| Identification | More | [Name]
4,4'-DIFLUOROBENZIL | [CAS]
579-39-5 | [Synonyms]
4,4'-DIFLUOROBENZIL
4,4'-DIFLUOROBIBENZOYL
4,4'-DIFLUORODIBENZOYL
4,4'-FLUOROBENZIL
BIS(P-FLUOROPHENYL)ETHANEDIONE
1,2-Bis(4-fluorophenyl)-1,2-ethanedione
4,4'-Difluorobenzil,99%
Ethanedione, bis(4-fluorophenyl)-
4,4'-Difluorobenzil | [Molecular Formula]
C14H8F2O2 | [MDL Number]
MFCD00134541 | [Molecular Weight]
246.21 | [MOL File]
579-39-5.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [TSCA ]
T | [HS Code ]
29147000 |
| Hazard Information | Back Directory | [Chemical Properties]
pale yellow powder | [Uses]
4,4′-Difluorobenzil is suitable for use in the preparation of 2,3-bis(4-fluorophenyl)thieno[3,4-b]pyrazine. It may be used in the synthesis of following:
- poly(ether-α-diketone)s, via nucleophilic substitution reaction with bisphenol A
- 4,4′-difluoro-2,3-diphenylpyrazine (DPPF) and 4,4′-difluoro-5-methyl 2,3-diphenylpyrazine (MDPPF), via direct condensation with ethylenediamine and 1,2-diaminopropane, respectively
- 2,3-bis(4-fluorophenyl)quinoxaline, via direct condensation with 1,2-phenylenediamine
| [Synthesis Reference(s)]
Tetrahedron Letters, 35, p. 2959, 1994 DOI: 10.1016/S0040-4039(00)76671-8 | [General Description]
4,4′-Difluorobenzil is a benzil derivative. Its reaction with benzylurea and phenethylurea has been investigated. It is reported to undergo condensation with Fe2(SH)2(CO)6 to afford the adduct Fe2[S2C2(OH)2(C6H4-4-F)2](CO)6. |
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