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ChemicalBook--->CAS DataBase List--->14649-03-7

14649-03-7

14649-03-7 Structure

14649-03-7 Structure
IdentificationMore
[Name]

(S)-(-)-1-Phenylethyl isocyanate
[CAS]

14649-03-7
[Synonyms]

ISOCYANIC ACID (S)-(-)-1-PHENYLETHYL ESTER
ISOCYANIC ACID (S)-(-)-ALPHA-METHYLBENZYL ESTER
(S)-(-)-1-PHENYLETHYL ISOCYANATE
(S)-1-PHENYLETHYLISOCYANATE
(S)-(-)-ALPHA-METHYLBENZYL ISOCYANATE
(S)(-)-ALPHA-PHENETHYL ISOCYANATE
(S)-(-)-A-METHYLBENZYL ISOCYANATE
(S) METHYL BENZYLISOCYANATE
IsocyanicAcid(S)-(-)-á-MethylbenzylEster
IsocyanicAcid(S)-(-)-α-MethylbenzylEster
(S)-(-)-ALPHA-METHYLBENZYL ISOCYANATE, 9 9%
Benzene, (1S)-1-isocyanatoethyl-
(s)-(-)-à-methylbenzyl isocyanate
(S)-(-)-1-PHENYLETHYL ISOCYANATE 98+%
(-)-[(S)-1-Isocyanatoethyl]benzene
[EINECS(EC#)]

238-698-6
[Molecular Formula]

C9H9NO
[MDL Number]

MFCD00002036
[Molecular Weight]

147.17
[MOL File]

14649-03-7.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liqui
[Melting point ]

65 °C
[alpha ]

-10 º (NEAT)
[Boiling point ]

55-56 °C2.5 mm Hg(lit.)
[density ]

1.045 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.5145(lit.)
[Fp ]

150 °F
[storage temp. ]

2-8°C
[form ]

Liquid
[color ]

Clear colorless to pale yellow
[optical activity]

[α]20/D 10°, neat
[Water Solubility ]

Decomposition
[Sensitive ]

Moisture Sensitive
[BRN ]

4230972
[InChIKey]

JJSCUXAFAJEQGB-QMMMGPOBSA-N
[CAS DataBase Reference]

14649-03-7(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xn,T+
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R42:May cause sensitization by inhalation.
R26:Very Toxic by inhalation.
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S24/25:Avoid contact with skin and eyes .
[RIDADR ]

UN 2206 6.1/PG 2
[WGK Germany ]

3
[F ]

3-10-21
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29291090
Hazard InformationBack Directory
[Chemical Properties]

Colorless to light yellow liqui
[Uses]

(S)-(-)-1-Phenylethyl isocyanate act by inhibition of cell proliferation and induction of apoptosis. It helps to prevent lung cancer and esophageal cancer. It is a fine chemical intermediate.
[General Description]

(S)-(-)-α-Methylbenzyl isocyanate is a commonly used chiral derivatizing agent for the resolution of enantiomers.
[Purification Methods]

Purify the isocyanates by fractional distillation under a vacuum. With ammonia
Spectrum DetailBack Directory
[Spectrum Detail]

(S)-(-)-1-Phenylethyl isocyanate(14649-03-7)1HNMR
(S)-(-)-1-Phenylethyl isocyanate(14649-03-7)13CNMR
(S)-(-)-1-Phenylethyl isocyanate(14649-03-7)IR1
(S)-(-)-1-Phenylethyl isocyanate(14649-03-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(S)-(-)-alpha-Methylbenzyl isocyanate, 98%(14649-03-7)
[Alfa Aesar]

(S)-(-)-1-Phenylethyl isocyanate, 98%(14649-03-7)
[Sigma Aldrich]

14649-03-7(sigmaaldrich)
[TCI AMERICA]

(S)-(-)-alpha-Methylbenzyl Isocyanate,>95.0%(GC)(14649-03-7)
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