天堂网亚洲,天天操天天搞,91视频高清,菠萝蜜视频在线观看入口,美女视频性感美女视频,95丝袜美女视频国产,超高清美女视频图片

N-BOC-1,6-diaminohexane

N-BOC-1,6-diaminohexane Struktur
51857-17-1
CAS-Nr.
51857-17-1
Englisch Name:
N-BOC-1,6-diaminohexane
Synonyma:
tert-Butyl (6-aMinohexyl)carbaMate;N-BOC-1,6-DIAMINOHEXANE;N-BOC-1,6-HEXANEDIAMINE;TERT-BUTYL N-(6-AMINOHEXYL)CARBAMATE;tert-butyl (6-aMinohexyl)carbaMate hydrochloride;AURORA KA-7567;AURORA KA-7545;AURORA KA-4392;Boc-NH-(CH2)6-NH2;TIMTEC-BB SBB006530
CBNumber:
CB0702254
Summenformel:
C11H24N2O2
Molgewicht:
216.32
MOL-Datei:
51857-17-1.mol

N-BOC-1,6-diaminohexane Eigenschaften

Siedepunkt:
106-110 °C (0.3 mmHg)
Dichte
0.965 g/mL at 20 °C(lit.)
Brechungsindex
n20/D 1.462
Flammpunkt:
125 °C
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
L?slichkeit
Soluble in dichloromethane and ethyl acetate.
pka
12.93±0.46(Predicted)
Aggregatzustand
Viscous Liquid
Farbe
Clear light yellow
Sensitive 
Air Sensitive
BRN 
2089264
InChIKey
RVZPDKXEHIRFPM-UHFFFAOYSA-N
CAS Datenbank
51857-17-1(CAS DataBase Reference)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher C
R-S?tze: 34
S-S?tze: 26-36/37/39-45
RIDADR  UN 2735 8/PG 2
WGK Germany  3
10-34
HazardClass  8
PackingGroup  III
HS Code  29241900
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H314 Verursacht schwere Ver?tzungen der Haut und schwere Augensch?den. ?tzwirkung auf die Haut Kategorie 1B Achtung GHS hazard pictogramssrc="/GHS05.jpg" width="20" height="20" /> P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Sicherheit
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P303+P361+P353 BEI BERüHRUNG MIT DER HAUT (oder dem Haar): Alle kontaminierten Kleidungsstücke sofort ausziehen. Haut mit Wasser abwaschen oder duschen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.
P363 Kontaminierte Kleidung vor erneutem Tragen waschen.
P405 Unter Verschluss aufbewahren.

N-BOC-1,6-diaminohexane Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R34:Verursacht Ver?tzungen.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).

Chemische Eigenschaften

Off-White Solid

Verwenden

N-Boc-1,6-diaminohexane is used to prepare 1,3-Bis[6-(Boc-amino)hexyl]urea by reacting with carbonyl dichloride in the presence of triethylamine. Further, it is used as a reagent for the introduction of a C6-spacer.

Application

N-Boc-1,6-hexanediamine can be used as a linear hexyl spacer (C6-spacer) to synthesize:
Biodegradable poly(disulfide amine)s for gene delivery.
A multifunctional dendrimer for theranostics.
Polyamide platinum anti-cancer complexes designed to target cancer specific DNA sequences.
Self-assembled monolayers (SAMs) that resist adsorption of proteins.
[N-(6-(4-Hydroxy-6-isopropylamino-1,3,5-triazin-2-ylamino)hexyl)-5-hydroxy-1,4-naphthoquinone-3-propionamide] (JUG-HATZ), which can be used in designing electrochemical immunosensors.

synthetische

synthesis of N-BOC-1,6-diaminohexane: 1,6-Diaminohexane 3 (Fig. 1) (100 g, 0.86 mol) was dissolved in CH2Cl2 (300 ml) and cooled in an ice bath to 0–3°C. To the stirred solution 0.3 eq. di-tert-butyl bicarbonate (62.6 g, 0.29 mol) was added slowly over a period of 1 h. The reaction was allowed to warm up to r.t., and proceeded overnight. The reaction mixture was extracted with saturated aqueous NaHCO3 (50 ml, three times). The organic phases were pooled, dried, and evaporated under reduced pressure. The resulting oil was dissolved in 200 ml, 1 N HCl and extracted with ether. The aqueous phase was washed with ether, made basic to a pH of 10 with aqueous 2 N NaO3, and extracted with ethyl acetate. The organic phases were pooled, dried, and evaporated under reduced pressure. The resulting oil was dissolved in 200 ml, 1 N HCL and extracted with ether. The aqueous phase was washed with ether, made basic to a pH of 10 with aqueous 2 N NaOH, and extracted with ethyl acetate. The organic extracts were pooled, dried over Na2SO4 and evaporated to give 10.5 g of homogeneous N-BOC-1, 6- diaminohexane 2c (Fig. 1) as a yellow oil which was used without further purification.
TLC Rf 0.51; 1H NMR (CDCL3) d 4.54 (bs, 1H; NH), 3.05 1 2.62 (m, 4H; NCH2), 1.41 (m, 9H; CH3), 1.29 (m, 8H; CH2).
Evaluation of aminoalkylmethacrylate nanoparticles as colloidal drug carrier systems. Part I: synthesis of monomers, dependence of the physical properties on the polymerization methods

