Methylphenyldiethoxysilane synthesis
- Product Name:Methylphenyldiethoxysilane
- CAS Number:775-56-4
- Molecular formula:C11H18O2Si
- Molecular Weight:210.34
2031-62-1
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71-43-2
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775-56-4
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Yield: 20 %Chromat.
Reaction Conditions:
with [Rh(OH)(cod)]2;1,2-bis((2S,5S)-2,5-di-i-propylphospholano)ethane in cyclohexene at 80; for 24 h;
Steps:
5
IN this example 5, phenyl,methyl,diethoxysilane of formulawas prepared as follows. In an oven-dried vial, [Rh(cod)(OH)]2 (4.6 mg, 0.01 mmol) and (S,S)-i-Pr-BPE (7.4 mg, 0.02 mmol) were placed. Benzene (1 ml), HMeSi(OEt)2 (134mg, 1 mmol) and cyclohexene (1.1 mmol) were added to the vial. The reaction mixture was allowed to stir for 24 hours at 80 00. GO-Ms analysis confirms formation ofPhMeSi(OEt)2 (GO-Ms yield: 20 %).
References:
DOW SILICONES CORPORATION;CHOI, Jongwook;KATSOULIS, Dimitris;LEE, Kangsang WO2018/190999, 2018, A1 Location in patent:Paragraph 0029
98-13-5
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775-56-4
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2031-67-6
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775-56-4
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149-74-6
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775-56-4
173 suppliers
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