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ChemicalBook CAS DataBase List 2-AMINO-5-BROMO-3-ETHOXYPYRAZINE
77112-66-4

2-AMINO-5-BROMO-3-ETHOXYPYRAZINE synthesis

3synthesis methods
24241-18-7 Synthesis
2-Amino-3,5-dibromopyrazine

24241-18-7
432 suppliers
$6.00/5g

-

Yield:77112-66-4 90%

Reaction Conditions:

in ethanol; for 8 h;Reflux;

Steps:

208.A Part A

A solution of 3,5-dibromopyrazin-2-amine (47.4 g, 190 mmol) and NaOEt (14 g, 206 mmol) in EtOH (500 mL) was heated at reflux for 8 h. The reaction mixture was evaporated to dryness in vacuo and the residue partitioned between H2O (400 mL) and EtOAc (500 mL). The combined organics were dried (MgSO4) and evaporated to dryness in vacuo to afford 5- bromo-3-ethoxypyrazin-2-amine (36.8 g, 90%).

References:

WO2020/263980,2020,A1 Location in patent:Page/Page column 164

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