N-BOC-1,6-diaminohexane Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


N-BOC-1,6-diaminohexane Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 205)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21634 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795
ivan@atkchemical.com China 32957 60
Jinan Carbotang Biotech Co.,Ltd.
+8615866703830
figo.gao@foxmail.com China 8497 58
Accela ChemBio Inc.
+1-858-6993322
info@accelachem.com United States 17777 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873
sales@chemdad.com China 39894 58
Alchem Pharmtech,Inc.
8485655694
sales@alchempharmtech.com United States 63687 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 49374 58
career henan chemical co
+86-0371-86658258 +8613203830695
factory@coreychem.com China 29811 58
TargetMol Chemicals Inc.
+1-781-999-5354 +1-00000000000
marketing@targetmol.com United States 32161 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763
sales@tnjchem.com China 34563 58

51857-17-1()Verwandte Suche:


  • AURORA KA-4392
  • AURORA KA-7545
  • AURORA KA-7567
  • TIMTEC-BB SBB006530
  • N-(6-AMINOHEXYL)CARBAMIC ACID TERT-BUTYL ESTER
  • N-(TERT-BUTOXYCARBONYL)-1,6-DIAMINOHEXANE
  • N-(TERT-BUTOXYCARBONYL)-1,6-HEXANEDIAMINE
  • 1-BOC-AMINO-1,6-HEXANEDIAMINE
  • 1-BOC-1,6-DIAMINOHEXANE
  • (6-Aminohexyl)carbamic Acid tert-Butyl Ester
  • 1-((tert-Butoxycarbonyl)amino)-6-aminohexane
  • N-(6-Aminohexyl)-carbamic Acid 1,1-Dimethylethyl Ester
  • n-(tert-butoxycarbonyl)hexamethylenediamine
  • N-tert-Butoxycarbonyl-1,6-hexanediamine N-Boc-1,6-diaminohexane N-(6-Aminohexyl)carbamic acid tert-butyl ester tert-butyl 6-aminohexylcarbamate
  • N-t-BOC-1,6-HEXANEDIAMINE
  • N-Boc-1,6-diaminohexane, tert-Butyl-N-(6-aminohexyl)carbamate
  • (6-Aminohexyl)carbamic acid 1,1-dimethylethyl ester
  • N-(tert-Butoxycarbonyl)hexane-1,6-diamine
  • N-(6-Aminohexyl)carbamic Acid tert-Butyl Ester N-Boc-1,6-diaminohexane N-Boc-1,6-hexanediamine N-(tert-Butoxycarbonyl)-1,6-hexanediamine tert-Butyl N-(6-Aminohexyl)carbamate
  • N-Boc-1,6-hexanediaMine 98%
  • N-(tert-Butoxycarbonyl)-1,6-diaMinohexane, 95.0%(GC)
  • N-Boc-1,6-hexanediamine >=98.0% (GC)
  • N-tert-Butoxycarbonyl-1,6-hexanediamine,95%
  • N-(tert-Butoxycarbonyl)-1,6-diaminohexane >
  • Carbamic acid, N-(6-aminohexyl)-, 1,1-dimethylethyl ester
  • )-1,6-diaminohexane
  • N-tert-Butoxycarbonyl-1,6-hexanediamine ISO 9001:2015 REACH
  • TERT-BUTYL N-(6-AMINOHEXYL)CARBAMATE
  • N-BOC-1,6-DIAMINOHEXANE
  • N-BOC-1,6-HEXANEDIAMINE
  • tert-Butyl (6-aMinohexyl)carbaMate
  • tert-butyl (6-aMinohexyl)carbaMate hydrochloride
  • NH2C6NHBoc,linker,NH2 C6 NH Boc,NH-2-C6-NH-Boc,inhibit,Inhibitor,PROTAC Linkers,PROTAC,Mcl-1
  • Boc-NH-(CH2)6-NH2
  • 51857-17-1
  • 51857-17-7
  • C11H24N2O2
  • CH33COCONHCH26NH2
  • C11H25N2O2
  • Organic Building Blocks
  • Nitrogen Compounds
  • Protected Amines
  • N-Boc-diaminoalkanes
  • Monoprotected Diaminoalkanes
  • Building Blocks
  • All Aliphatics
  • Monoprotected Diaminoalkanes
  • N-Boc-diaminoalkanes
  • Aliphatics
  • Amines
Copyright 2019 ? ChemicalBook. All rights reserved