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1,2-Dimethoxy-4-(2-propenyl)benzol

Methyl eugenol Struktur
93-15-2
CAS-Nr.
93-15-2
Bezeichnung:
1,2-Dimethoxy-4-(2-propenyl)benzol
Englisch Name:
Methyl eugenol
Synonyma:
4-ALLYL-1,2-DIMETHOXYBENZENE;EUGENOL METHYL ETHER;1,2-DIMETHOXY-4-(2-PROPENYL)BENZENE;EUGENYL METHYL ETHER;jiaji;O-Methyleugenol;Benzene, 1,2-dimethoxy-4-(2-propenyl)-;3-METHYLEUGENOL;4-Allylveratrol;4-ALLYLVERATROLE
CBNumber:
CB8198972
Summenformel:
C11H14O2
Molgewicht:
178.23
MOL-Datei:
93-15-2.mol

1,2-Dimethoxy-4-(2-propenyl)benzol Eigenschaften

Schmelzpunkt:
-4 °C (lit.)
Siedepunkt:
254-255 °C (lit.)
Dichte
1.036 g/mL at 25 °C (lit.)
Dampfdruck
0.463-1.983Pa at 25℃
Brechungsindex
n20/D 1.534(lit.)
Flammpunkt:
>230 °F
storage temp. 
2-8°C
L?slichkeit
0.5g/l
Aggregatzustand
Oil
Farbe
Colourless to Pale Yellow
Geruch (Odor)
at 1.00 % in dipropylene glycol. sweet fresh warm spicy clove carnation cinnamon
Geruchsart
spicy
Wasserl?slichkeit
insoluble
Merck 
14,6073
BRN 
1910871
Stabilit?t:
Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey
ZYEMGPIYFIJGTP-UHFFFAOYSA-N
LogP
2.74-3.03
CAS Datenbank
93-15-2(CAS DataBase Reference)
IARC
2B (Vol. 101) 2013
NIST chemische Informationen
Benzene, 1,2-dimethoxy-4-(2-propenyl)-(93-15-2)
EPA chemische Informationen
Methyleugenol (93-15-2)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xn
R-S?tze: 22-36/37/38-40
S-S?tze: 26-36/37/39
WGK Germany  1
RTECS-Nr. CY2450000
HS Code  29093090
Giftige Stoffe Daten 93-15-2(Hazardous Substances Data)
Toxizit?t LD50 orally in rats: 1560 mg/kg (Jenner)
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitssch?dlich bei Verschlucken. Akute Toxizit?t oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
H341 Kann vermutlich genetische Defekte verursachen. Keimzellmutagenit?t Kategorie 2 Warnung P201,P202, P281, P308+P313, P405,P501
H351 Kann vermutlich Krebs verursachen. Karzinogenit?t Kategorie 2 Warnung P201, P202, P281, P308+P313, P405,P501
H411 Giftig für Wasserorganismen, mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 2
Sicherheit
P201 Vor Gebrauch besondere Anweisungen einholen.
P273 Freisetzung in die Umwelt vermeiden.
P308+P313 BEI Exposition oder falls betroffen: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen.

1,2-Dimethoxy-4-(2-propenyl)benzol Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R22:Gesundheitssch?dlich beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R40:Verdacht auf krebserzeugende Wirkung.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.

Chemische Eigenschaften

colourless to light yellow liquid

Occurrence

Reported in the essential oils of Myrtaceae and Luraceae; it was identifed originally in the essential oil from roots of Asarum europaeum L and Asarum canadense L Subsequently, it was identifed as the main constituent of the oil from wood of Dacrydium franklinii Hook (97 5%), in Melaleuca bracteata F v M (leaves, 90 to 95%), in Cinnamomum oliveri Bail (leaves, 90 to 95%), and as a minor constituent in the oils of betel, citronella, Japanese calamus, pimenta, hyacinth, rose, basil, bay, cajeput and others Reported found in heated blackberry, pepper, lovage seed, chervil, lemon balm, alpinia species, clove buds, nutmeg, pepper, mace, tarragon, Ocimum sanctum, laurel, myrtle leaf and berry, rosemary, pimento berry and mastic gum leaf oil

Verwenden

Methyl eugenol may be used as an analytical reference standard for the quantification of the analyte in the following:????????
  • Essential oil of Pimenta pseudocaryophyllus using high-performance liquid chromatography (HPLC). The purity of the extracted compound is then determined by gas chromatography coupled to flame ionization detector (GC/FID).???????
  • Stem bark of Cinnamomum zeylanicum Blume using reversed-phase high-performance liquid chromatography (RP-HPLC) with UV-visible detection.???????
  • Rosa hybrida using gas-chromatography coupled to mass spectrometry (GC-MS) technique.

synthetische

Usually prepared by methylation of eugenol.

Allgemeine Beschreibung

Clear colorless to pale yellow liquid with a spicy earthy odor. Bitter burning taste.

Air & Water Reaktionen

Insoluble in water.

Reaktivit?t anzeigen

Methyl eugenol is incompatible with strong oxidizers . May react exothermically with reducing agents to release hydrogen gas.

