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ChemicalBook--->CAS DataBase List--->14284-93-6

14284-93-6

14284-93-6 Structure

14284-93-6 Structure
IdentificationBack Directory
[Name]

Ruthenium acetylacetonate
[CAS]

14284-93-6
[Synonyms]

Rutheniumpentanedionate
Tris(2,4-pentanedionato)
Ruthenium acetylacetonate
Acetylacetone Ruthenium Salt
Ruthenium 2,4-pentanedionate
Ruthenium(Ⅲ) acetylacetonate
TrisacetylacetonateRutheniuM
RutheniuM(Ⅲ)2,4-pentanedionate
RUTHENIUM(III) ACETYLACETONATE
Tris(acetylacetonato) ruthenium
RUTHENIUM(III) 2,4-PENTANEDIONATE
Ruthenium(III)acetylacetonate,99%
Acetylacetone Ruthenium(III) Salt
Ruthenium(III) acetylacetonate,97%
Rutheniumacetylacetonateredbrownxtl
TRIS(ACETYLACETONATO)RUTHENIUM(III)
RUTHENIUM (III) ACETYLACETONATE 99%
Tris(acetylaccetonato)rutheniuM (III)
2,4-Pentanedione ruthenium derivative
Tris(2,4-pentanedionato)ruthenium(III)
TRIS(PENTANE-2,4-DIONATO)RUTHENIUM(III)
tris(pentane-2,4-dionato-O,O')ruthenium
RUTHENIUM(III) ACETYLACETONATE FOR SYNTH
2,4-PENTANEDIONE, RUTHENIUM(III) DERIVATIVE
RutheniuM(III) 2,4-pentanedionate, Ru 24% Min
4-pentanedionato-o,o’)-tris((oc-6-11)-rutheniu
RutheniuM(III) acetylacetonate, Ru(CH3COCHCOCH3)3
Tris(acetylacetonato)ruthenium(III) dec. 230-235
RutheniuM(Ⅲ) acetylacetonate, 25% Ru, Product of UMicore
2,4-Pentanedione ruthenium(III) derivative, Ru(acac)3
RutheniuM (III)2,4-Pentanedionate [“RutheniuM Acetylacetonate”]
Acetylacetone Ruthenium(III) Salt Ruthenium(III) Acetylacetonate
Ruthenium(III) 2,4-pentanedionate~Tris(acetylacetonato)ruthenium(III)~Tris(2,4-pentanedionato)ruthenium(III)
[EINECS(EC#)]

238-193-0
[Molecular Formula]

C15H21O6Ru
[MDL Number]

MFCD00000030
[MOL File]

14284-93-6.mol
[Molecular Weight]

398.39
Chemical PropertiesBack Directory
[Appearance]

dark-red crystals
[Melting point ]

260 °C (dec.)(lit.)
[storage temp. ]

Store below +30°C.
[form ]

Crystalline
[color ]

White
[Water Solubility ]

Soluble in most organic solvents such as acetone, chlorinated hydrocarbons, alcohols, cyclohexane and benzene. Insoluble in water.
[InChIKey]

RTZYCRSRNSTRGC-LNTINUHCSA-K
[EPA Substance Registry System]

Ruthenium, tris(2,4-pentanedionato-.kappa. O,.kappa.O')-, (OC-6-11)-(14284-93-6)
Hazard InformationBack Directory
[Chemical Properties]

dark-red crystals
[Uses]

Precursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid.
[Purification Methods]

Purify the complex by recrystallisation from *benzene. [Wilkinson J Am Chem Soc 74 6146 1952, Beilstein 1 IV 3677.]
Safety DataBack Directory
[Hazard Codes ]

Xi,T
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36-24/25
[WGK Germany ]

3
[F ]

10
[TSCA ]

Yes
[HS Code ]

28439000
Spectrum DetailBack Directory
[Spectrum Detail]

Ruthenium acetylacetonate(14284-93-6)FT-IR
Ruthenium acetylacetonate(14284-93-6)IR
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