| Identification | More | [Name]
Sodium acrylate | [CAS]
7446-81-3 | [Synonyms]
2-propenoic acid sodium salt
ACRYLIC ACID, SODIUM SALT
SODIUM ACRYLATE
Sodium 2-propenoate
SODIUM ACRYLATE ANHYDROUS
Propenoic acid sodium salt
Sodium propenoate | [EINECS(EC#)]
231-209-7 | [Molecular Formula]
C3H3NaO2 | [MDL Number]
MFCD00067207 | [Molecular Weight]
94.04 | [MOL File]
7446-81-3.mol |
| Chemical Properties | Back Directory | [Appearance]
solid | [Melting point ]
>300 °C (lit.) | [density ]
1.528[at 20℃] | [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
Aqueous Acid (Slightly), Methanol (Slightly), Water (Slightly) | [form ]
Solid | [color ]
White to Off-White | [Stability:]
May be unstable; may spontaneously polymerize. Incompatible with strong oxidizing agents. | [Water Solubility ]
479g/L at 20℃ | [Hydrolytic Sensitivity]
0: forms stable aqueous solutions | [LogP]
0.46 at 25℃ | [CAS DataBase Reference]
7446-81-3(CAS DataBase Reference) | [EPA Substance Registry System]
7446-81-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 3077 9 / PGIII | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
29161100 | [Hazardous Substances Data]
7446-81-3(Hazardous Substances Data) |
| Hazard Information | Back Directory | [Chemical Properties]
solid | [Uses]
Sodium Acrylate is the acid form of Acrylic Acid (A191350); which is an antibacterial agent. | [Application]
Sodium acrylate (NA) is a metal salt that can be made by an acid-base reaction of sodium hydroxide and acrylic acid. It can be used to produce poly(sodium acrylate) using bulk, solution, emulsion, and suspension polymerization processes. It results in the formation of a water soluble polymer that can be used in a variety of industrial and personal applications. It can be used in grain size optimization of iron oxide microparticles for potential applications in biological assays and chemical sensors. It can be used as a reducing and capping agent on gold nanoparticles that can be used in biological application. | [General Description]
Sodium acrylate (SA) is a metal salt that can be prepared by an acid-base reaction between sodium hydroxide and acrylic acid. It can be used in the preparation of poly(sodium acrylate) using bulk, solution, emulsion, and suspension polymerization techniques. It results in the formation of a water soluble polymer that can be used in a variety of industries and personal care applications. | [Flammability and Explosibility]
Nonflammable | [Synthesis]
An aqueous solution of sodium acrylate is prepared from 216.2 g of acrylic acid (100%=3 mol), 262.8 g of NaOH (50%) and 497 g of water. 3.7 g of N-nitrosodiphenylamine and 3.7 g of 4-methoxyphenol are added to stabilize the solution. 12 g of the quaternary ammonium salt used in Example 1 are also added. 1,125 g (9 mol) of 1,4-dichlorobutene are run in at 90° C. 15.9 g of Na2CO3 are added after 1 hour and the mixture is left to react for a further 2 hours at 90° C. After phase separation, the organic layer is distilled under vacuum. 286.0 g (1.78 mol) of 4-chloro-2-butenyl acrylate (59.4% of the theoretical yield) are obtained. 641 g (5.13 mol) of dichlorobutene are recovered. | [References]
[1] SIMONE MANZINI . Palladium- and Nickel-Catalyzed Synthesis of Sodium Acrylate from Ethylene, CO2, and Phenolate Bases: Optimization of the Catalytic System for a Potential Process[J]. European Journal of Organic Chemistry, 2015, 2015 32: Pages 7122-7130. DOI:10.1002/ejoc.201501113.
[2] KALRA B, GROSS R A. HRP-mediated polymerizations of acrylamide and sodium acrylate[J]. Green Chemistry, 2002, 2: 174-178. DOI:10.1039/B106735B.
[3] https://www.ewg.org/skindeep/ingredients/705976-SODIUM_ACRYLATES_COPOLYMER/ |
|
|