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ChemicalBook--->CAS DataBase List--->1499-55-4

1499-55-4

1499-55-4 Structure

1499-55-4 Structure
IdentificationMore
[Name]

L-Glutamic acid 5-methyl ester
[CAS]

1499-55-4
[Synonyms]

5-METHYL L-GLUTAMATE
GAMMA-L-GLU-METHYL ESTER
GAMMA-METHYL-L-GLUTAMATE
GLUTAMIC ACID DELTA-METHYL ESTER
GLUTAMIC ACID-GAMMA-METHYL ESTER
GLUTAMIC ACID(OME)-OH
H-GLU(OME)-OH
H-L-GLU(ME)-OH
L-GLUTAMIC ACID 5-METHYL ESTER
L-GLUTAMIC ACID GAMMA-METHYL ESTER
L-GLUTAMIC ACID, G-METHYL ESTER
L-Glutamicacidγ-methylester
(5)-methyl L-hydrogen glutamate
L-GUTAMIC ACID 5-METHYL ESTER 99%
L-Gutamic Acid 5-Methyl Ester
Mono-methyl-L-glutamate
L-Glutamicacid5-methylester,L-Glutamicacidγ-methylester
L-GLUTAMIC ACID-Y-METHYLESTER
Duplicate of B24859
(2S)-2-Amino-5-methoxy-5-oxopentanoic acid
[EINECS(EC#)]

216-110-9
[Molecular Formula]

C6H11NO4
[MDL Number]

MFCD00002632
[Molecular Weight]

161.16
[MOL File]

1499-55-4.mol
Chemical PropertiesBack Directory
[Appearance]

white amorphous powder
[Melting point ]

182 °C (dec.) (lit.)
[alpha ]

13 º (c=1, H2O 24 ºC)
[Boiling point ]

287.44°C (rough estimate)
[density ]

1.3482 (rough estimate)
[refractive index ]

29 ° (C=2, 6mol/L HCl)
[storage temp. ]

2-8°C
[solubility ]

Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
[Water Solubility ]

Soluble in water
[form ]

powder to crystal
[pka]

2.18±0.10(Predicted)
[color ]

White to Almost white
[optical activity]

[α]20/D +29°, c = 2 in 6 M HCl
[BRN ]

1725252
[CAS DataBase Reference]

1499-55-4(CAS DataBase Reference)
Safety DataBack Directory
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[HS Code ]

29224999
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Methanol-->Diethyl ether-->Thionyl chloride-->Ammonium hydroxide-->L-Glutamic acid
[Preparation Products]

L-Glutamine-->Aceglutamide-->L-Glutamic acid dimethyl ester hydrochloride-->H-Glu(OMe)-OtBu-->BOC-GLU(OME)-OH
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

L-Glutamic acid gamma-methyl ester(1499-55-4).msds
Hazard InformationBack Directory
[Chemical Properties]

white amorphous powder
[Uses]

L-Glutamic acid 5-methyl ester is a protected form of L-Glutamic acid (G596960). L-Glutamic acid is a nonessential amino acid that is important to the mammalian central nervous system. L-Glutamic acid is also a neurotransmitter for cone photoreceptors in the human brain and is used as a treatment for patients who have liver disease accompanied by encephalopathy (a condition termed ‘hepatic coma’).
[Definition]

ChEBI: L-glutamic acid 5-methyl ester is a glutamic acid 5-methyl ester having L-configuration. It is a L-glutamic acid derivative, a non-proteinogenic L-alpha-amino acid and a glutamic acid 5-methyl ester.
[reaction suitability]

reaction type: solution phase peptide synthesis
Spectrum DetailBack Directory
[Spectrum Detail]

L-Glutamic acid 5-methyl ester(1499-55-4)MS
L-Glutamic acid 5-methyl ester(1499-55-4)1HNMR
L-Glutamic acid 5-methyl ester(1499-55-4)13CNMR
L-Glutamic acid 5-methyl ester(1499-55-4)IR1
L-Glutamic acid 5-methyl ester(1499-55-4)IR2
L-Glutamic acid 5-methyl ester(1499-55-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

L-Glutamic acid 5-methyl ester, 99%(1499-55-4)
[Alfa Aesar]

L-Glutamic acid 5-methyl ester, 99%(1499-55-4)
[Sigma Aldrich]

1499-55-4(sigmaaldrich)
[TCI AMERICA]

5-Methyl L-Glutamate,>98.0%(T)(1499-55-4)
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