| Identification | More | [Name]
Girard's Reagent T | [CAS]
123-46-6 | [Synonyms]
2-hydrazino-n,n,n-trimethyl-2-oxo-ethanaminium chloride
ACETHYDRAZIDE TRIMETHYLAMMONIUM CHLORIDE
ACETOHYDRAZIDE TRIMETHYLAMMONIUM CHLORIDE
BETAINE HYDRAZIDE HYDROCHLORIDE
CARBAZOYLMETHYLTRIMETHYLAMMONIUM CHLORIDE
(CARBOXYMETHYL)TRIMETHYLAMMONIUM CHLORIDE HYDRAZIDE
GIRARD-REAGENT T
GIRARD'S REAGENT T
GIRARD'S T
GIRARD'S T REAGEN T
GIRARD'S ''T'' REAGENT
GIRARD T
(HYDRAZINOCARBONYLMETHYL)TRIMETHYLAMMONIUM CHLORIDE
LABOTEST-BB LT00455523
TRIMETHYLACETHYDRAZIDEAMMONIUM CHLORIDE
TRIMETHYLACETOHYDRAZIDEAMMONIUM CHLORIDE
(Carboxymethyl)trimethylammomiumchloridehydrazide
2-hydrazino-n,n,n-trimethyl-2-oxo-ethanaminiuchloride
ammonium,(carboxymethyl)trimethyl-,chloride,hydrazide
Ethanaminium,2-hydrazino-N,N,N-trimethyl-2-oxo-,chloride | [EINECS(EC#)]
204-629-3 | [Molecular Formula]
C10H27ClN4O4 | [MDL Number]
MFCD00012009 | [Molecular Weight]
302.8 | [MOL File]
123-46-6.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xn-F,Xn,F | [Risk Statements ]
R44:Risk of explosion if heated under confinement.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/22:Harmful by inhalation and if swallowed .
R11:Highly Flammable. | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S16:Keep away from sources of ignition-No smoking . | [WGK Germany ]
3
| [RTECS ]
CP3150000
| [F ]
21 | [HS Code ]
29280000 |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Ethyl chloroacetate-->Trimethylamine-->Ethanaminium,2-[2-[(4-hydroxy-3-methoxyphenyl)methylene]hydrazinyl]-N,N,N-trimethyl-2-oxo-,chloride (1:1)-->Ethanaminium,2-[2-[(4-chlorophenyl)methylene]hydrazinyl]-N,N,N-trimethyl-2-oxo-, chloride(1:1)-->Ethanaminium,N,N,N-trimethyl-2-oxo-2-[2-(phenylmethylene)hydrazinyl]-, chloride (1:1)-->Ethanaminium,N,N,N-trimethyl-2-[2-(1-naphthalenylmethylene)hydrazinyl]-2-oxo-, chloride(1:1)-->[(4-methoxyphenyl)methylideneamino]carbamoylmethyl-trimethyl-azanium-->4-Biphenylcarboxaldehyde-->Benzaldehyde-->p-Anisaldehyde-->4-Fluorobenzaldehyde-->4-Bromobenzaldehyde-->2-Naphthaldehyde-->1-Naphthaldehyde-->4-Nitrobenzaldehyde-->4-Chlorobenzaldehyde-->p-Tolualdehyde | [Preparation Products]
trans-Cinnamaldehyde |
| Hazard Information | Back Directory | [Chemical Properties]
white to almost white crystalline powder | [Uses]
Girard''s Reagent T is a derivatizing agent used to generate permanent cationic charge at the reducing ends of neutral oligosaccharides for easier quantification in matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS). | [Purification Methods]
It is purified by crystallisation from absolute EtOH (slight decomposition) until it has only a slight odour. Store it in well-stoppered containers because it is very hygroscopic. It is very soluble in H2O, AcOH and glycerol but slightly soluble in EtOH (0.66%). It forms water-soluble hydrazones with carbonyl compounds. [Beilstein 4 III 1133.] |
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