-2-NAPHTHOL 1147-56-4 C13H9N3OS
Cymiazole Cymiazole 61676-87-7 C12H14N2S
Dinotefuran Dinotefuran 165252-70-0 C7H14N4O3
4-Acetoxyacetanilide 4-Acetoxyacetanilide 2623-33-8 C10H11NO3
Benoxacor Benoxacor 98730-04-2 C11H11Cl2NO2
4,4'-DICHLOROBIPHENYL 4,4'-DICHLOROBIPHENYL 2050-68-2 C12H8Cl2
Terconazole Terconazole 67915-31-5 C26H31Cl2N5O3
N-PENTYL PROPIONATE N-PENTYL PROPIONATE 624-54-4 C8H16O2
Metobromuron Metobromuron 3060-89-7 C9H11BrN2O2
3-(4-METHYLBENZYLIDENE)CAMPHOR 3-(4-METHYLBENZYLIDENE)CAMPHOR 36861-47-9 C18H22O
(+/-)-alpha-Lipoamide (+/-)-alpha-Lipoamide 940-69-2 C8H15NOS2
Cellulose acetate phthalate Cellulose acetate phthalate 9004-38-0 C116H116O64
NITARSONE NITARSONE 98-72-6 C6H6AsNO5
PHENTERMINE HYDROCHLORIDE PHENTERMINE HYDROCHLORIDE 1197-21-3 C10H16ClN
Valencene Valencene 4630-07-3 C15H24
TETRAPHENYLPHOSPHONIUM TETRAPHENYLBORATE TETRAPHENYLPHOSPHONIUM TETRAPHENYLBORATE 15525-15-2 C48H40BP
NEOTHORIN NEOTHORIN 3547-38-4 C16H11AsN2Na2O11S2
25-HYDROXYVITAMIN D2 25-HYDROXYVITAMIN D2 21343-40-8 C28H44O2
PALM OIL PALM OIL 8002-75-3
Metalaxyl-M Metalaxyl-M 70630-17-0 C15H21NO4
Vardenafil dihydrochloride Vardenafil dihydrochloride 224789-15-5 C23H33ClN6O4S
cis-11-Eicosenoic acid cis-11-Eicosenoic acid 5561-99-9 C20H38O2
Hydroxysafflor yellow A Hydroxysafflor yellow A 78281-02-4 C27H32O16
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