| Identification | More | [Name]
1-Chloro-2-butene | [CAS]
591-97-9 | [Synonyms]
1-CHLORO-2-BUTENE
1-CHLORO-2-BUTYLENE
2-BUTEN-1-YL CHLORIDE
CIS,TRANS-1-CHLORO-2-BUTENE
CIS,TRANS-CROTYL CHLORIDE
CROTYL CHLORIDE
(e)-1-chlorobut-2-ene
(E)CROTYL CHLORIDE
GAMMA-METHYLALLYL CHLORIDE
TRANS-1-CHLORO-2-BUTENE
TRANS-CROTYL CHLORIDE
(2E)-1-Chloro-2-butene
1-chloro-2-buten
1-chloro-but-2-ene
1-chlorobut-2-ene
2-Butene,1-chloro-
2-Butenyl chloride
2-butenylchloride
alpha-Chloro-beta-butylene
-Chloro-butylene | [EINECS(EC#)]
209-739-5 | [Molecular Formula]
C4H7Cl | [MDL Number]
MFCD00000987 | [Molecular Weight]
90.55 | [MOL File]
591-97-9.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless liquid | [Melting point ]
-65°C | [Boiling point ]
85-86 °C(lit.)
| [density ]
0.923 g/mL at 20 °C(lit.)
| [refractive index ]
n20/D 1.430
| [Fp ]
-12°C | [storage temp. ]
0-6°C | [solubility ]
water: soluble14g/L at 20°C | [form ]
clear liquid | [color ]
Colorless to Light yellow | [Stability:]
Stable. Highly flammable. Incompatible with strong oxidizing agents. | [Water Solubility ]
999mg/L(temperature not stated) | [Detection Methods]
GC | [Merck ]
2130 | [BRN ]
605304 | [CAS DataBase Reference]
591-97-9(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Butene, 1-chloro-(591-97-9) | [EPA Substance Registry System]
591-97-9(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
F,C | [Risk Statements ]
R11:Highly Flammable.
R22:Harmful if swallowed.
R34:Causes burns. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2924 3/PG 2
| [WGK Germany ]
2
| [RTECS ]
EM4264000
| [F ]
19 | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29049090 |
| Hazard Information | Back Directory | [Chemical Properties]
colourless liquid | [Uses]
Crotyl chloride has been used:
- to investihgate the kinetics of the reactions of atomic chlorine with series of unsaturated aldehydes and ketones at 298K, to probe structure-reactivity relationships
- in the preparation of (E)-crotyltrichlorosilane
| [General Description]
Crotyl chloride reacts with trichlorosilane in the presence of tertiary amine and copper salts to give the corresponding allyltrichlorosilanes. |
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