2 7-DI-TERT-BUTYL-9-FLUORENYLMETHANOL synthesis
- Product Name:2 7-DI-TERT-BUTYL-9-FLUORENYLMETHANOL
- CAS Number:136453-59-3
- Molecular formula:C22H28O
- Molecular Weight:308.46
50-00-0
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58775-05-6
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136453-59-3
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$53.89/1g
Yield:136453-59-3 63%
Reaction Conditions:
Stage #1: 2,7-di-tert-butyl-9H-fluorenewith n-butyllithium in tetrahydrofuran;hexane at 0 - 5; for 0.133333 h;Metallation;
Stage #2: formaldehyd in tetrahydrofuran;hexane at 0 - 20; for 0.833333 h;Further stages.;hydroxymethylation;
References:
Stigers, Kimberly D.;Koutroulis, Mathew R.;Chung, De Michael;Nowick, James S. [Journal of Organic Chemistry,2000,vol. 65,# 12,p. 3858 - 3859]