Identification | More | [Name]
(-)-Diisopinocampheyl chloroborane | [CAS]
85116-37-6 | [Synonyms]
(-)-B-CHLORODIISOPINOCAMPHENYLBORANE (-)-B-CHLORODIISOPINOCAMPHEYLBORANE (-)-B-DIISOPINOCAMPHEYL-CHLOROBORANE (-)-BETA-CHLORODIISOPINOCAMPHEYLBORANE (-)-DIP-CHLORIDE (-)-DIP-CHLORIDE(TM) (-)-IPC2BCL (-)-b-chlorodiisopinocampherylborane (-)-diisopinocampheylchloroborane,(-)-dpc,inheptanes (-)-diisopinocampheylchloroborane,(-)-dpc,inhexanes (-)-Diisopinocampheylchloroborane, in hexanes, 2M solution (-)-Diisopinocampheylchloroborane, in heptanes, 2M solution (-)-DIP-CHLORIDE, 50-65 WT% IN HEPTANE (-)-DIP-CHLORIDE, 60-75 WT% IN HEXANES (-)-DIP CHLORIDE, 65-75 WT% IN ALPHA-PI& (-)-dip-chloride tm solution (-)-B-Chlorodiisopinocampheylborane (-)-Diisopinocampheyl chloroborane (-)-DIP-Chloride (-)-SS-CHLORODIISOPINOCAMPHEYLBORANE | [EINECS(EC#)]
237-458-8 | [Molecular Formula]
C20H34BCl | [MDL Number]
MFCD00074807 | [Molecular Weight]
320.75 | [MOL File]
85116-37-6.mol |
Safety Data | Back Directory | [Hazard Codes ]
C,F+,N | [Risk Statements ]
R34:Causes burns. R20/22:Harmful by inhalation and if swallowed . R12:Extremely Flammable. R10:Flammable. R67:Vapors may cause drowsiness and dizziness. R65:Harmful: May cause lung damage if swallowed. R62:Possible risk of impaired fertility. R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation . | [Safety Statements ]
S9:Keep container in a well-ventilated place . S16:Keep away from sources of ignition-No smoking . S29:Do not empty into drains . S33:Take precautionary measures against static discharges . S36/37:Wear suitable protective clothing and gloves . S61:Avoid release to the environment. Refer to special instructions safety data sheet . S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [HazardClass ]
3/8 | [PackingGroup ]
II | [HS Code ]
29319090 |
Hazard Information | Back Directory | [Chemical Properties]
solutio | [Uses]
Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols. |
|
|