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ChemicalBook--->CAS DataBase List--->94-70-2

94-70-2

94-70-2 Structure

94-70-2 Structure
IdentificationMore
[Name]

o-Phenetidine
[CAS]

94-70-2
[Synonyms]

1-amino-2-ethoxybenzene
2-Aminoethoxybenzene
2-AMINOPHENETOL
2-AMINOPHENETOLE
2-ETHOXYANILINE
2-ETHOXYBENZAMINE
2-ETHOXYBENZENAMINE
2-PHENETIDINE
AKOS 91146
AKOS BBS-00003548
LABOTEST-BB LTBB000532
o-
O-ETHOXYANILINE
O-PHENETIDINE
TIMTEC-BB SBB006726
2-ethoxy-benzenamin
2-ethoxyphenylamine
Benzenamine,2-ethoxy-
o-Aminophenetole
o-Aminophenolethylether
[EINECS(EC#)]

202-356-4
[Molecular Formula]

C8H11NO
[MDL Number]

MFCD00007689
[Molecular Weight]

137.18
[MOL File]

94-70-2.mol
Chemical PropertiesBack Directory
[Appearance]

deep red liquid
[Melting point ]

-20 °C
[Boiling point ]

231-233 °C(lit.)
[density ]

1.051 g/mL at 25 °C(lit.)
[vapor pressure ]

1 mm Hg ( 67 °C)
[refractive index ]

n20/D 1.555(lit.)
[Fp ]

177 °F
[storage temp. ]

Store at +15°C to +25°C.
[solubility ]

7g/l
[form ]

Liquid
[pka]

4.43(at 28℃)
[color ]

Deep red
[Water Solubility ]

0.5-1.0 g/100 mL at 24.5 ºC
[Merck ]

14,7227
[BRN ]

637069
[InChIKey]

ULHFFAFDSSHFDA-UHFFFAOYSA-N
[CAS DataBase Reference]

94-70-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzenamine, 2-ethoxy-(94-70-2)
[EPA Substance Registry System]

94-70-2(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T,Xi
[Risk Statements ]

R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R33:Danger of cumulative effects.
[Safety Statements ]

S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2311 6.1/PG 3
[WGK Germany ]

2
[RTECS ]

SI6465300
[F ]

8-10-23
[Autoignition Temperature]

425 °C
[Hazard Note ]

Irritant
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29222200
[Toxicity]

LD50 orl-rbt: 600 mg/kg NYKZAU 52,215,56
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->2-Nitrochlorobenzene-->2-Chloroaniline-->2-NITROPHENETOLE-->chloronitrobenzene-->diethyl {[(2-ethoxyphenyl)amino]methylidene}propanedioate-->Bromoethane-->2-Aminophenol
[Preparation Products]

3-Hydroxy-2-naphthoyl-ortho-phenetidide-->1-(2-ETHOXYPHENYL)PIPERAZINE HYDROCHLORIDE-->2-ETHOXYPHENYL ISOTHIOCYANATE-->2-CHLOROPHENETOLE-->Azoic Coupling Component 107-->3-Hydroxy-2-naphthoyl-ortho-phenetidide-->1-Naphthalenamine, 4-[2-(2-ethoxyphenyl)diazenyl]--->N-(2-Ethoxy-phenyl)-oxalamic acid ethyl ester-->8-ETHOXY-4-HYDROXY-QUINOLINE-3-CARBOXYLIC ACID-->N-(2-Ethoxyphenyl)-N'-(4-ethylphenyl)-ethlyene diamide
Hazard InformationBack Directory
[General Description]

Reddish brown oily liquid.
[Reactivity Profile]

O-PHENETIDINE(94-70-2) neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
[Air & Water Reactions]

This compound is very sensitive to exposure to light and air. . Slightly soluble in water.
[Fire Hazard]

This chemical is probably combustible.
[Chemical Properties]

deep red liquid
[Uses]

manufacture of dyes.
[Definition]

ChEBI: o-Phenetidine is a substituted aniline and an aromatic ether. It is used in the manufacture of acetophenetidin.
[Preparation]

o-Phenetidine is produced from 2- ethoxynitrobenzene by reduction with iron or by catalytic hydrogenation in the presence of precious-metal catalysts or Raney nickel.
[Safety Profile]

Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of NOx.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Aminophenetole(94-70-2).msds
Spectrum DetailBack Directory
[Spectrum Detail]

o-Phenetidine(94-70-2)MS
o-Phenetidine(94-70-2)1HNMR
o-Phenetidine(94-70-2)13CNMR
o-Phenetidine(94-70-2)IR1
o-Phenetidine(94-70-2)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

o-Phenetidine, 99%(94-70-2)
[Alfa Aesar]

o-Phenetidine, 98+%(94-70-2)
[Sigma Aldrich]

94-70-2(sigmaaldrich)
[TCI AMERICA]

o-Phenetidine,>98.0%(GC)(94-70-2)
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