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ChemicalBook CAS DataBase List 8-Bromooctanoic acid
17696-11-6

8-Bromooctanoic acid synthesis

11synthesis methods
29823-21-0 Synthesis
Ethyl 8-bromooctanoate

29823-21-0
328 suppliers
$10.00/1g

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Yield:17696-11-6 97%

Reaction Conditions:

with water;sodium hydroxide in ethanol at 0; for 5 h;

Steps:

8-Bromooctanoic Acid (17)

To a solution of ethyl 8-bromooctanoate (1.0 g, 3.98mmol) in EtOH (10 mL), 1M NaOH (3.98 mL) was addeddropwise, and the resulting mixture was stirred at 0°C for 5h. The mixture was acidified with 1M HCl and extractedwith ethyl acetate (3 10 mL). The organic layer waswashed with satd NaHCO3 (2 20 mL) and brine (2 20mL), dried over Na2SO4, filtered, and concentrated to getcompound 17 as colorless oil 0.86 g, yield 97%.

References:

Zhang, Liying;Dong, Jizhe;Zhang, Yingxia;Liu, Jun;Zhang, Luyong;Sun, Hongbin [Medicinal Chemistry,2013,vol. 9,# 2,p. 294 - 302]

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