| Identification | More | [Name]
2-(1-CYCLOHEXENYL)ETHYLAMINE | [CAS]
3399-73-3 | [Synonyms]
1-CYCLOHEXENE-1-ETHANAMINE
1-CYCLOHEXENE-2-ETHANAMINE
2-(1-CYCLOHEXENYL)ETHYLAMINE
2-AMINOETHYL-1-CYCLOHEXENE
CYCLOHEXENYLETHYLAMINE
RARECHEM AN KA 1280
1-Cyclohexen-1-ylethylamine
2-(1-Cyclohexen-1-yl)ethanamine
2-(1-Cyclohexen-1-yl)ethylamine
beta-(1-Cyclohexenyl)ethylamine
cyclohex-1-ene-1-ethylamine
2-(1-Cyaclohexenyl1)Ethylamine
(1-Cyclohexenyl)-Ethylamine
2-(1-CYCLOHEXENYL)ETHYLAMINE 97+%
2-(1-CYCLOHEXENYL)ETHYLAMI
1-(2-Aminoethyl)-1-cyclohexene
2-(1-Cyclohexenyl)ethanamine | [EINECS(EC#)]
222-267-4 | [Molecular Formula]
C8H15N | [MDL Number]
MFCD00012058 | [Molecular Weight]
125.21 | [MOL File]
3399-73-3.mol |
| Chemical Properties | Back Directory | [Appearance]
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID | [Melting point ]
-55 °C
| [Boiling point ]
53-54 °C/2.5 mmHg (lit.) | [density ]
0.9
| [refractive index ]
1.486-1.488
| [Fp ]
57 °C
| [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
clear liquid | [pka]
10.94±0.10(Predicted) | [color ]
Colorless to Light yellow | [Sensitive ]
Air Sensitive | [BRN ]
774030 | [Stability:]
Light Sensitive | [InChIKey]
IUDMXOOVKMKODN-UHFFFAOYSA-N | [CAS DataBase Reference]
3399-73-3(CAS DataBase Reference) | [EPA Substance Registry System]
1-Cyclohexene-1-ethanamine (3399-73-3) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
2735 | [WGK Germany ]
3 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29213000 |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID | [Uses]
2-(1-Cyclohexenyl)ethylamine has been employed:
- as substrate for allylic hydroxylation reaction
- in preparation of thin films and single crystals of 2-(1-cyclohexenyl)ethyl ammonium lead iodide, used to fabricate optoelectronic-compatible heterostructures
| [Synthesis]
125 ml of ethylamine was placed in a 250 ml three-necked flask, which had previously been flushed with argon, at -70 ° C. 6.27 g (50 mmol) of 2-phenylethylamine was added. The resulting clear, colorless solution was metered in with 1.14 g (164.2 mmol) of Li powder; the solution turned dark blue 5 minutes after the onset of turbidity. After stirring for 2 hours at -70 ° C, the mixture was warmed to -30 ° C. Then another 0.24 g (34.6 mmol) of Li powder was added. After stirring again at -30 ° C. for 2 hours, the cooling bath was removed. The reaction mixture was allowed to warm to room temperature overnight. The reaction mixture was then given 25 ml of abs. After that, a gray suspension formed. After stirring for 20 minutes at room temperature, 25 ml of water was slowly added (exothermic temperature 40 ° C.). The excess ethylamine was then distilled off at 40 °C. The distillation residue was evaporated to dryness. Then, 100 ml of water was added and extracted 3 times with 80 ml chloroform. The combined organic phases were dried over Na?SO?, filtered, and evaporated. The
2-(1-Cyclohexenyl)ethylamine was obtained in a GC yield of 69.8%. |
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