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ChemicalBook CAS DataBase List 1H-Benzimidazol-5-ylmethanol
106429-29-2

1H-Benzimidazol-5-ylmethanol synthesis

6synthesis methods
-

Yield:106429-29-2 77%

Reaction Conditions:

with lithium aluminium tetrahydride in tetrahydrofuran at 65; for 48 h;Inert atmosphere;

Steps:

Preparation of compounds 7-10
Preparation of compounds 7-10
To a suspension of 2.0?g (12.3?mmol) of 1H-benzo[d]imidazole-5-carboxylic acid in 50?mL of dry THF, in inert atmosphere was added 983?mg (24,7?mmol) of LiAlH4 and stirred 48?h?at 65?°C.
The reaction mixture was poured into EtOAc/EtOH and was filtered, by evaporation to dryness 1.4?g (77%) of compound 7 was obtained.

References:

álvarez, Raquel;Gajate, Consuelo;Puebla, Pilar;Mollinedo, Faustino;Medarde, Manuel;Peláez, Rafael [European Journal of Medicinal Chemistry,2018,vol. 158,p. 167 - 183]

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