| Identification | More | [Name]
4-Tolylboronic acid | [CAS]
5720-05-8 | [Synonyms]
4-METHYLBENZENEBORONIC ACID
4-METHYLPHENYLBORIC ACID
4-METHYLPHENYLBORONIC ACID
4-TOLYBORONIC ACID
4-TOLYLBORONIC ACID
AKOS BRN-0019
P-METHYLPHENYLBORONIC ACID
P-TOLYLBORONIC ACID
RARECHEM AH PB 0227
TOLUENE-4-BORONIC ACID
(4-methylphenyl)-boronicaci
Boronic acid, (4-methylphenyl)-
Boronic acid, p-tolyl-
p-methylbenzeneboronicacid
p-methylborophenylicacid
p-Tolueneboronic acid
p-tolueneboronicacid
p-tolyl-boronicaci
t-509
4-Methylbenzeneboronicacid,98% | [EINECS(EC#)]
611-480-1 | [Molecular Formula]
C7H9BO2 | [MDL Number]
MFCD00039138 | [Molecular Weight]
135.96 | [MOL File]
5720-05-8.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powder | [Melting point ]
256-263 °C(lit.) | [Boiling point ]
275.2±33.0 °C(Predicted) | [density ]
1.10±0.1 g/cm3(Predicted) | [storage temp. ]
0-6°C | [solubility ]
DMSO (Slightly), Methanol (Slightly) | [form ]
Crystalline Powder | [pka]
8.84±0.10(Predicted) | [color ]
Off-white | [Water Solubility ]
It is soluble in water. | [Detection Methods]
HPLC,NMR | [BRN ]
2935970 | [InChI]
InChI=1S/C7H9BO2/c1-6-2-4-7(5-3-6)8(9)10/h2-5,9-10H,1H3 | [InChIKey]
BIWQNIMLAISTBV-UHFFFAOYSA-N | [SMILES]
B(C1=CC=C(C)C=C1)(O)O | [CAS DataBase Reference]
5720-05-8(CAS DataBase Reference) | [NIST Chemistry Reference]
P-methylbenzeneboronic acid(5720-05-8) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [RTECS ]
XS7400000
| [Hazard Note ]
Irritant | [HazardClass ]
IRRITANT | [HS Code ]
29319099 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powder | [Uses]
Reagent used for
- Palladium (Pd)-catalyzed direct arylation
- Direct Palladium(II)-Catalyzed Synthesis
- Palladium-catalyzed arylation by Suzuki-Miyaura cross-coupling in water
- Cyclopalladation
- Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence
- Ruthenium catalyzed direct arylation
- Rhodium-catalyzed asymmetric conjugate addition
- Ligand-free copper-catalyzed cross-coupling reactions
- Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions
- Ligand-free Suzuki, Sonogashira, and Heck cross-coupling reactions
Reagent used in Preparation of
- Catalysts for Suzuki-Miyaura cross-coupling of aryl bromides
- Recyclable Palladium nanoparticle catalysts immobilized by click ionic copolymers as for Suzuki-Miyaura cross-coupling reactions in water
| [Uses]
4-Methylbenzeneboronic acid, is a commonly used chemical in Suzuki coupling reactions. It is also used as an intermediate in pharmaceutical industry | [Uses]
suzuki reaction |
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