| Identification | More | [Name]
2-Aminobenzylalcohol | [CAS]
5344-90-1 | [Synonyms]
2-amino-benzenemethanol
2-AMINOBENZYL ALCOHOL
(2-AMINOPHENYL)METHANOL
2-HYDROXYMETHYLANILINE
O-AMINOBENZYL ALCOHOL
O-AMINOPHENYLCARBINOL
RARECHEM AQ BD 0001
2-amino-benzenemethano
Benzenemethanol, 2-amino-
Benzyl alcohol, o-amino-
o-(Hydroxymethyl)aniline
o-amino-benzylalcoho
o-Aminobenzylic alcohol
o-aminobenzylicalcohol
2-Aminobenzylalcohol(o-Aminobenzylalcohol)
oABAIc
2-AMINOBENZYL ALCOHOL 98%
O-ACETAMINOPHENOL
2-Aminobenzene-1-methanol
o-Aminobenzenemethanol | [EINECS(EC#)]
226-293-7 | [Molecular Formula]
C7H9NO | [MDL Number]
MFCD00007749 | [Molecular Weight]
123.15 | [MOL File]
5344-90-1.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [RTECS ]
DN3155000
| [F ]
8-10-23 | [Hazard Note ]
Irritant | [TSCA ]
Yes | [HS Code ]
29221980 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde.
2-Aminobenzyl alcohol was used in the synthesis of ethyl 2-hydroxymethylcarbanilate. | [Application]
A double dehydrogenative coupling of 2-aminobenzyl alcohol with secondary aryl alcohols furnishes 2-arylquinolines in good to excellent yields under mild and sustainable conditions. The reaction is catalyzed by the molecularly defined phosphine-free nickel complex.
| [General Description]
2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde. | [storage]
Keep Cold. Air Sensitive. Light Sensitive.
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