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ChemicalBook CAS DataBase List 1-(2-Methoxyphenyl)piperazine hydrobromide
100939-96-6

1-(2-Methoxyphenyl)piperazine hydrobromide synthesis

2synthesis methods
-

Yield:100939-96-6 96.74%

Reaction Conditions:

with hydrogen bromide in methanol at -15 - 5; for 2.5 h;Solvent;Temperature;

Steps:

9-12; 4 Example 9

Urapidil intermediate 1-(2-methoxyphenyl)piperazine obtained in Example 1 is used to prepare a urapidil intermediate 1-(2-methoxyphenyl)piperazine hydrobromide, The specific operations are as follows:In a 1000mL four-necked flask, add methanol 300mL and 1-(2-methoxyphenyl)piperazine 50g, turn on stirring, control the temperature to 5°C, and drip 148.7mL concentration of 150g/L hydrogen bromide methanol solution in 30min. , cooled to -15°C for 120min after the dropwise addition was completed, and after suction filtration and drying, urapidil intermediate 1-(2-methoxyphenyl)piperazine hydrobromide 68.73g was obtained, yield 96.74%, melting range 232.6-234.4, HPLC purity 99.50%

References:

CN114685399,2022,A Location in patent:Paragraph 0091-0102; 0109-0110

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