ChemicalBook CAS DataBase List 5,5-diMethyl-5H-dibenzo[b,d]stannole

5,5-diMethyl-5H-dibenzo[b,d]stannole synthesis

7synthesis methods

Product Name:5,5-diMethyl-5H-dibenzo[b,d]stannole
CAS Number:5565-85-5
Molecular formula:C14H14Sn
Molecular Weight:300.97

13029-09-9 Synthesis

13029-09-9
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753-73-1 Synthesis

753-73-1
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5565-85-5
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Yield:5565-85-5 96%

Reaction Conditions:

with n-C₄H₉Li in diethyl ether;byproducts: LiCl; Sonication; (Ar); using Schlenk techniques; condensation of Et2O onto solid C12H8Br2at -78°C with stirring, addn. of soln. of 2 equiv. of n-BuLi in hexane, stirring for 3 h at room temp., addn. of soln. of Me2SnCl2 in Et 2O at room temp., stirring overnight; removal of solvent in vac.; vac. transferring of hexane into flask, sonication for 10 min; filtration, removal of solvent in vac., elem. anal.;

References:

Romero, Patricio E.;Piers, Warren E.;Decker, Stephen A.;Chau, Dan;Woo, Tom K.;Parvez, Masood [Organometallics,2003,vol. 22,# 6,p. 1266 - 1274]

13029-09-9 Synthesis

13029-09-9
285 suppliers
$20.00/1g