| Identification | More | [Name]
1-ACENAPHTHENOL | [CAS]
6306-07-6 | [Synonyms]
1,2-DIHYDROACENAPHTHYLENE-1-OL
1-ACENAPHTHENOL
1-HYDROXY-1,2-DIHYDROACENAPHTHYLENE
1-HYDROXYACENAPHTHENE
1-HYDROXYNAPHTHYLENETHYLENE
1-HYDROXY-PERI-ETHYLENENAPHTHALENE
ACENAPHTHENE-1-HYDROXY
ACENAPHTHENOL
AKOS 94203
AKOS AUF2112
NAPHTHYLENEETHYLENE-1-OL
PERI-ETHYLENENAPHTHALENE-1-OL
TIMTEC-BB SBB003856
1,2-Dihydro-1-acenaphthylenol
1-Acenaphthylenol, 1,2-dihydro-
7-Acenaphthenol
Acenaphthenol-1
1-ACENAPHTHENOL 99%
1-Acenaphthenol,99% | [EINECS(EC#)]
228-618-8 | [Molecular Formula]
C12H10O | [MDL Number]
MFCD00003808 | [Molecular Weight]
170.21 | [MOL File]
6306-07-6.mol |
| Chemical Properties | Back Directory | [Description]
1-Acenaphthenol is a white to cream solid in appearance. It is almost insoluble in water.
1-Acenaphthenol is a stable and combustible chemical substance. It is incompatible with
strong oxidising agents. It is used in the syntheses of organic compounds.
Exposures to 1-acenaphthenol cause irritant effects. It is harmful by ingestion, inhalation,
as well as through skin absorption. There are no complete data on the toxicology of
1-acenaphthenol. | [Appearance]
white to cream solid | [Melting point ]
145-148 °C (lit.) | [Boiling point ]
369℃ | [density ]
1.290 | [Fp ]
129℃ | [storage temp. ]
-20°C Freezer | [solubility ]
Chloroform (Slightly, Sonicated), Methanol (Slightly) | [form ]
Solid | [pka]
13.68±0.20(Predicted) | [color ]
Yellow to Dark Yellow | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents. | [BRN ]
2048222 | [CAS DataBase Reference]
6306-07-6(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Health Hazard]
Exposures to 1-acenaphthenol cause irritant effects. It is harmful by ingestion, inhalation,
or skin absorption. There are no complete data on the toxicology of 1-acenaphthenol. | [Chemical Properties]
1-Acenaphthenol is a white to cream solid in appearance. It is almost insoluble in water.
1-Acenaphthenol is a stable and combustible chemical substance. It is incompatible with
strong oxidizing agents. It is used in the syntheses of organic compounds. | [Uses]
1-Acenaphthenol is a product of the microbial metabolism and photolysis of acenaphthene, of acenaphthene, a polycyclic hydrocarbon that has potential to act as polyploidizing agents in plants. 1-Acenaphthenol is also a known substrate of dihydrodiol dehydrogenases. | [Purification Methods]
If highly coloured (yellow), dissolve it in boiling *benzene (14g in 200mL), add charcoal (0.5g), filter it through a heated funnel, concentrate to 100mL and cool to give almost colourless needles. *Benzene vapour is TOXIC; use an efficient fume cupboard. The acetate has b 166-168o/5mm (bath temperature 180-185o). [Cason Org Synth Coll Vol III 3 1955.] It can also be recrystallised from *C6H6 or EtOH [Fieser & Cason J Am Chem Soc 62 432 1940]. It forms a brick-red crystalline complex with 2,4,5,7-tetranitrofluoren-9-one which is recrystallised from AcOH and is dried in a vacuum over KOH and P2O5 at room temperature, m 170-172o [Newman & Lutz J Am Chem Soc 78 2469 1956]. [Beilstein 6 IV 4623.] |
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