Identification | More | [Name]
4-Vinylbenzyl chloride | [CAS]
1592-20-7 | [Synonyms]
4-(CHLOROMETHYL)STYRENE 4-VINYLBENZYL CHLORIDE CHLOROMETHYLSTYRENE VINYLBENZYL CHLORIDE 1-(chloromethyl)-4-ethenyl-benzen 1-(chloromethyl)-4-ethenyl-Benzene 1-(chloromethyl)-4-vinylbenzene 4-VINYLBENZYL CHLORIDE, STAB. 4-Vinylbenylchloride 4-Vinylbenzyl chloride, tech., 90% 4-VINYLBENZYLCHLORIDE,TECHNICAL P-CHLOROMETHYL STYRENE(4-VINYLBENZYL CHLORIDE) p-Vinylbenzyl chloride PARA-VINYLBENZYLCHLORIDE 4-CHLOROMETHYLSTYRENE, STABILIZED WITH TBC+ONP+O-NITROCRESOL BENZENE,1-(CHLOROMETHYL)-4-ETHENYL- 4-(Chloromethyl)styrene (stabilized with TBC + ONP + 2-Nitro-p-cresol) CMS 14 p-(Chloromethyl)styrene 4-Vinylbenzyl chloride,90%,tech. | [EINECS(EC#)]
250-005-9 | [Molecular Formula]
C9H9Cl | [MDL Number]
MFCD00051362 | [Molecular Weight]
152.62 | [MOL File]
1592-20-7.mol |
Chemical Properties | Back Directory | [Appearance]
clear yellow liquid | [Boiling point ]
229 °C(lit.)
| [density ]
1.083 g/mL at 25 °C(lit.)
| [vapor density ]
5.3 (vs air)
| [vapor pressure ]
1 mm Hg ( 56.1 °C)
| [refractive index ]
n20/D 1.572(lit.)
| [Fp ]
221 °F
| [storage temp. ]
−20°C
| [solubility ]
Chloroform (Sparingly) | [Water Solubility ]
Insoluble in water | [form ]
Liquid | [color ]
Clear yellow | [FreezingPoint ]
-15.5 | [BRN ]
2204384 | [Stability:]
Light Sensitive | [InChIKey]
ZRZHXNCATOYMJH-UHFFFAOYSA-N | [CAS DataBase Reference]
1592-20-7(CAS DataBase Reference) | [Storage Precautions]
Air sensitive;Light sensitive | [EPA Substance Registry System]
1592-20-7(EPA Substance) |
Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. R43:May cause sensitization by skin contact. R21/22:Harmful in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3265 8/PG 3
| [WGK Germany ]
3
| [F ]
8-19 | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29039990 |
Hazard Information | Back Directory | [Chemical Properties]
clear yellow liquid | [Uses]
Component of ion exchange resins, photo-resist polymers, cross-linkable fibers, coupling agents and electroconducting polymers. Starter for various copolymer preparations. Dual functional monomer. Readily derivatized by chloride displacement. | [Purification Methods]
Purify 4-vinylbenzyl chloride by dissolving it in Et2O, washing it with 0.5% of aqueous NaOH, separating, drying the organic layer (Na2SO4), evaporating and distilling the residual oil under N2 in vacuo. Add 0.05% of 4-tert-butylcatechol as stabilizer. It is lachrymatory. [Nishikubo et al. Tetrahedron Lett 22 3872 1981, Tanimoto et al. Synth Commun 4 193 1974, Beilstein 6 IV 3818.] |
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