ChemicalBook CAS DataBase List Diethylene glycol diacrylate

Diethylene glycol diacrylate synthesis

4synthesis methods

Product Name:Diethylene glycol diacrylate
CAS Number:4074-88-8
Molecular formula:C10H14O5
Molecular Weight:214.22

75-21-8
229 suppliers
$33.29/crm44609

79-10-7 Synthesis

79-10-7
698 suppliers
$20.16/100 mL

2274-11-5 Synthesis

2274-11-5
72 suppliers
$66.90/100mg

4074-88-8
149 suppliers
$16.30/25g

Yield:2274-11-5 10 %Chromat. ，4074-88-8 9 %Chromat.

Reaction Conditions:

with tempol;10H-phenothiazine;[Zn₄O(benzene-1,4-dicarboxylate)3] at 59; under 7500.75 Torr;

Steps:

4 EXAMPLE 4; Alkoxylation of Acrylic Acid with Ethylene Oxide
33.2 g acrylic acid (stabilized with 2,2', 6,6'-tetramethyl-4-hydroxypiperidine-N-oxide and phenothiazine) and 0.5 g catalyst of Example 1 were weighed into a 300 ml steering autoclave under nitrogen atmosphere. The autoclave was closed and pressurized with 10 bar nitrogen. Upon steering 20 g ethylene oxide were subsequently introduced via a screw press. After five hours at 50° C. the catalyst was filtered off and the raw product was analyzed by gas chromatography. Based on the area percentages the following composition of the solution (residual ethylene oxide not considered): [0128] Acrylic acid 76%, monoethylene glycol acrylate 10%, diethylene glycol acrylate 9%, other side products 5%.

References:

Mueller, Ulrich;Stober, Michael;Ruppel, Raimund;Baum, Eva;Bohres, Edward;Sigl, Marcus;Lobree, Lisa;Yaghi, Omar M;Eddaoudi, Mohamed US2004/249189, 2004, A1 Location in patent:Page 8

FullText