Hazard

Possible carcinogen.

Brandgefahr

Methyl eugenol is combustible.

Sicherheitsprofil

Confirmed carcinogen. Poison by intravenous route. Moderately toxic by ingestion and intraperitoneal routes. A skin irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. Some other alkenylbenzenes have carcinogenic activity. See also EUGENOL, ALLYL COMPOUNDS, and ETHERS

m?gliche Exposition

Methyl eugenol is a naturally occurring substance found in the essential oils of several plant species. Methyleugenol is used as a flavoring agent in jellies, baked goods, nonalcoholic beverages, chewing gum, candy, pudding, relish, and ice cream. Methyleugenol has been used as an anesthetic in rodents. It also is used as an insect attractant in combination with insecticides.

Carcinogenicity

Methyleugenol is reasonably anticipated to be a human carcinogenbased on sufficient evidence of carcinogenicity from studies in experimental animals.

Solubility in organics

Soluble in alcohol and oils

Versand/Shipping

UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

l?uterung methode

Recrystallise the ether from hexane at low temperature and redistil it (preferably in vacuo). [Hillmer & Schorning Z Phys Chem [A] 167 407 1934, Briner & Fliszár Helv Chim Acta 42 2063 1959, Beilstein 6 H 963, 6 IV 6337.]

Inkompatibilit?ten

Methyleugenol is Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with reducing agents may cause the release of hydrogen gas

Waste disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

1,2-Dimethoxy-4-(2-propenyl)benzol Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


1,2-Dimethoxy-4-(2-propenyl)benzol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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93-15-2(1,2-Dimethoxy-4-(2-propenyl)benzol)Verwandte Suche:


  • 1-ALLYL-3,4-DIMETHOXYBENZENE
  • Eugenolmethylether,98%
  • Methyl eugenol (technical)
  • 1-ALLYL-3,4-DIMETHYOXYBENZENE
  • methyleugenol,1,2-dimethoxy-4-(2-propenyl)-benzene,veratrolemethylether
  • 1-ALLYL-3,4-DIMENTHOXYBENZENE
  • Eugenol methyl ether Methyl eugenol
  • EUGENOL METHYLETHER WITH GC
  • Methyl Eugenol/Eugenol methyl ether
  • METHYL EUGENOL 98+% FCC
  • EUGENOL METHYL ETHER 99%
  • eugenal methyl ether
  • METHYL EUGENOL extrapure
  • 1,3,4-Eugenol methyl ether
  • 1,3,4-eugenolmethylether
  • 4-allyl-1,2-dimethoxy-benzen
  • 4-Allyl-1,2-dimethyoxybenzene
  • Allyl veratrole
  • Allyl-1,2-dimethoxybenzene
  • Benzene, 4-(2-propenyl)-1,2-dimethoxy
  • Benzene, 4-allyl-1,2-dimethoxy-
  • Dimethoxy-4-(2-propenyl)benzene
  • Ent 21040
  • ent21040
  • 4-Allyl-1,2-dimethoxybenzene, Eugenol methyl ether
  • 1,2-Dimethoxy-4-(2-propenyl)benzene,98%
  • 1-(3,4-Dimethoxyphenyl)-2-propen
  • 1,2-dimethoxy-4-(2-propenyl)-benzen
  • 1,2-Dimethoxy-4-allylbenzene
  • Eugenol Methyl Ether 1-Allyl-3,4-dimethoxybenzene
  • Methyl eugenol ,98%
  • 4-Allyl-1.2-dimethoxybenzene 1g [93-15-2]
  • 4-Allyl-1,2-dimethoxybenzene,4-Allyl-1,2-dimethoxybenzene, Eugenol methyl ether
  • Methyl eugenol,4-Allyl-1,2-dimethoxybenzene, Eugenol methyl ether, Eugenyl methyl ether
  • LEVO-ROSE OXIDE
  • 1,2-DiMethoxy-4-(2-propenyl)benzene, 98% 100ML
  • Eugenol Methyl Ether Methyleugenol 4-Allylveratrole
  • Allyl-3,4-diMethoxybenzene
  • Benzene,1,2-diMethoxy-4-(2-propen-1-yl)-
  • Eugenol-Methyl
  • TIMTEC-BB SBB007916
  • 1-(3,4-Dimethoxyphenyl)-2-propene
  • femanumber2475
  • Methyl eugenol ether
  • Methyl eugenyl ether
  • methyleugenylether
  • o-Methyl eugenol ether
  • Veratrole methyl ether
  • veratrolemethylether
  • METHYL EUGENOL
  • FEMA 2475
  • 3,4-DIMETHOXYALLYLBENZENE
  • 3-(3,4-DIMETHOXYPHENYL)-1-PROPENE
  • Eugenol Impurity 5(Eugenol EP Impurity E)
  • 4-Allyl-1,2-dimethoxybenzene>
  • Methyleugenol@1000 μg/mL in EtOH
  • 1,2-dimethoxy-4-(prop-2-en-1-yl)benzene
  • Methyl eugenol USP/EP/BP
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